Concept explainers
Interpretation:
The angle of diffraction has to be given.
Concept introduction:
Bragg equation:
Bragg diffraction occurs when radiation, with a wavelength comparable to atomic spacing is scattered in a regular fashion by the atoms of a crystalline system and undergoes constructive interference. For a crystalline solid the waves are scattered from lattice planes separated by the interplanar distance
Figure 1
The Bragg equation is,
Where,
Want to see the full answer?
Check out a sample textbook solutionChapter 11 Solutions
Chemistry: Principles and Practice
- Palladium has a cubic crystal structure in which the edge of the unit cell is 389 pm long. If the density of palladium is 12.02 g/cm3, how many palladium atoms are in a unit cell? In which of the cubic unit cells does palladium crystallize?arrow_forwardCalcium oxide consists of a face-centered cubic array of O2 ions, with Ca2+ ions at the center of the unit cell and along the centers of all 12 edges. Calculate the number of each ion in the unit cell.arrow_forwardLithium hydride (LiH) has the sodium chloride structure, and the length of the edge of the unit cell is 4.086 108 cm. Calculate the density of this solid.arrow_forward
- 8.98 If you know the density of material and the length of the edge of its cubic Iattice, how would you determine if it is face-centered cubic, body-centered cubic, or simple cubic Would you have to look up any information?arrow_forward8.16 Iridium forms a face-centered cubic lattice, and an iridium atom is 271.4 pm in diameter. Calculate the density of iridium.arrow_forwardThe density of polonium metal is 9.2 g/cm3. If the extended lattice of polonium exhibits a simple cubic unit cell, estimate the atomic radius of polonium.arrow_forward
- A metal with spacing between planes equal to 0.4164 nm diffracts X-rays with a wavelength of 0.2879 nm. What is the diffraction angle for the first order diffraction peak?arrow_forwardX rays from a copper X-ray tube ( = 154 pm) were diffracted at an angle of 14.22 degrees by a crystal of silicon. Assuming first-order diffraction (n = 1 in the Bragg equation), what is the interplanar spacing in silicon?arrow_forwardThe unit cell of silicon carbide, SiC, is illustrated below. (a) In what type of unit cell are the (dark gray) C atoms arranged? (b) If one edge of the silicon carbide unit cell is 436.0 pm, what is the calculated density of this compound? A portion of the solid-state structure of silicon carbide.arrow_forward
- The surface tension and viscosity of water at several different temperatures are given in this table. Water Surface Tension (mN/m) Viscosity (mPa s) 0 C 75.6 1.79 20 C 72.8 1.00 60 C 66.2 0.47 100 C 58.9 0.28 (a) As temperature increases, what happens to the surface tension of water? Explain why this occurs, in terms of molecular interactions and the effect of changing temperature. (b) As temperature increases, what happens to the viscosity of water? Explain why this occurs, in terms of molecular interactions and the effect of changing temperature.arrow_forwardAluminum metal crystallizes with a face-centered cubic unit cell. The volume of the cell is 0.0662 nm3. (a) What is the atomic radius of aluminum in cm? (b) What is the volume of a single aluminum atom? (c) What is the density of a single aluminum atom? (d) In face-centered cubic cell packing, the fraction of empty space is 26.0%. When this is factored in, what is the calculated density of aluminum?arrow_forwardCrystalline polonium has a primitive cubic unit cell, lithium has a body-centered cubic unit cell, and calcium has a face-centered cubic unit cell. How many Po atoms belong to one unit cell? How many Li atoms belong to one unit cell? How many Ca atoms belong to one unit cell? Draw each unit cell. Indicate on your drawing what fraction of each atom lies within the unit cell.arrow_forward
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning
- Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage LearningChemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning