(a) Interpretation: The synthesis of dicyclohexyl ether using alkoxymercuration-reduction is to be stated. Concept introduction: The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

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Answer 1

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Chapter 11, Problem 11.7P

Interpretation Introduction

(a)

Interpretation:

The synthesis of dicyclohexyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butyl-isobutyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

Question

Chapter 11, Problem 11.7P

Interpretation Introduction

(a)

Interpretation:

The synthesis of dicyclohexyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butyl-isobutyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

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Answer 3

Question

Chapter 11, Problem 11.7P

Interpretation Introduction

(a)

Interpretation:

The synthesis of dicyclohexyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butyl-isobutyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

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Answer 4

Question

Chapter 11, Problem 11.7P

Interpretation Introduction

(a)

Interpretation:

The synthesis of dicyclohexyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butyl-isobutyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

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Answer 5

Chapter 11, Problem 11.7P

Interpretation Introduction

(a)

Interpretation:

The synthesis of dicyclohexyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butyl-isobutyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Answer 6

Chapter 11, Problem 11.7P

Interpretation Introduction

(a)

Interpretation:

The synthesis of dicyclohexyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Answer 7

Chapter 11, Problem 11.7P

Interpretation Introduction

(a)

Interpretation:

The synthesis of dicyclohexyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butyl-isobutyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butyl-isobutyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Answer 10

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Answer 11

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Answer 13

Ch. 11 - Prob. 11.1P Ch. 11 - Prob. 11.2P Ch. 11 - Prob. 11.3P Ch. 11 - Prob. 11.4P Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Prob. 11.7P Ch. 11 - Prob. 11.8P Ch. 11 - Prob. 11.9P Ch. 11 - Prob. 11.10P

Solution Summary: The author explains the synthesis of dicyclohexyl ether using alkoxymercuration-reduction.

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