(a) Interpretation: The curved arrow mechanism and structure of X for the given reaction of δ -chlorobutyl phenyl sulfide in dioxane are to be stated. Concept introduction: Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

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Answer 1

Question

Chapter 11, Problem 11.75AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism and structure of X for the given reaction of δ-chlorobutyl phenyl sulfide in dioxane are to be stated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(b)

Interpretation:

The proximity effect value is to be calculated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the proximity value is smaller than the effect calculated for the similar reaction is to be stated. .

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

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Answer 2

Question

Chapter 11, Problem 11.75AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism and structure of X for the given reaction of δ-chlorobutyl phenyl sulfide in dioxane are to be stated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(b)

Interpretation:

The proximity effect value is to be calculated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the proximity value is smaller than the effect calculated for the similar reaction is to be stated. .

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

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Answer 3

Question

Chapter 11, Problem 11.75AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism and structure of X for the given reaction of δ-chlorobutyl phenyl sulfide in dioxane are to be stated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(b)

Interpretation:

The proximity effect value is to be calculated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the proximity value is smaller than the effect calculated for the similar reaction is to be stated. .

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

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Answer 4

Question

Chapter 11, Problem 11.75AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism and structure of X for the given reaction of δ-chlorobutyl phenyl sulfide in dioxane are to be stated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(b)

Interpretation:

The proximity effect value is to be calculated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the proximity value is smaller than the effect calculated for the similar reaction is to be stated. .

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

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Answer 5

Chapter 11, Problem 11.75AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism and structure of X for the given reaction of δ-chlorobutyl phenyl sulfide in dioxane are to be stated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(b)

Interpretation:

The proximity effect value is to be calculated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the proximity value is smaller than the effect calculated for the similar reaction is to be stated. .

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Answer 6

Chapter 11, Problem 11.75AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism and structure of X for the given reaction of δ-chlorobutyl phenyl sulfide in dioxane are to be stated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Answer 7

Chapter 11, Problem 11.75AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism and structure of X for the given reaction of δ-chlorobutyl phenyl sulfide in dioxane are to be stated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The proximity effect value is to be calculated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The proximity effect value is to be calculated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The reason as to why the proximity value is smaller than the effect calculated for the similar reaction is to be stated. .

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The reason as to why the proximity value is smaller than the effect calculated for the similar reaction is to be stated. .

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 11 - Prob. 11.1P Ch. 11 - Prob. 11.2P Ch. 11 - Prob. 11.3P Ch. 11 - Prob. 11.4P Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Prob. 11.7P Ch. 11 - Prob. 11.8P Ch. 11 - Prob. 11.9P Ch. 11 - Prob. 11.10P

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