Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 11, Problem 11.74AP
Interpretation Introduction
(a)
Interpretation:
The curved arrow mechanism for the given reaction is to stated.
Concept introduction:
Neighbouring group participation is the interaction of the lone pair electrons of a hetero atom or electron present in sigma and pi bond with the parent molecule to increase the
Interpretation Introduction
(b)
Interpretation:
The curved arrow mechanism for the given reaction is to stated.
Concept introduction:
Neighbouring group participation is the interaction of the lone pair electrons of a hetero atom or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ
Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions
about this system:
?
rise
Under these conditions, will the pressure of NOCI tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO?
In other words, if you said the pressure of NOCI will tend to rise, can that
be changed to a tendency to fall by adding NO? Similarly, if you said the
pressure of NOCI will tend to fall, can that be changed to a tendency to
rise by adding NO?
yes
no
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO needed to reverse it.
Round your answer to 2 significant digits.
0.035 atm
✓
G
00.
18
Ar
Highlight each glycosidic bond in the molecule below. Then answer the questions in the table under the drawing area.
HO-
HO-
-0
OH
OH
HO
NG
HO-
HO-
OH
OH
OH
OH
NG
OH
€
+
Suppose the molecule in the drawing area below were reacted with H₂ over a platinum catalyst. Edit the molecule to show what would happen to it. That is, turn
it into the product of the reaction.
Also, write the name of the product molecule under the drawing area.
Name: ☐
H
C=0
X
H-
OH
HO-
H
HO-
-H
CH₂OH
×
Chapter 11 Solutions
Organic Chemistry
Ch. 11 - Prob. 11.1PCh. 11 - Prob. 11.2PCh. 11 - Prob. 11.3PCh. 11 - Prob. 11.4PCh. 11 - Prob. 11.5PCh. 11 - Prob. 11.6PCh. 11 - Prob. 11.7PCh. 11 - Prob. 11.8PCh. 11 - Prob. 11.9PCh. 11 - Prob. 11.10P
Ch. 11 - Prob. 11.11PCh. 11 - Prob. 11.12PCh. 11 - Prob. 11.13PCh. 11 - Prob. 11.14PCh. 11 - Prob. 11.15PCh. 11 - Prob. 11.16PCh. 11 - Prob. 11.17PCh. 11 - Prob. 11.18PCh. 11 - Prob. 11.19PCh. 11 - Prob. 11.20PCh. 11 - Prob. 11.21PCh. 11 - Prob. 11.22PCh. 11 - Prob. 11.23PCh. 11 - Prob. 11.24PCh. 11 - Prob. 11.25PCh. 11 - Prob. 11.26PCh. 11 - Prob. 11.27PCh. 11 - Prob. 11.28PCh. 11 - Prob. 11.29PCh. 11 - Prob. 11.30PCh. 11 - Prob. 11.31PCh. 11 - Prob. 11.32PCh. 11 - Prob. 11.33PCh. 11 - Prob. 11.34PCh. 11 - Prob. 11.35PCh. 11 - Prob. 11.36PCh. 11 - Prob. 11.37PCh. 11 - Prob. 11.38PCh. 11 - Prob. 11.39PCh. 11 - Prob. 11.40PCh. 11 - Prob. 11.41PCh. 11 - Prob. 11.42PCh. 11 - Prob. 11.43PCh. 11 - Prob. 11.44APCh. 11 - Prob. 11.45APCh. 11 - Prob. 11.46APCh. 11 - Prob. 11.47APCh. 11 - Prob. 11.48APCh. 11 - Prob. 11.49APCh. 11 - Prob. 11.50APCh. 11 - Prob. 11.51APCh. 11 - Prob. 11.52APCh. 11 - Prob. 11.53APCh. 11 - Prob. 11.54APCh. 11 - Prob. 11.55APCh. 11 - Prob. 11.56APCh. 11 - Prob. 11.57APCh. 11 - Prob. 11.58APCh. 11 - Prob. 11.59APCh. 11 - Prob. 11.60APCh. 11 - Prob. 11.61APCh. 11 - Prob. 11.62APCh. 11 - Prob. 11.63APCh. 11 - Prob. 11.64APCh. 11 - Prob. 11.65APCh. 11 - Prob. 11.66APCh. 11 - Prob. 11.67APCh. 11 - Prob. 11.68APCh. 11 - Prob. 11.69APCh. 11 - Prob. 11.70APCh. 11 - Prob. 11.71APCh. 11 - Prob. 11.72APCh. 11 - Prob. 11.73APCh. 11 - Prob. 11.74APCh. 11 - Prob. 11.75APCh. 11 - Prob. 11.76APCh. 11 - Prob. 11.77APCh. 11 - Prob. 11.78APCh. 11 - Prob. 11.79APCh. 11 - Prob. 11.80APCh. 11 - Prob. 11.81AP
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