Concept explainers
Interpretation:
The common pollutants and reactions due to combustion of gasoline in internal combustion engine needs to be determined and strategy to reduce pollutant with stoichiometry needs to be explained.
Concept introduction:
The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

Answer to Problem 116A
Some common pollutant gases are
The mass transit can reduce the use of gasoline that directly reduce the release of pollutant. It can show with stoichiometry as:
1 mole of gasoline = 1 vehicle
Explanation of Solution
The combustion of gasoline occurs in the presence of oxygen and leads to the formation of carbon dioxide and water with several other pollutants. Some common pollutant gases are
The mass transit can reduce the use of gasoline that directly reduce the release of pollutant. It can show with stoichiometry as:
1 mole of gasoline = 1 vehicle
So as the number of vehicles will decrease with mass transit, it will decrease the combustion of gasoline also.
Mole ratio is used to show the relation between use of gasoline and number of vehicle.
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- Using reaction free energy to predict equilibrium composition Consider the following equilibrium: N2 (g) + 3H2 (g) = 2NH3 (g) AG⁰ = -34. KJ Now suppose a reaction vessel is filled with 8.06 atm of nitrogen (N2) and 2.58 atm of ammonia (NH3) at 106. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of N2 tend to rise or fall? ☐ x10 fall Is it possible to reverse this tendency by adding H₂? In other words, if you said the pressure of N2 will tend to rise, can that be changed to a tendency to fall by adding H₂? Similarly, if you said the pressure of N2 will tend to fall, can that be changed to a tendency to rise by adding H₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H₂ needed to reverse it. Round your answer to 2 significant digits. yes no ☐ atm ☑ 5 00. 18 Ararrow_forwardi need help with the followingarrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NO(g) +Cl₂ (g) = 2NOC1 (g) AGº = -41. kJ Now suppose a reaction vessel is filled with 8.90 atm of chlorine (C12) and 5.71 atm of nitrosyl chloride (NOC1) at 1075. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. atm ☑ 18 Ararrow_forward
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