Connect 1-Semester Online Access for Principles of General, Organic & Biochemistry
Connect 1-Semester Online Access for Principles of General, Organic & Biochemistry
2nd Edition
ISBN: 9780077633707
Author: Janice Smith
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 11, Problem 11.59AP
Interpretation Introduction

Interpretation:

The structure for formation of two products from the hydration reaction of 2-pentene with water in the presence of sulfuric acid has to be drawn and the reason for more than one product is formed has to be explained.

Concept Introduction:

Hydaration reaction is nothing but the addition of water to an alkene.  In this reaction two bonds are simultaneously broken, one is carbon-carbon double bond, and second one is HOH bond, finally forms two  C-H and C-OH bonds. .  The general reaction can be represented as follows,

Connect 1-Semester Online Access for Principles of General, Organic & Biochemistry, Chapter 11, Problem 11.59AP

In the addition of water to an unsymmetrical alknene, the hydrogen from water is bonded to the less substituted carbon atom and is called Markovnikov’s rule.

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Alkenes can be converted to alcohols by reaction with mercuric acetate to form a β-hydroxyalkylmercury(II) acetate compound, a reaction called oxymercuration. Subsequent reduction with NaBH4 reduces the C–Hg bond to a C–H bond, forming the alkyl alcohol, a reaction called demercuration. Draw the structures of the Hg-containing compound(s) and the final alcohol product(s) formed in the following reaction sequence, omitting byproducts. If applicable, draw hydrogen at a chirality center and indicate stereochemistry via wedge-and-dash bonds.
Alkenes can be converted to alcohols by reaction with mercuric acetate to form a β-hydroxyalkylmercury(II) acetate compound, a reaction called oxymercuration. Subsequent reduction with NaBH4 reduces the C–Hg bond to a C–H bond, forming the alkyl alcohol, a reaction called demercuration. Draw the structures of the Hg-containing compound(s) and the final alcohol product(s) formed in the following reaction sequence, omitting byproducts. If applicable, draw hydrogen at a chirality center and indicate stereochemistry via wedge-and-dash bonds.

Chapter 11 Solutions

Connect 1-Semester Online Access for Principles of General, Organic & Biochemistry

Ch. 11.3 - Prob. 11.11PCh. 11.5 - Prob. 11.12PCh. 11.5 - Prob. 11.13PCh. 11.6 - Prob. 11.14PCh. 11.6 - Prob. 11.15PCh. 11.7 - Prob. 11.16PCh. 11.7 - Prob. 11.17PCh. 11.9 - Prob. 11.18PCh. 11.9 - Draw the structure corresponding to each name. a....Ch. 11.10 - Prob. 11.20PCh. 11.10 - Prob. 11.21PCh. 11.10 - Prob. 11.22PCh. 11 - Prob. 11.23UKCCh. 11 - Prob. 11.24UKCCh. 11 - Prob. 11.25UKCCh. 11 - Prob. 11.26UKCCh. 11 - Answer the following questions about compound A,...Ch. 11 - Prob. 11.28UKCCh. 11 - Prob. 11.29UKCCh. 11 - Prob. 11.30UKCCh. 11 - Prob. 11.31UKCCh. 11 - Prob. 11.32UKCCh. 11 - Prob. 11.33APCh. 11 - Prob. 11.34APCh. 11 - Prob. 11.35APCh. 11 - Prob. 11.36APCh. 11 - Prob. 11.37APCh. 11 - Falcarinol is a natural pesticide found in carrots...Ch. 11 - Prob. 11.39APCh. 11 - Prob. 11.40APCh. 11 - Prob. 11.41APCh. 11 - Prob. 11.42APCh. 11 - Prob. 11.43APCh. 11 - Give the structure corresponding to each IUPAC...Ch. 11 - Leukotriene C4 is a key compound that causes the...Ch. 11 - Prob. 11.46APCh. 11 - Prob. 11.47APCh. 11 - Prob. 11.48APCh. 11 - Prob. 11.49APCh. 11 - Prob. 11.50APCh. 11 - Prob. 11.51APCh. 11 - Prob. 11.52APCh. 11 - Prob. 11.53APCh. 11 - Prob. 11.54APCh. 11 - Prob. 11.55APCh. 11 - Prob. 11.56APCh. 11 - Prob. 11.57APCh. 11 - Draw the products formed in each reaction.Ch. 11 - Prob. 11.59APCh. 11 - Prob. 11.60APCh. 11 - Prob. 11.61APCh. 11 - Prob. 11.62APCh. 11 - Prob. 11.63APCh. 11 - Prob. 11.64APCh. 11 - Prob. 11.65APCh. 11 - Prob. 11.66APCh. 11 - Prob. 11.67APCh. 11 - Prob. 11.68APCh. 11 - Prob. 11.69APCh. 11 - Prob. 11.70APCh. 11 - Prob. 11.71APCh. 11 - Prob. 11.72APCh. 11 - Prob. 11.73APCh. 11 - Prob. 11.74APCh. 11 - Prob. 11.75APCh. 11 - Prob. 11.76APCh. 11 - Prob. 11.77APCh. 11 - Prob. 11.78APCh. 11 - Prob. 11.79APCh. 11 - Prob. 11.80APCh. 11 - Prob. 11.81APCh. 11 - Prob. 11.82APCh. 11 - Prob. 11.83APCh. 11 - Prob. 11.84APCh. 11 - Prob. 11.85APCh. 11 - Prob. 11.86APCh. 11 - Are cis-2-hexene and trans-3-hexene constitutional...Ch. 11 - Prob. 11.88CP
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