The time in days has to be calculated for Fluorine-18 sample to drop to one-eighth of its original level if half-life of fluorine-18 is 110 minutes. Concept Introduction: Radioactive nuclides undergo disintegration by emission of radiation. All the radioactive nuclide do not undergo the decay at a same rate. Some decay rapidly and others decay very slowly. The nuclear stability can be quantitatively expressed by using the half-life. The time required for half quantity of the radioactive substance to undergo decay is known as half-life. It is represented as t 1 / 2 . The equation that relates amount of decayed radioactive material, amount of undecayed radioactive material and the time elapsed can be given as, ( Amount of radionuclide undecayed after n half lives ) = ( Original amount of radionuclide ) x ( 1 2 n )

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LTS Solid: AT=Te-Ti Trial 1 Trial 2 Trial 3 Average ΔΗ Mass water, g 24.096 23.976 23.975 Moles of solid, mol 0.01763 001767 0101781 Temp. change, °C 2.9°C 11700 2.0°C Heat of reaction, J -292.37J -170.473 -193.26J AH, kJ/mole 16.58K 9.647 kJ 10.85 kr 16.58K59.64701 KJ mol 12.35k Minimum AS, J/mol K 41.582 mol-k Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn & Show your calculations for: AH in J and then in kJ/mole for Trial 1: qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J qsin = qrxn = 292.35 292.37J AH in J = 292.375 0.2923kJ 0.01763m01 =1.65×107 AH in kJ/mol = = 16.58K 0.01763mol mol qrx Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con Kelvin.) AS=AHIT (1.65×10(9.64×103) + (1.0 Jimai

Answer 1

Question

Chapter 11, Problem 11.32EP

(a)

Interpretation Introduction

Interpretation:

The time in days has to be calculated for Fluorine-18 sample to drop to one-eighth of its original level if half-life of fluorine-18 is 110 minutes.

Concept Introduction:

Radioactive nuclides undergo disintegration by emission of radiation. All the radioactive nuclide do not undergo the decay at a same rate. Some decay rapidly and others decay very slowly. The nuclear stability can be quantitatively expressed by using the half-life.

The time required for half quantity of the radioactive substance to undergo decay is known as half-life. It is represented as t1/2.

The equation that relates amount of decayed radioactive material, amount of undecayed radioactive material and the time elapsed can be given as,

(Amount of radionuclideundecayed after n half lives) = (Original amount of radionuclide) x (12n)

(b)

Interpretation Introduction

Interpretation:

The time in days has to be calculated for Fluorine-18 sample to drop to 1/32 of its original level if half-life of fluorine-18 is 110 minutes.

Concept Introduction:

Radioactive nuclides undergo disintegration by emission of radiation. All the radioactive nuclide do not undergo the decay at a same rate. Some decay rapidly and others decay very slowly. The nuclear stability can be quantitatively expressed by using the half-life.

The time required for half quantity of the radioactive substance to undergo decay is known as half-life. It is represented as t1/2.

The equation that relates amount of decayed radioactive material, amount of undecayed radioactive material and the time elapsed can be given as,

(Amount of radionuclideundecayed after n half lives) = (Original amount of radionuclide) x (12n)

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LTS Solid: AT=Te-Ti Trial 1 Trial 2 Trial 3 Average ΔΗ Mass water, g 24.096 23.976 23.975 Moles of solid, mol 0.01763 001767 0101781 Temp. change, °C 2.9°C 11700 2.0°C Heat of reaction, J -292.37J -170.473 -193.26J AH, kJ/mole 16.58K 9.647 kJ 10.85 kr 16.58K59.64701 KJ mol 12.35k Minimum AS, J/mol K 41.582 mol-k Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn & Show your calculations for: AH in J and then in kJ/mole for Trial 1: qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J qsin = qrxn = 292.35 292.37J AH in J = 292.375 0.2923kJ 0.01763m01 =1.65×107 AH in kJ/mol = = 16.58K 0.01763mol mol qrx Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con Kelvin.) AS=AHIT (1.65×10(9.64×103) + (1.0 Jimai

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