The major product of the given reaction should be drawn. Concept introduction: In the presence of acid catalyst, this reaction takes place through partial S N 1 and partial S N 2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product. Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

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Answer 1

Question

Chapter 10.7, Problem 27P

(a)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(b)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(c)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(d)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

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Draw the complete mechanism for the reaction below. Please include appropriate arrows, intermediates, and formal charges.

(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.

(III) adsorbent (b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous solution was examined. The adsorption was modelled using a modified Langmuir isotherm, yielding the following values of Kat pH = 6.5: (ii) T/K 10-10 K 280 2.505 295 1.819 310 1.364 325 1.050 Determine the enthalpy of adsorption, AadsHⓇ. If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above conditions, determine Aads Gº.

Answer 2

Question

Chapter 10.7, Problem 27P

(a)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(b)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(c)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(d)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

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Answer 3

Question

Chapter 10.7, Problem 27P

(a)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(b)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(c)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(d)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

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Answer 4

Question

Chapter 10.7, Problem 27P

(a)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(b)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(c)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(d)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 5

Chapter 10.7, Problem 27P

(a)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(b)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(c)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(d)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

Answer 6

Chapter 10.7, Problem 27P

(a)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

Answer 7

Chapter 10.7, Problem 27P

(a)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial S_N1 and partial S_N2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks the Epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 10.1 - Why are NH3 and CH3NH2 no longer nucleophiles when...Ch. 10.1 - Explain the difference in reactivity between...Ch. 10.1 - Prob. 5P Ch. 10.1 - Prob. 6P Ch. 10.1 - Prob. 8P Ch. 10.2 - Prob. 9P Ch. 10.3 - Prob. 11P Ch. 10.3 - Show how 1-propanol can be converted into the...Ch. 10.4 - Which of the following alcohols dehydrates the...Ch. 10.4 - Prob. 14P

Solution Summary: The author explains that the major product of the given reaction should be drawn in the presence of acid catalyst.

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