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What mass of acetylene
if 425 mL of the gas is collected over water at
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- Liquid oxygen was first prepared by heating potassium chlorate, KClO3, in a closed vessel to obtain oxygen at high pressure. The oxygen was cooled until it liquefied. 2KClO3(s)2KCl(s)+3O2(g) If 171 g of potassium chlorate reacts in a 2.70-L vessel, which was initially evacuated, what pressure of oxygen will be attained when the temperature is finally cooled to 25C? Use the preceding chemical equation and ignore the volume of solid product.arrow_forwardPyruvic acid, HC3H3O3, is involved in cell metabolism. It can be assayed for (that is, the amount of it determined) by using a yeast enzyme. The enzyme makes the following reaction go to completion: HC3H3O3(aq)C2H4O(aq)+CO2(g) If a sample containing pyruvic acid gives 21.2 mL of carbon dioxide gas, CO2, at 349 mmHg and 30C, how many grams of pyruvic acid are there in the sample?arrow_forwardRaoul Pictet, the Swiss physicist who first liquefied oxygen, attempted to liquefy hydrogen. He heated potassium formate, KCHO2, with KOH in a closed 2.50-Lvessel. KCHO2(s)+KOH(s)K2CO3(s)+H2(g) If 75.0 g of potassium formate reacts in a 2.50-L vessel, which was initially evacuated, what pressure of hydrogen will be attained when the temperature is finally cooled to 25C? Use the preceding chemical equation and ignore the volume of solid product.arrow_forward
- A mixture contained zinc sulfide, ZnS, and lead sulfide, PbS. A sample of the mixture weighing 6.12 g was reacted with an excess of hydrochloric acid. The reactions are ZnS(s)+2HCL(aq)ZnCl2(aq)+H2S(g)PbS(s)+2HCL(aq)PbCl2(aq)+H2S(g) If the sample reacted completely and produced 1.049 L of hydrogen sulfide, H2S, at 23C and 762 mmHg, what were the percentages of ZnS and PbS in the mixture?arrow_forward54 One way to generate oxygen is to heat potassium chlorate, KClO3. (The other product is potassium chloride.) If 386 mL of oxygen at 41 C and 97.8 kPa is generated by this reaction, what is the minimum mass of KClO3used?arrow_forwardA mixture contained calcium carbonate, CaCO3, and magnesium carbonate, MgCO3. A sample of this mixture weighing 7.85 g was reacted with excess hydrochloric acid. The reactions are CaCO3(g)+2HCL(aq)CaCl2(aq)+H2O(I)+CO2(g)MgCO3(s)+2HCL(aq)MgCl2(aq)+H2O(I)+CO2(g) If the sample reacted completely and produced 1.94 L of carbon dioxide, CO2, at 25C and 785 mmHg, what were the percentages of CaCO3 and MgCO3 in the mixture?arrow_forward
- You have a gas, one of the three known phosphorus-fluorine compounds (PF3, PF3, and P2F4). To find out which, you have decided to measure its molar mass. (a) First, yon determine that the density of the gas is 5.60 g/L at a pressure of 0.971 atm and a temperature of 18.2 C. Calculate the molar mass and identify the compound. (b) To check the results from part (a), you decide to measure the molar mass based on the relative rales of effusion of the unknown gas and CO2. You find that CO2 effuses at a rate of 0.050 mol/min, whereas the unknown phosphorus fluoride effuses at a rate of 0.028 mol/min. Calculate the molar mass of the unknown gas based on these results.arrow_forward47 HCl(g) reacts with ammonia gas, NH3(g), to form solid ammonium chloride. If a sample of ammonia occupying 250 mL at 21 C and a pressure of 140 torr is allowed to react with excess HCl, what mass of NH4Cl will form?arrow_forward5-114 Carbon dioxide gas, saturated with water vapor, can be produced by the addition of aqueous acid to calcium carbonate based on the following balanced net ionic equation: (a) How many moles of wet CO (g), collected at 60.°C and 774 torr total pressure, are produced by the complete reaction of 10.0 g of CaCO3 with excess acid? (b) What volume does this wet CO2 occupy? (c) What volume would the CO2 occupy at 774 torr if a desiccant (a chemical drying agent) were added to remove the water? The vapor pressure of water at 60.°C is 149.4 mm Hg.arrow_forward
- Potassium peroxide is used to absorb the CO2 produced by the people in a space vehicle. 2K2O2(s)+2CO2(g)2K2CO3(s)+O2(g)If a person at rest exhales 3.0 L of air per minute and CO2 is 3.4% (by volume) of exhaled air, how many grams of K2O2 are needed per person for a five-day trip. Assume a temperature of 250 and 728 mm Hg pressure.arrow_forwardYou have an equimolar mixture of the gases SO2 and O2, along with some He, in a container fitted with a piston. The density of this mixture at STP is 1.924 g/L. Assume ideal behavior and constant temperature and pressure. a. What is the mole fraction of He in the original mixture? b. The SO2 and O2 react to completion to form SO3. What is the density of the gas mixture after the reaction is complete?arrow_forwardA 1.0-L flask contains 10.0 g each of O2 and CO2 at 25 C. (a) Which gas has the greater partial pressure, O2 or CO2, or are they the same? (b) Which molecules have the greater rms speed, or are they the same? (c) Which molecules have the greater average kinetic energy, or are they the same?arrow_forward
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