Major elimination product from E 2 when each alkyl halide reacts with hydroxide ion is to be identified. Concept Introduction: The major product of an E 2 reaction is more stable alkene except when the reactants are sterically hindered or leaving group are poor. Zaitsev’s Rule: States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

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Answer 1

Question

Chapter 10.2, Problem 3P

(a)

Interpretation Introduction

Interpretation:

Major elimination product from E₂ when each alkyl halide reacts with hydroxide ion is to be identified.

Concept Introduction:

The major product of an E₂ reaction is more stable alkene except when the reactants are sterically hindered or leaving group are poor.

Zaitsev’s Rule: States that the more substituted alkene is obtained when a hydrogen from is removed from the β-carbon that is bonded to the fewest hydrogen.

(b)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β-carbon that is bonded to the fewest hydrogen.

(c)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

(d)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

(e)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

(f)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

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Potential Energy (kJ) 1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction. AH = -950 kJ AH = 575 kJ (i) Cl₂ (g) + Pt (s) 2C1 (g) + Pt (s) Ea = 1550 kJ (ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s) (iii) Cl (g) + CICO (g) → Cl₂CO (g) Ea = 2240 kJ Ea = 2350 kJ AH = -825 kJ 2600 2400 2200 2000 1800 1600 1400 1200 1000 a. Draw the potential energy diagram for the reaction. Label the data points for clarity. The potential energy of the reactants is 600 kJ 800 600 400 200 0 -200- -400 -600- -800- Reaction Progress

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Answer 2

Question

Chapter 10.2, Problem 3P

(a)

Interpretation Introduction

Interpretation:

Major elimination product from E₂ when each alkyl halide reacts with hydroxide ion is to be identified.

Concept Introduction:

The major product of an E₂ reaction is more stable alkene except when the reactants are sterically hindered or leaving group are poor.

Zaitsev’s Rule: States that the more substituted alkene is obtained when a hydrogen from is removed from the β-carbon that is bonded to the fewest hydrogen.

(b)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β-carbon that is bonded to the fewest hydrogen.

(c)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

(d)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

(e)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

(f)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

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Answer 3

Question

Chapter 10.2, Problem 3P

(a)

Interpretation Introduction

Interpretation:

Major elimination product from E₂ when each alkyl halide reacts with hydroxide ion is to be identified.

Concept Introduction:

The major product of an E₂ reaction is more stable alkene except when the reactants are sterically hindered or leaving group are poor.

Zaitsev’s Rule: States that the more substituted alkene is obtained when a hydrogen from is removed from the β-carbon that is bonded to the fewest hydrogen.

(b)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β-carbon that is bonded to the fewest hydrogen.

(c)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

(d)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

(e)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

(f)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

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Answer 4

Question

Chapter 10.2, Problem 3P

(a)

Interpretation Introduction

Interpretation:

Major elimination product from E₂ when each alkyl halide reacts with hydroxide ion is to be identified.

Concept Introduction:

The major product of an E₂ reaction is more stable alkene except when the reactants are sterically hindered or leaving group are poor.

Zaitsev’s Rule: States that the more substituted alkene is obtained when a hydrogen from is removed from the β-carbon that is bonded to the fewest hydrogen.

(b)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β-carbon that is bonded to the fewest hydrogen.

(c)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

(d)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

(e)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

(f)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

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Answer 5

Chapter 10.2, Problem 3P

(a)

Interpretation Introduction

Interpretation:

Major elimination product from E₂ when each alkyl halide reacts with hydroxide ion is to be identified.

Concept Introduction:

The major product of an E₂ reaction is more stable alkene except when the reactants are sterically hindered or leaving group are poor.

Zaitsev’s Rule: States that the more substituted alkene is obtained when a hydrogen from is removed from the β-carbon that is bonded to the fewest hydrogen.

(b)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β-carbon that is bonded to the fewest hydrogen.

(c)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

(d)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

(e)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

(f)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

Answer 6

Chapter 10.2, Problem 3P

(a)

Interpretation Introduction

Interpretation:

Major elimination product from E₂ when each alkyl halide reacts with hydroxide ion is to be identified.

Concept Introduction:

The major product of an E₂ reaction is more stable alkene except when the reactants are sterically hindered or leaving group are poor.

Zaitsev’s Rule: States that the more substituted alkene is obtained when a hydrogen from is removed from the β-carbon that is bonded to the fewest hydrogen.

Answer 7

Chapter 10.2, Problem 3P

(a)

Interpretation Introduction

Interpretation:

Major elimination product from E₂ when each alkyl halide reacts with hydroxide ion is to be identified.

Concept Introduction:

The major product of an E₂ reaction is more stable alkene except when the reactants are sterically hindered or leaving group are poor.

Zaitsev’s Rule: States that the more substituted alkene is obtained when a hydrogen from is removed from the β-carbon that is bonded to the fewest hydrogen.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β-carbon that is bonded to the fewest hydrogen.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β-carbon that is bonded to the fewest hydrogen.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

Answer 16

(f)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

Answer 17

(f)

Interpretation Introduction

Interpretation:

The major elimination product from E2 when each alkyl halide reacts with hydroxide ion has to be identified.

Concept Introduction:

Zaitsev’s Rule:

States that the more substituted alkene is obtained when a hydrogen from is removed from the β -carbon that is bonded to the fewest hydrogen.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 10.2 - Prob. 1P Ch. 10.2 - Prob. 2P Ch. 10.2 - Prob. 3P Ch. 10.2 - Prob. 4P Ch. 10.3 - Four alkenes are formed from the E1 reaction of...Ch. 10.3 - If 2-fluoropentane could undergo an E1 reaction,...Ch. 10.3 - Prob. 7P Ch. 10.3 - Propose a mechanism for the following reaction:Ch. 10.4 - Prob. 9P Ch. 10.4 - What products will be obtained from the El...

Solution Summary: The author explains Zaitsev's rule that the more substituted alkene is obtained when a hydrogen from is removed from the -carbon that is bonded to the fewest hydrogen.

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