
Chemistry
4th Edition
ISBN: 9780078021527
Author: Julia Burdge
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 10.15, Problem 1PPA
Interpretation Introduction
Interpretation:
The mole fraction of oxygen is to be calculated for partial pressure of oxygen to be 2.8 atm.
Concept introduction:
The mole fraction of an individual gas, for a combination of gases, is the ratio of the moles of the individual gas with the total number of moles of the mixture.
Here,
Also, the mole fraction of an individual gas, for a combination of gases, can be calculated from the ratio of the partial pressure of the individual gas to the total pressure of the combination.
Here,
Expert Solution & Answer

Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 10 Solutions
Chemistry
Ch. 10.1 - Practice ProblemATTEMPT What pressure (in atm) is...Ch. 10.1 - Prob. 1PPBCh. 10.1 - Prob. 1PPCCh. 10.1 - Express a pressure of 1 .15 atm in units of bar....Ch. 10.1 - Prob. 2CPCh. 10.1 - Prob. 3CPCh. 10.1 - Prob. 4CPCh. 10.1 - Prob. 5CPCh. 10.2 - Prob. 1PPACh. 10.2 - Practice ProblemBUILD At what pressure would a...
Ch. 10.2 - Prob. 1PPCCh. 10.2 - 10.2.1 Given .
Ch. 10.2 - Prob. 2CPCh. 10.2 - 10.2.3 At what temperature will a gas sample...Ch. 10.2 - What volume of NH 3 will be produced when 180 mL...Ch. 10.2 - Prob. 5CPCh. 10.2 - Prob. 6CPCh. 10.3 - Practice ProblemATTEMPT A sample of gas originally...Ch. 10.3 - Practice ProblemBUILD At what temperature (in °C )...Ch. 10.3 - Prob. 1PPCCh. 10.3 - Prob. 1CPCh. 10.3 - Prob. 2CPCh. 10.3 - Prob. 3CPCh. 10.3 - Prob. 4CPCh. 10.4 - Practice ProblemATTEMPT What volume (in liters) of...Ch. 10.4 - Practice ProblemBUILD What volumes (in liters) of...Ch. 10.4 - Practice Problem CONCEPTUALIZE
A hypothetical...Ch. 10.4 - Prob. 1CPCh. 10.4 - Prob. 2CPCh. 10.5 - Practice Problem ATTEMPT
What would be the volume...Ch. 10.5 - Prob. 1PPBCh. 10.5 - Prob. 1PPCCh. 10.5 - Prob. 1CPCh. 10.5 - Prob. 2CPCh. 10.5 - Prob. 3CPCh. 10.5 - 10.5.4 What mass of acetylene is produced by the...Ch. 10.5 - In the following diagram, each color represents a...Ch. 10.5 - Prob. 6CPCh. 10.6 - Practice ProblemATTEMPT What is the volume of 5.12...Ch. 10.6 - Practice ProblemBUILD At what temperature ( in °C...Ch. 10.6 - Practice Problem CONCEPTUALIZE
The diagram shown...Ch. 10.6 - Prob. 1CPCh. 10.6 - Prob. 2CPCh. 10.7 - Practice Problem ATTEMPT
Calculate the density of...Ch. 10.7 - Prob. 1PPBCh. 10.7 - Prob. 1PPCCh. 10.7 - Prob. 1CPCh. 10.7 - Prob. 2CPCh. 10.8 - Practice Problem ATTEMPT Determine the molar mass...Ch. 10.8 - Practice Problem BUILD
A sample of the volatile...Ch. 10.8 - Practice ProblemCONCEPTUALIZE These models...Ch. 10.9 - Practice Problem ATTEMPT
What volume (in liters)...Ch. 10.9 - Practice Problem BUILD What mass (in grams) of Na...Ch. 10.9 - Prob. 1PPCCh. 10.10 - Practice Problem ATTEMPT Using all the same...Ch. 10.10 - Practice ProblemBUILD By how much would the...Ch. 10.10 - Prob. 1PPCCh. 10.11 - Prob. 1PPACh. 10.11 - Prob. 1PPBCh. 10.11 - Prob. 1PPCCh. 10.12 - Practice Problem ATTEMPT Determine the partial...Ch. 10.12 - Practice Problem BUILD
Determine the number of...Ch. 10.12 - Prob. 1PPCCh. 10.13 - Prob. 1PPACh. 10.13 - Practice ProblemBUILD Determine the partial...Ch. 10.13 - Prob. 1PPCCh. 10.14 - Practice Problem ATTEMPT
Calculate the mass of ...Ch. 10.14 - Practice ProblemBUILD Determine the volume of gas...Ch. 10.14 - Practice ProblemCONCEPTUALIZE The first diagram...Ch. 10.15 - Prob. 1PPACh. 10.15 - Practice ProblemBUILD What chamber pressure would...Ch. 10.15 - Practice ProblemCONCEPTUALIZE The diagram on the...Ch. 10.16 - Prob. 1PPACh. 10.16 - Practice ProblemBUILD Determine the molar mass and...Ch. 10.16 - Practice ProblemCONCEPTUALIZE The diagram on the...Ch. 10.17 - Practice ProblemATTEMPT Using data from Table...Ch. 10.17 - Practice ProblemBUILD Calculate the pressure...Ch. 10.17 - Practice ProblemCONCEPTUALIZE What properties of...Ch. 10 - Determine the mole fraction of helium in a gaseous...Ch. 10 - Prob. 2KSPCh. 10 - Determine the mole fraction of water in a solution...Ch. 10 - Prob. 4KSPCh. 10 - Prob. 1QPCh. 10 - Prob. 2QPCh. 10 - Prob. 3QPCh. 10 - Prob. 4QPCh. 10 - Prob. 5QPCh. 10 - Prob. 6QPCh. 10 - Prob. 7QPCh. 10 - Prob. 8QPCh. 10 - Prob. 9QPCh. 10 - Prob. 10QPCh. 10 - Prob. 11QPCh. 10 - Prob. 12QPCh. 10 - Prob. 13QPCh. 10 - Prob. 14QPCh. 10 - Calculate the height of a column of methanol (C H...Ch. 10 - Prob. 16QPCh. 10 - What pressure (in atm) is exerted by a column of...Ch. 10 - What pressure (in atm) is exerted by a column of...Ch. 10 - Prob. 19QPCh. 10 - Prob. 20QPCh. 10 - Prob. 21QPCh. 10 - Prob. 22QPCh. 10 - Prob. 23QPCh. 10 - A sample of air occupies 3.8 L when the pressure...Ch. 10 - Prob. 25QPCh. 10 - 10.26 Under constant-pressure conditions a sample...Ch. 10 - 10.27 Ammonia bums in oxygen gas to form nitric...Ch. 10 - Molecular chlorine and molecular fluorine combine...Ch. 10 - A gaseous sample of a substance is cooled at...Ch. 10 - Consider the following gaseous sample in a...Ch. 10 - Prob. 31QPCh. 10 - Prob. 32QPCh. 10 - Prob. 33QPCh. 10 - Prob. 34QPCh. 10 - 10.35 Given that 6.9 moles of carbon monoxide gas...Ch. 10 - What volume will 9.8 moles of sulfur hexafluoride...Ch. 10 - Prob. 37QPCh. 10 - Prob. 38QPCh. 10 - Prob. 39QPCh. 10 - An ideal gas originally at 0.85 atm and 66°C was...Ch. 10 - Calculate the volume (in liters) of 124.3 g of CO...Ch. 10 - Prob. 42QPCh. 10 - Prob. 43QPCh. 10 - Prob. 44QPCh. 10 - At 741 torr and 44°C, 7.10 g of a gas occupies a...Ch. 10 - Prob. 46QPCh. 10 - Assuming that air contains 78 percent N 2 , 21...Ch. 10 - 10.48 A 2.10-L vessel contains 4.65 g of a gas at...Ch. 10 - Calculate the density of hydrogen bromide ( HBr )...Ch. 10 - A certain anesthetic contains 64.9 percent C, 13.5...Ch. 10 - A compound has the empirical formula SF 4 . At...Ch. 10 - Prob. 52QPCh. 10 - Prob. 53QPCh. 10 - Prob. 54QPCh. 10 - Methane, the principal component of natural gas,...Ch. 10 - Prob. 56QPCh. 10 - In alcohol fermentation, yeast converts glucose to...Ch. 10 - A compound of P and F was analyzed as follows:...Ch. 10 - 10.59 A quantity of 0.225 g of a metal M (molar...Ch. 10 - Prob. 60QPCh. 10 - Prob. 61QPCh. 10 - Prob. 62QPCh. 10 - Ethanol ( C 2 H 5 OH ) burns in air: C 2 H 5 OH( l...Ch. 10 - Prob. 64QPCh. 10 - Prob. 65QPCh. 10 - Prob. 66QPCh. 10 - A 2.5-L flask at 15°C contains a mixture of N 2 ,...Ch. 10 - Dry air near sea level has the following...Ch. 10 - Prob. 69QPCh. 10 - Prob. 70QPCh. 10 - 10.71 A sample of zinc metal reacts completely...Ch. 10 - Prob. 72QPCh. 10 - Prob. 73QPCh. 10 - Prob. 74QPCh. 10 - 10.75 The volume of the box on the right is twice...Ch. 10 - Prob. 76QPCh. 10 - Prob. 77QPCh. 10 - Prob. 78QPCh. 10 - Prob. 79QPCh. 10 - Prob. 80QPCh. 10 - Prob. 81QPCh. 10 - Compare the root-mean-square speeds of O 2 and U F...Ch. 10 - Prob. 83QPCh. 10 - Prob. 84QPCh. 10 - 10.85 At a certain temperature the speeds of six...Ch. 10 - Prob. 86QPCh. 10 - Prob. 87QPCh. 10 - Prob. 88QPCh. 10 - Prob. 89QPCh. 10 - Cite two pieces of evidence to show that gases do...Ch. 10 - Figure 10.25(a) shows that at o°C , with the...Ch. 10 - 10.92 Write the van der Waals equation for a real...Ch. 10 - Prob. 93QPCh. 10 - Prob. 94QPCh. 10 - Prob. 95QPCh. 10 - 10.96 Discuss the following phenomena in terms of...Ch. 10 - Prob. 97APCh. 10 - Prob. 98APCh. 10 - Prob. 99APCh. 10 - Prob. 100APCh. 10 - Prob. 101APCh. 10 - Prob. 102APCh. 10 - On heating, potassium chlorate ( KClO 3 )...Ch. 10 - Prob. 104APCh. 10 - Prob. 105APCh. 10 - Prob. 106APCh. 10 - Prob. 107APCh. 10 - Prob. 108APCh. 10 - Prob. 109APCh. 10 - Prob. 110APCh. 10 - A mixture of Na 2 CO 3 and MgCO 3 of mass 7.63 g...Ch. 10 - Prob. 112APCh. 10 - Prob. 113APCh. 10 - Prob. 114APCh. 10 - Prob. 115APCh. 10 - Prob. 116APCh. 10 - Prob. 117APCh. 10 - Prob. 118APCh. 10 - Prob. 119APCh. 10 - Prob. 120APCh. 10 - Prob. 121APCh. 10 - Prob. 122APCh. 10 - Prob. 123APCh. 10 - Prob. 124APCh. 10 - Prob. 125APCh. 10 - Prob. 126APCh. 10 - Prob. 127APCh. 10 - Prob. 128APCh. 10 - Prob. 129APCh. 10 - Prob. 130APCh. 10 - Prob. 131APCh. 10 - Prob. 132APCh. 10 - Prob. 133APCh. 10 - Prob. 134APCh. 10 - Prob. 135APCh. 10 - Prob. 136APCh. 10 - Prob. 137APCh. 10 - Prob. 138APCh. 10 - Prob. 139APCh. 10 - Given that the van der Waals constant b is the...Ch. 10 - Prob. 141APCh. 10 - Prob. 142APCh. 10 - Prob. 143APCh. 10 - Prob. 144APCh. 10 - Prob. 145APCh. 10 - Prob. 146APCh. 10 - Prob. 147APCh. 10 - Prob. 148APCh. 10 - A 5.00-mol sample of NH 3 gas is kept in a 1.92-L...Ch. 10 - In the metallurgical process of refining nickel,...Ch. 10 - Some commercial drain cleaners contain a mixture...Ch. 10 - Prob. 152APCh. 10 - Prob. 153APCh. 10 - Prob. 154APCh. 10 - Prob. 155APCh. 10 - 10. 156 Air entering the lungs ends up in tiny...Ch. 10 - Prob. 157APCh. 10 - Prob. 158APCh. 10 - Prob. 159APCh. 10 - Prob. 160APCh. 10 - The percent by mass of bicarbonate ( HCO 3 ) in a...Ch. 10 - Prob. 162APCh. 10 - Prob. 163APCh. 10 - Prob. 164APCh. 10 - Prob. 165APCh. 10 - Prob. 166APCh. 10 - Prob. 167APCh. 10 - Venus's atmosphere is composed of 96.5 percent CO...Ch. 10 - Acidic oxides such as carbon dioxide react with...Ch. 10 - Prob. 170APCh. 10 - 10.171 In a constant-pressure calorimetry...Ch. 10 - Prob. 2SEPPCh. 10 - Prob. 3SEPPCh. 10 - Prob. 4SEPP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- elow are experimentally determined van Deemter plots of column efficiency, H, vs. flow rate. H is a quantitative measurement of band broadening. The left plot is for a liquid chromatography application and the night is for gas chromatography. Compare and contrast these two plots in terms of the three band broadening mechanisms presented in this activity. How are they similar? How do they differ? Justify your answers.? 0.4 H (mm) 0.2 0.1- 0.3- 0 0.5 H (mm) 8.0 7.0 6.0 5.0 4.0- 3.0 T +++ 1.0 1.5 0 2.0 4.0 Flow Rate, u (cm/s) 6.0 8.0 Flow Rate, u (cm/s)arrow_forwardPredict the products of this organic reaction: + H ZH NaBH3CN H+ n. ? Click and drag to start drawing a structure. Xarrow_forwardWhat is the missing reactant R in this organic reaction? + R H3O+ + • Draw the structure of R in the drawing area below. • Be sure to use wedge and dash bonds if it's necessary to draw one particular enantiomer. Click and drag to start drawing a structure.arrow_forward
- What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1 1. PPh3 2. n-BuLi 2 • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Click and drag to start drawing a structure.arrow_forwardThe product on the right-hand side of this reaction can be prepared from two organic reactants, under the conditions shown above and below the arrow. Draw 1 and 2 below, in any arrangement you like. 1+2 NaBH₂CN H+ N Click and drag to start drawing a structure. X $arrow_forwardExplain what is the maximum absorbance of in which caffeine absorbs?arrow_forward
- Explain reasons as to why the amount of caffeine extracted from both a singular extraction (5ml Mountain Dew) and a multiple extraction (2 x 5.0ml Mountain Dew) were severely high when compared to coca-cola?arrow_forwardProtecting Groups and Carbonyls 6) The synthesis generates allethrolone that exhibits high insect toxicity but low mammalian toxicity. They are used in pet shampoo, human lice shampoo, and industrial sprays for insects and mosquitos. Propose detailed mechanistic steps to generate the allethrolone label the different types of reagents (Grignard, acid/base protonation, acid/base deprotonation, reduction, oxidation, witting, aldol condensation, Robinson annulation, etc.) III + VI HS HS H+ CH,CH,Li III I II IV CI + P(Ph)3 V ༼ Hint: no strong base added VI S VII IX HO VIII -MgBr HgCl2,HgO HO. isomerization aqeuous solution H,SO, ༽༽༤༽༽ X MeOH Hint: enhances selectivity for reaction at the S X ☑arrow_forwardDraw the complete mechanism for the acid-catalyzed hydration of this alkene. esc 田 Explanation Check 1 888 Q A slock Add/Remove step Q F4 F5 F6 A བྲA F7 $ % 5 @ 4 2 3 & 6 87 Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Ce W E R T Y U S D LL G H IK DD 요 F8 F9 F10 F1 * ( 8 9 0 O P J K L Z X C V B N M H He commandarrow_forward
- Explanation Check F1 H₂O H₂ Pd 1) MCPBA 2) H3O+ 1) Hg(OAc)2, H₂O 2) NaBH4 OH CI OH OH OH hydration halohydrin formation addition halogenation hydrogenation inhalation hydrogenation hydration ☐ halohydrin formation addition halogenation formation chelation hydrogenation halohydrin formation substitution hydration halogenation addition Ohalohydrin formation subtraction halogenation addition hydrogenation hydration F2 80 F3 σ F4 F5 F6 1 ! 2 # 3 $ 4 % 05 Q W & Å © 2025 McGraw Hill LLC. All Rights Reserved. F7 F8 ( 6 7 8 9 LU E R T Y U A F9arrow_forwardShow the mechanism steps to obtain the lowerenergy intermediate: *see imagearrow_forwardSoap is made by the previous reaction *see image. The main difference between one soap and another soap isthe length (number of carbons) of the carboxylic acid. However, if a soap irritates your skin, they mostlikely used too much lye.Detergents have the same chemical structure as soaps except for the functional group. Detergentshave sulfate (R-SO4H) and phosphate (R-PO4H2) functional groups. Draw the above carboxylic acidcarbon chain but as the two variants of detergents. *see imagearrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningIntroduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
- Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning

Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning

General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning

Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning

Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,

Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning

Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning