
Chemistry
4th Edition
ISBN: 9780078021527
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Question
Chapter 10, Problem 43QP
Interpretation Introduction
Interpretation:
The pressure of
Concept Introduction:
The ideal gas equation elaborates the physical properties of gases by relating the pressure, volume, temperature, and number of moles linked with each other with the help of four
Here,
The number of moles can be calculated as:
Here,
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A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in
the following reaction.
Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is
a weak base used to neutralize strong acid (pKa < 0) produced by the reaction.
Redraw the product to show the configuration(s) that form at C-2 and C-4.
Br2
OH
CH2Cl2
Na* HCO3
Br
HO
OH
+ Na Br +
2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If
two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each
reagent set. If a reaction cannot be carried out with reagents (sets)
class, write NP (not possible) in the solvent box for reagent set #1.
Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s).
Solvents: CH2Cl2 (A);
H₂O (B);
Reagents:
HBr (1);
R₂BH (6);
H2SO4 (2);
CH3OH (C);
Br₂ (3);
CH3CO₂H (D)
NaHCO3 (4);
Hg(OAc)2 (5);
H₂O2/HO (7);
NaBH4 (8)
Reagent Set #1
Reagent Set #2
FGI
+ enant
OH
Solvent Reagent(s) Solvent Reagent(s)
Chapter 10 Solutions
Chemistry
Ch. 10.1 - Practice ProblemATTEMPT What pressure (in atm) is...Ch. 10.1 - Prob. 1PPBCh. 10.1 - Prob. 1PPCCh. 10.1 - Express a pressure of 1 .15 atm in units of bar....Ch. 10.1 - Prob. 2CPCh. 10.1 - Prob. 3CPCh. 10.1 - Prob. 4CPCh. 10.1 - Prob. 5CPCh. 10.2 - Prob. 1PPACh. 10.2 - Practice ProblemBUILD At what pressure would a...
Ch. 10.2 - Prob. 1PPCCh. 10.2 - 10.2.1 Given .
Ch. 10.2 - Prob. 2CPCh. 10.2 - 10.2.3 At what temperature will a gas sample...Ch. 10.2 - What volume of NH 3 will be produced when 180 mL...Ch. 10.2 - Prob. 5CPCh. 10.2 - Prob. 6CPCh. 10.3 - Practice ProblemATTEMPT A sample of gas originally...Ch. 10.3 - Practice ProblemBUILD At what temperature (in °C )...Ch. 10.3 - Prob. 1PPCCh. 10.3 - Prob. 1CPCh. 10.3 - Prob. 2CPCh. 10.3 - Prob. 3CPCh. 10.3 - Prob. 4CPCh. 10.4 - Practice ProblemATTEMPT What volume (in liters) of...Ch. 10.4 - Practice ProblemBUILD What volumes (in liters) of...Ch. 10.4 - Practice Problem CONCEPTUALIZE
A hypothetical...Ch. 10.4 - Prob. 1CPCh. 10.4 - Prob. 2CPCh. 10.5 - Practice Problem ATTEMPT
What would be the volume...Ch. 10.5 - Prob. 1PPBCh. 10.5 - Prob. 1PPCCh. 10.5 - Prob. 1CPCh. 10.5 - Prob. 2CPCh. 10.5 - Prob. 3CPCh. 10.5 - 10.5.4 What mass of acetylene is produced by the...Ch. 10.5 - In the following diagram, each color represents a...Ch. 10.5 - Prob. 6CPCh. 10.6 - Practice ProblemATTEMPT What is the volume of 5.12...Ch. 10.6 - Practice ProblemBUILD At what temperature ( in °C...Ch. 10.6 - Practice Problem CONCEPTUALIZE
The diagram shown...Ch. 10.6 - Prob. 1CPCh. 10.6 - Prob. 2CPCh. 10.7 - Practice Problem ATTEMPT
Calculate the density of...Ch. 10.7 - Prob. 1PPBCh. 10.7 - Prob. 1PPCCh. 10.7 - Prob. 1CPCh. 10.7 - Prob. 2CPCh. 10.8 - Practice Problem ATTEMPT Determine the molar mass...Ch. 10.8 - Practice Problem BUILD
A sample of the volatile...Ch. 10.8 - Practice ProblemCONCEPTUALIZE These models...Ch. 10.9 - Practice Problem ATTEMPT
What volume (in liters)...Ch. 10.9 - Practice Problem BUILD What mass (in grams) of Na...Ch. 10.9 - Prob. 1PPCCh. 10.10 - Practice Problem ATTEMPT Using all the same...Ch. 10.10 - Practice ProblemBUILD By how much would the...Ch. 10.10 - Prob. 1PPCCh. 10.11 - Prob. 1PPACh. 10.11 - Prob. 1PPBCh. 10.11 - Prob. 1PPCCh. 10.12 - Practice Problem ATTEMPT Determine the partial...Ch. 10.12 - Practice Problem BUILD
Determine the number of...Ch. 10.12 - Prob. 1PPCCh. 10.13 - Prob. 1PPACh. 10.13 - Practice ProblemBUILD Determine the partial...Ch. 10.13 - Prob. 1PPCCh. 10.14 - Practice Problem ATTEMPT
Calculate the mass of ...Ch. 10.14 - Practice ProblemBUILD Determine the volume of gas...Ch. 10.14 - Practice ProblemCONCEPTUALIZE The first diagram...Ch. 10.15 - Prob. 1PPACh. 10.15 - Practice ProblemBUILD What chamber pressure would...Ch. 10.15 - Practice ProblemCONCEPTUALIZE The diagram on the...Ch. 10.16 - Prob. 1PPACh. 10.16 - Practice ProblemBUILD Determine the molar mass and...Ch. 10.16 - Practice ProblemCONCEPTUALIZE The diagram on the...Ch. 10.17 - Practice ProblemATTEMPT Using data from Table...Ch. 10.17 - Practice ProblemBUILD Calculate the pressure...Ch. 10.17 - Practice ProblemCONCEPTUALIZE What properties of...Ch. 10 - Determine the mole fraction of helium in a gaseous...Ch. 10 - Prob. 2KSPCh. 10 - Determine the mole fraction of water in a solution...Ch. 10 - Prob. 4KSPCh. 10 - Prob. 1QPCh. 10 - Prob. 2QPCh. 10 - Prob. 3QPCh. 10 - Prob. 4QPCh. 10 - Prob. 5QPCh. 10 - Prob. 6QPCh. 10 - Prob. 7QPCh. 10 - Prob. 8QPCh. 10 - Prob. 9QPCh. 10 - Prob. 10QPCh. 10 - Prob. 11QPCh. 10 - Prob. 12QPCh. 10 - Prob. 13QPCh. 10 - Prob. 14QPCh. 10 - Calculate the height of a column of methanol (C H...Ch. 10 - Prob. 16QPCh. 10 - What pressure (in atm) is exerted by a column of...Ch. 10 - What pressure (in atm) is exerted by a column of...Ch. 10 - Prob. 19QPCh. 10 - Prob. 20QPCh. 10 - Prob. 21QPCh. 10 - Prob. 22QPCh. 10 - Prob. 23QPCh. 10 - A sample of air occupies 3.8 L when the pressure...Ch. 10 - Prob. 25QPCh. 10 - 10.26 Under constant-pressure conditions a sample...Ch. 10 - 10.27 Ammonia bums in oxygen gas to form nitric...Ch. 10 - Molecular chlorine and molecular fluorine combine...Ch. 10 - A gaseous sample of a substance is cooled at...Ch. 10 - Consider the following gaseous sample in a...Ch. 10 - Prob. 31QPCh. 10 - Prob. 32QPCh. 10 - Prob. 33QPCh. 10 - Prob. 34QPCh. 10 - 10.35 Given that 6.9 moles of carbon monoxide gas...Ch. 10 - What volume will 9.8 moles of sulfur hexafluoride...Ch. 10 - Prob. 37QPCh. 10 - Prob. 38QPCh. 10 - Prob. 39QPCh. 10 - An ideal gas originally at 0.85 atm and 66°C was...Ch. 10 - Calculate the volume (in liters) of 124.3 g of CO...Ch. 10 - Prob. 42QPCh. 10 - Prob. 43QPCh. 10 - Prob. 44QPCh. 10 - At 741 torr and 44°C, 7.10 g of a gas occupies a...Ch. 10 - Prob. 46QPCh. 10 - Assuming that air contains 78 percent N 2 , 21...Ch. 10 - 10.48 A 2.10-L vessel contains 4.65 g of a gas at...Ch. 10 - Calculate the density of hydrogen bromide ( HBr )...Ch. 10 - A certain anesthetic contains 64.9 percent C, 13.5...Ch. 10 - A compound has the empirical formula SF 4 . At...Ch. 10 - Prob. 52QPCh. 10 - Prob. 53QPCh. 10 - Prob. 54QPCh. 10 - Methane, the principal component of natural gas,...Ch. 10 - Prob. 56QPCh. 10 - In alcohol fermentation, yeast converts glucose to...Ch. 10 - A compound of P and F was analyzed as follows:...Ch. 10 - 10.59 A quantity of 0.225 g of a metal M (molar...Ch. 10 - Prob. 60QPCh. 10 - Prob. 61QPCh. 10 - Prob. 62QPCh. 10 - Ethanol ( C 2 H 5 OH ) burns in air: C 2 H 5 OH( l...Ch. 10 - Prob. 64QPCh. 10 - Prob. 65QPCh. 10 - Prob. 66QPCh. 10 - A 2.5-L flask at 15°C contains a mixture of N 2 ,...Ch. 10 - Dry air near sea level has the following...Ch. 10 - Prob. 69QPCh. 10 - Prob. 70QPCh. 10 - 10.71 A sample of zinc metal reacts completely...Ch. 10 - Prob. 72QPCh. 10 - Prob. 73QPCh. 10 - Prob. 74QPCh. 10 - 10.75 The volume of the box on the right is twice...Ch. 10 - Prob. 76QPCh. 10 - Prob. 77QPCh. 10 - Prob. 78QPCh. 10 - Prob. 79QPCh. 10 - Prob. 80QPCh. 10 - Prob. 81QPCh. 10 - Compare the root-mean-square speeds of O 2 and U F...Ch. 10 - Prob. 83QPCh. 10 - Prob. 84QPCh. 10 - 10.85 At a certain temperature the speeds of six...Ch. 10 - Prob. 86QPCh. 10 - Prob. 87QPCh. 10 - Prob. 88QPCh. 10 - Prob. 89QPCh. 10 - Cite two pieces of evidence to show that gases do...Ch. 10 - Figure 10.25(a) shows that at o°C , with the...Ch. 10 - 10.92 Write the van der Waals equation for a real...Ch. 10 - Prob. 93QPCh. 10 - Prob. 94QPCh. 10 - Prob. 95QPCh. 10 - 10.96 Discuss the following phenomena in terms of...Ch. 10 - Prob. 97APCh. 10 - Prob. 98APCh. 10 - Prob. 99APCh. 10 - Prob. 100APCh. 10 - Prob. 101APCh. 10 - Prob. 102APCh. 10 - On heating, potassium chlorate ( KClO 3 )...Ch. 10 - Prob. 104APCh. 10 - Prob. 105APCh. 10 - Prob. 106APCh. 10 - Prob. 107APCh. 10 - Prob. 108APCh. 10 - Prob. 109APCh. 10 - Prob. 110APCh. 10 - A mixture of Na 2 CO 3 and MgCO 3 of mass 7.63 g...Ch. 10 - Prob. 112APCh. 10 - Prob. 113APCh. 10 - Prob. 114APCh. 10 - Prob. 115APCh. 10 - Prob. 116APCh. 10 - Prob. 117APCh. 10 - Prob. 118APCh. 10 - Prob. 119APCh. 10 - Prob. 120APCh. 10 - Prob. 121APCh. 10 - Prob. 122APCh. 10 - Prob. 123APCh. 10 - Prob. 124APCh. 10 - Prob. 125APCh. 10 - Prob. 126APCh. 10 - Prob. 127APCh. 10 - Prob. 128APCh. 10 - Prob. 129APCh. 10 - Prob. 130APCh. 10 - Prob. 131APCh. 10 - Prob. 132APCh. 10 - Prob. 133APCh. 10 - Prob. 134APCh. 10 - Prob. 135APCh. 10 - Prob. 136APCh. 10 - Prob. 137APCh. 10 - Prob. 138APCh. 10 - Prob. 139APCh. 10 - Given that the van der Waals constant b is the...Ch. 10 - Prob. 141APCh. 10 - Prob. 142APCh. 10 - Prob. 143APCh. 10 - Prob. 144APCh. 10 - Prob. 145APCh. 10 - Prob. 146APCh. 10 - Prob. 147APCh. 10 - Prob. 148APCh. 10 - A 5.00-mol sample of NH 3 gas is kept in a 1.92-L...Ch. 10 - In the metallurgical process of refining nickel,...Ch. 10 - Some commercial drain cleaners contain a mixture...Ch. 10 - Prob. 152APCh. 10 - Prob. 153APCh. 10 - Prob. 154APCh. 10 - Prob. 155APCh. 10 - 10. 156 Air entering the lungs ends up in tiny...Ch. 10 - Prob. 157APCh. 10 - Prob. 158APCh. 10 - Prob. 159APCh. 10 - Prob. 160APCh. 10 - The percent by mass of bicarbonate ( HCO 3 ) in a...Ch. 10 - Prob. 162APCh. 10 - Prob. 163APCh. 10 - Prob. 164APCh. 10 - Prob. 165APCh. 10 - Prob. 166APCh. 10 - Prob. 167APCh. 10 - Venus's atmosphere is composed of 96.5 percent CO...Ch. 10 - Acidic oxides such as carbon dioxide react with...Ch. 10 - Prob. 170APCh. 10 - 10.171 In a constant-pressure calorimetry...Ch. 10 - Prob. 2SEPPCh. 10 - Prob. 3SEPPCh. 10 - Prob. 4SEPP
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