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Hydrogen peroxide and ferrous sulfate react to produce hydroxyl radical (HO·), as reported in 1894 by. English chemist H.J. H. Fenton. When tert-butyl alcohol is treated with HO· generated this way, it affords a crystalline reaction produa X, mp 92 °C, which has these spectral properties:
MS: heaviest mass peak is at m/z 131
IR: 3620, 3350 (broad), 2980, 2940, 1385, 1370 cm−1
Draw the structure of X and write a mechanism for its formation.
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Organic Chemistry
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