Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 10, Problem 37P

The halogen atom of an alkyl halide can be replaced by the hydrogen atom bonded to tin in tributytin hydride ( B u 3 S n H ) . The process, called dehalogenation, is a radical reaction, and it can be initiated by AIBN (2, 2'-azobisisobutyronitrile). AIBN decomposes to form nitrogen gas and two isobutyronitrile radicals, which initiate the reaction. Write a mechanism for the reaction.

Chapter 10, Problem 37P, The halogen atom of an alkyl halide can be replaced by the hydrogen atom bonded to tin in tributytin

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Part I. Problem solving. Include all necessary calculations 13 provide plots and graphs. Complexation wl diphenyl carbazide (OPC) in acidic media is another type of sensitive photometric method used for the analysis of aqueous. hexavalent chromium. At 540nm the cherry-red complex as a result of DPC reaction w/ chromium can be photometrically measured. at this wavelength. - a 25mL The UV-vis analysis for the determination of nexavalent chromium in ground water sample is given below. The experiment was based on external calibration method w/ each measurement sample prepared are as follows lab sample analysis contained the standard 100 ppb croy cor groundwater sample, volumes used as indicated below), 12.50 mL of 0.02 M H2Soy and 5.50 ml of 100 ppm DPC (wi water to adjust final volume to 25-ml). The main stripping method was square wave voltammetry, following the conditions set in the main ASV experiment. Standard 100 Volumetric Groundwater H2SO4 0.20 M, flask Sample, mL ppb CrO4*, 100…
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