* 10.108 Early one cool ( 60 .0 °F ) morning you start on a bike ride with the atmospheric pressure at 14 .7 lb in . -2 and the tire gauge pressure at 50 .0 lb in . -2 . (Gauge pressure is the amount that the pressure exceeds atmospheric pressure.) By late afternoon, the air had warmed up considerably, and this plus the heat generated by tire friction sent the temperature inside the tire to 104 °F . What will the tire gauge now read, assuming that the volume of the air in the tire and the atmospheric pressure have not changed?
* 10.108 Early one cool ( 60 .0 °F ) morning you start on a bike ride with the atmospheric pressure at 14 .7 lb in . -2 and the tire gauge pressure at 50 .0 lb in . -2 . (Gauge pressure is the amount that the pressure exceeds atmospheric pressure.) By late afternoon, the air had warmed up considerably, and this plus the heat generated by tire friction sent the temperature inside the tire to 104 °F . What will the tire gauge now read, assuming that the volume of the air in the tire and the atmospheric pressure have not changed?
*10.108 Early one cool
(
60
.0 °F
)
morning you start on a bike ride with the atmospheric pressure at
14
.7 lb in
.
-2
and the tire gauge pressure at
50
.0 lb in
.
-2
. (Gauge pressure is the amount that the pressure exceeds atmospheric pressure.) By late afternoon, the air had warmed up considerably, and this plus the heat generated by tire friction sent the temperature inside the tire to
104 °F
. What will the tire gauge now read, assuming that the volume of the air in the tire and the atmospheric pressure have not changed?
What spectral features allow you to differentiate the product from the starting material?
Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR.
2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too.
3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.
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