The explosive PETN, pentaerythritoltetranitrate, is one of the most powerful explosives P known. It reacts with the following balanced equation C(CH 2 ONO 2 ) 4 ( s ) → 2CO( g )+4H 2 O( g )+3CO 2 ( g )+2N 2 ( g ) If 0.0250 mol of PETN reacts to fill a 30.0 L sphere at a temperature of 25 °C , what is the partial pressure of each gas and the total pressure in the flask? ( Hint: Stan by calculating the moles of each gas present.)
The explosive PETN, pentaerythritoltetranitrate, is one of the most powerful explosives P known. It reacts with the following balanced equation C(CH 2 ONO 2 ) 4 ( s ) → 2CO( g )+4H 2 O( g )+3CO 2 ( g )+2N 2 ( g ) If 0.0250 mol of PETN reacts to fill a 30.0 L sphere at a temperature of 25 °C , what is the partial pressure of each gas and the total pressure in the flask? ( Hint: Stan by calculating the moles of each gas present.)
The explosive PETN, pentaerythritoltetranitrate, is one of the most powerful explosives P known. It reacts with the following balanced equation
C(CH
2
ONO
2
)
4
(
s
)
→
2CO(
g
)+4H
2
O(
g
)+3CO
2
(
g
)+2N
2
(
g
)
If 0.0250 mol of PETN reacts to fill a 30.0 L sphere at a temperature of
25 °C
, what is the partial pressure of each gas and the total pressure in the flask? (Hint: Stan by calculating the moles of each gas present.)
Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
respectively.
F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
have a reasonable yield of product.
NH2
Br
Br
Br
OH
Br
Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
NH2
LL
F
C
D
OH
CI
LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
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