Uranium hexafluoride is a white solid that readily passes directly into the vapor state. (Its vapor pressure at 20 .0 °C is 120 torr.) A trace of the uranium in this compound—about 0.7%—is uranium-235, which can be used in a nuclear power plant. The rest of the uranium is essentially uranium-238, and its presence interferes with these applications for uranium-235. Gas effusion of UF 6 can be used to separate the fluoride made from uranium-235 and the fluoride made from uranium-238. Which hexafluoride effuses more rapidly? By how much? (You can check your answer by reading Chemistry and Current Affairs 10.1 in Section 10.6.)
Uranium hexafluoride is a white solid that readily passes directly into the vapor state. (Its vapor pressure at 20 .0 °C is 120 torr.) A trace of the uranium in this compound—about 0.7%—is uranium-235, which can be used in a nuclear power plant. The rest of the uranium is essentially uranium-238, and its presence interferes with these applications for uranium-235. Gas effusion of UF 6 can be used to separate the fluoride made from uranium-235 and the fluoride made from uranium-238. Which hexafluoride effuses more rapidly? By how much? (You can check your answer by reading Chemistry and Current Affairs 10.1 in Section 10.6.)
Uranium hexafluoride is a white solid that readily passes directly into the vapor state. (Its vapor pressure at
20
.0 °C
is 120 torr.) A trace of the uranium in this compound—about 0.7%—is uranium-235, which can be used in a nuclear power plant. The rest of the uranium is essentially uranium-238, and its presence interferes with these applications for uranium-235. Gas effusion of
UF
6
can be used to separate the fluoride made from uranium-235 and the fluoride made from uranium-238. Which hexafluoride effuses more rapidly? By how much? (You can check your answer by reading Chemistry and Current Affairs 10.1 in Section 10.6.)
Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
respectively.
F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
have a reasonable yield of product.
NH2
Br
Br
Br
OH
Br
Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
NH2
LL
F
C
D
OH
CI
LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
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