Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
expand_more
expand_more
format_list_bulleted
Question
Chapter 1, Problem 70CP
Interpretation Introduction
Interpretation:
To explain why the liquid product 3 and 4 doesn’t separate easily in room temperature but upon heating it separates easily.
Concept introduction:
Boiling point of a compound is the temperature at which the compounds escape into vapor state from liquid state. The boiling temperature of a compound depends upon many facts and few of them are,
- Number of carbon atoms present
- Presence of hydrogen bonding (intermolecular or intramolecular)
- Presence of hydrogen acceptors etc…
To find: To find why mixture of products compound 3 and compound 4 separates easily when temperature is raised.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
d.
a phenylal
Give the major organic product(s) of each of the following reactions or sequences of reactions. Show all
levant stereochemistry. [three only]
0
A.
B.
CH3
Bra
CH3COOH
OH
1. Br₂, PBrz
2 H₂O
12
2
Show how the following conversions might be accomplished. Show all reagents and all intermediate
ructures. More than one step may be required [2 ONLY]:
A.
B.
°
C.
OH
0
OH
0
Chapter 1 Solutions
Organic Chemistry
Ch. 1.2 - Prob. 1LTSCh. 1.2 - Prob. 1PTSCh. 1.2 - Prob. 2ATSCh. 1.2 - Prob. 3ATSCh. 1.2 - Prob. 4ATSCh. 1.3 - Prob. 2LTSCh. 1.3 - Prob. 5PTSCh. 1.3 - Prob. 6ATSCh. 1.3 - Prob. 7ATSCh. 1.3 - Prob. 8ATS
Ch. 1.3 - Prob. 9ATSCh. 1.3 - Prob. 3LTSCh. 1.3 - Prob. 10PTSCh. 1.3 - Prob. 11ATSCh. 1.3 - Prob. 12ATSCh. 1.4 - Prob. 4LTSCh. 1.4 - Prob. 13PTSCh. 1.4 - Prob. 14ATSCh. 1.5 - Prob. 5LTSCh. 1.5 - Prob. 15PTSCh. 1.5 - Prob. 16ATSCh. 1.6 - Prob. 6LTSCh. 1.6 - Prob. 17PTSCh. 1.6 - Prob. 18ATSCh. 1.9 - Prob. 19CCCh. 1.9 - Prob. 20CCCh. 1.9 - Prob. 21CCCh. 1.9 - Prob. 7LTSCh. 1.9 - Prob. 22PTSCh. 1.9 - Prob. 23ATSCh. 1.9 - Prob. 24CCCh. 1.10 - Prob. 8LTSCh. 1.10 - Prob. 25PTSCh. 1.10 - Prob. 26PTSCh. 1.10 - Prob. 27ATSCh. 1.10 - Prob. 28ATSCh. 1.11 - Prob. 9LTSCh. 1.11 - Prob. 29PTSCh. 1.11 - Prob. 30ATSCh. 1.11 - Prob. 31ATSCh. 1.12 - Prob. 10LTSCh. 1.12 - Prob. 32PTSCh. 1.12 - Prob. 33ATSCh. 1 - Prob. 34PPCh. 1 - Prob. 35PPCh. 1 - Prob. 36PPCh. 1 - Prob. 37PPCh. 1 - Prob. 38PPCh. 1 - Prob. 39PPCh. 1 - Prob. 40PPCh. 1 - Prob. 41PPCh. 1 - Prob. 42PPCh. 1 - Prob. 43PPCh. 1 - Prob. 44PPCh. 1 - Prob. 45PPCh. 1 - Prob. 46PPCh. 1 - Prob. 47PPCh. 1 - Prob. 48PPCh. 1 - Prob. 49PPCh. 1 - Prob. 50PPCh. 1 - Prob. 51PPCh. 1 - Prob. 52PPCh. 1 - Prob. 53PPCh. 1 - Prob. 54PPCh. 1 - Prob. 55PPCh. 1 - Prob. 56PPCh. 1 - Prob. 57PPCh. 1 - Prob. 58PPCh. 1 - Prob. 59PPCh. 1 - Prob. 60PPCh. 1 - Prob. 61PPCh. 1 - Prob. 62PPCh. 1 - Prob. 63IPCh. 1 - Prob. 67IPCh. 1 - Prob. 68IPCh. 1 - Prob. 69IPCh. 1 - Prob. 70CPCh. 1 - Prob. 71CPCh. 1 - Prob. 72CPCh. 1 - Prob. 73CPCh. 1 - Prob. 74CPCh. 1 - Prob. 75CPCh. 1 - Prob. 76CPCh. 1 - Prob. 77CP
Knowledge Booster
Similar questions
- A 20.3 mL sample of 0.263 M triethylamine, (C2H5)3N, is titrated with 0.252 M hydrochloric acid. (1) At the titration midpoint, the pH is . (2) At the equivalence point, the pH is .arrow_forwardd. 3,4,5-trimethoxybenzoyl chloride . What is the order of decreasing reactivity towards nucleophilic acyl substitution for the arboxylic acid derivatives? (most reactive first) A. B. 0 0 O 0 0 H3C-C-O-C-CH3 H3C-C-N(CH3)2 H3C-C-OCH 3 (CH3)2CH-C-OCH3 I || ။ IV a. I, II, III, IV b. I, III, IV, II C. II, IV, III, I d. II, I, III, IV 0 0 0 0 0 R-C-O C-R R-C-NH2 R-C OR R-C-CI a. I, III, II, IV | 11 III IV b. II, III, I, IV c. III, II, I, IV d. IV, I, III, IIarrow_forwardB. d. a hydrate 4. Give the major organic product(s) for each of the following reactions or sequences of reactions. Show all relevant stereochemistry [4 ONLY]. A. CH₂OH PCC CH2Cl2 0 H KCN HCN 2arrow_forward
- Propose a synthesis of the anti-inflammatory drug Ibuprofen from benzene. Show all reagents and all intermediate structures. Assume that ortho and para isomers can be separated. (CH3)2CHCH2 CH3 CHCOOH 1buprofen be requiredarrow_forwardAssuming that no equilibria other than dissolution are involved, calculate the molar solubility of each of the following from its solubility product: (a) KHC4H4O6arrow_forwardAnswer the following by equation 1. reactio of CH3MgBr with Acetone [CH3COCH3] 2. acetal formation reaction of acetaldehyde [CH3CHO] 3. preparation of ethylmethylether [C2H5OCH3] 4. the acidity of the carboxylic acid depends and affected by the substitutions on the rest of the acid molecule: draw 2 structures of acids to show the different effects on acidity by different subsarrow_forward
- Consider the reaction sequence below to answer the following questions: 0 0 0 0 0 1. NaOEt, EtOH H3O* OEt OET 2 PhCH Br heat Ph + EtOH + CO₂ CHh B C A A. The starting material A in this reaction sequence is called a a. ẞ-keto ester b. a-carboethoxy ketone C. malonic ester d. acetoacetic ester B. Conversion of A into B is a type of reaction termed a. an acylation b. an enolation C. d. an alkylation a phenylation f reactionsarrow_forward1. Refer to the compounds below to answer the following questions: CO₂Et 0 C. H O O₂N-CH2-C-CH3 0 OEt || 111 A. Indicate all the acidic hydrogens in Compounds I through IV. IV B. Indicate which hydrogens in Compound II are the most acidic. Explain your answer C. Choose the most acidic compound from Compounds I - IV. Explain your choice.arrow_forwardShow how you would accomplish the following transformations. More than one step may be required. ow all reagents and all intermediate structures [one ONLY] A. H Br H CH3 NHz CH3 CH3 B. CH3CH2C-Br CH3CH2C-CN CH3 CH3.arrow_forward
- Show how you would accomplish the following transformations. More than one step may be required. now all reagents and all intermediate structures [one ONLY] A. H Br H CH3 NHz CH3 CH3 B. CH3CH2C-Br CH3 CH3CH2C-CN CH3arrow_forwardCan I please get help with this?arrow_forwardC. I, II, III Consider the reaction sequence below to answer the following questions: 0 0 1. NaOEt, EtOH ΕΙΟ OEt 2 Compound X CO₂Et NaOEt, EtOH CO₂Et Br Compound Y A Compound Z A. Compound X, diethyl propanedioate, is more commonly known as a. ethyl acetoacetate acetoacetic ester b. C. oxalic ester d. malonic ester B. Write the complete stepwise mechanism for the conversion of Compound X into Compound Y. Show all electron flow with arrows and draw all intermediate structures.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY