Introductory Chemistry: A Foundation
9th Edition
ISBN: 9781337399425
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 1, Problem 6QAP
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Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
respectively.
F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
have a reasonable yield of product.
NH2
Br
Br
Br
OH
Br
Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
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LL
F
C
D
OH
CI
LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
Page 3 of 5
Chapter 1 Solutions
Introductory Chemistry: A Foundation
Ch. 1.4 - What if everyone in the government used the...Ch. 1 - Discuss how a hypothesis can become a theory. Can...Ch. 1 - Make five qualitative and five quantitative...Ch. 1 - Prob. 3ALQCh. 1 - Differentiate between a “theory” and a “scientific...Ch. 1 - Describe three situations when you used the...Ch. 1 - Scientific models do not describe reality. They...Ch. 1 - Theories should inspire questions. Discuss a...Ch. 1 - Describe how you would set up an experiment to...Ch. 1 - If all scientists use the scientific method to try...
Ch. 1 - As stated in the text, there is no one scientific...Ch. 1 - In Section 1.3 the statement is made that it is...Ch. 1 - As part of a science project, you study traffic...Ch. 1 - Prob. 13ALQCh. 1 - Chemistry is an intimidating academic subject for...Ch. 1 - The first paragraphs in this chapter ask you if...Ch. 1 - This section presents several ways our day-to-day...Ch. 1 - The Chemistry in Focus segment titled Dr....Ch. 1 - This textbook provides a specific definition of...Ch. 1 - We use chemical reactions in our everyday lives,...Ch. 1 - Prob. 7QAPCh. 1 - Being a scientist is very much like being a...Ch. 1 - In science, what is the difference between a law...Ch. 1 - Observations may be either qualitative or...Ch. 1 - Prob. 11QAPCh. 1 - True or false? If a theory is disproven, then all...Ch. 1 - Although, in general, science has advanced our...Ch. 1 - Discuss several political, social, or personal...Ch. 1 - Although reviewing your lecture notes and reading...Ch. 1 - Why is the ability to solve problems important in...Ch. 1 - Students approaching the study of chemistry must...Ch. 1 - The ‘Chemistry in Focus” segmentChemistry: An...
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- Q10: (a) Propose a synthesis of C from A. (b) Propose a synthesis of C from B. Br Br ...\SCH 3 A B Carrow_forward9: Complete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d).arrow_forwardComplete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d).arrow_forward
- QUESTION 3: Provide the synthetic steps that convert the starting material into the product (no mechanism required). HO OH NH CH3 multiple steps 요요 H3Carrow_forwardQ6: Predict the effect of the changes given on the rate of the reaction below. CH3OH CH3Cl + NaOCH3 → CH3OCH3 + NaCl a) Change the substrate from CH3CI to CH31: b) Change the nucleophile from NaOCH 3 to NaSCH3: c) Change the substrate from CH3CI to (CH3)2CHCI: d) Change the solvent from CH3OH to DMSO.arrow_forwardQ3: Arrange each group of compounds from fastest SN2 reaction rate to slowest SN2 reaction rate. a) CI Cl فيكم H3C-Cl A B C D Br Br b) A B C Br H3C-Br Darrow_forward
- Q2: Group these solvents into either protic solvents or aprotic solvents. Acetonitrile (CH3CN), H₂O, Acetic acid (CH3COOH), Acetone (CH3COCH3), CH3CH2OH, DMSO (CH3SOCH3), DMF (HCON(CH3)2), CH3OHarrow_forwardSuppose the rate of evaporation in a hot, dry region is 1.76 meters per year, and the seawater there has a salinity of 35 ‰. Assuming a 93% yield, how much salt (NaCl) can be harvested each year from 1 km2 of solar evaporation ponds that use this seawater as a source?arrow_forwardhelparrow_forward
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