Chemistry: The Molecular Nature of Matter
7th Edition
ISBN: 9781118516461
Author: Neil D. Jespersen, Alison Hyslop
Publisher: WILEY
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Textbook Question
Chapter 1, Problem 47RQ
The temperature of the core of the sun is estimated to be about 15.7 million K. What is this temperature in
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 1 Solutions
Chemistry: The Molecular Nature of Matter
Ch. 1 - Practice Exercise 1.1
What is the process of the...Ch. 1 - Practice Exercise 1.2
Classify the following as an...Ch. 1 - Practice Exercise 1.3
Each of the following can be...Ch. 1 - Practice Exercise 1.4
Each of these properties can...Ch. 1 - Prob. 5PECh. 1 - Prob. 6PECh. 1 - What is 355CinF? (Hint: What tool relates these...Ch. 1 - Convert 55F to its Celsius temperature. What...Ch. 1 - Prob. 9PECh. 1 - Perform the following calculations involving...
Ch. 1 - Practice Exercise 1.11
Use dimensional analysis to...Ch. 1 - Use dimensional analysis to perform the following...Ch. 1 - A 15.0 mL sample of polystyrene used in insulated...Ch. 1 - Practice Exercise 1.14
A crystal of salt was grown...Ch. 1 - A gold-colored metal object has a mass of 365 g...Ch. 1 - Practice Exercise 1.16
A certain metal alloy has a...Ch. 1 - Practice Exercise 1.17
Table wines have a minimum...Ch. 1 - Practice Exercise 1.18
Diabetes can cause a...Ch. 1 - After some thought, give two reasons why a course...Ch. 1 - What steps are involved in the scientific method?Ch. 1 - Prob. 3RQCh. 1 - Can a theory be proved to be correct? Can a theory...Ch. 1 - 1.5 Define matter. Which are examples of matter?...Ch. 1 - Define (a) element, (b) compound, (c) mixture, (d)...Ch. 1 - 1.7 Which kind of change, chemical or physical, is...Ch. 1 - Prob. 8RQCh. 1 - 1.9 What is the name of each of the following...Ch. 1 - For each of the following molecular pictures,...Ch. 1 - 1.11 Consider the following four samples of...Ch. 1 - 1.12 What is a physical change? What is a chemical...Ch. 1 - 1.13 “A sample of calcium (an electrically...Ch. 1 - 1.14 In places like Saudi Arabia, freshwater is...Ch. 1 - How does a chemical property differ from a...Ch. 1 - Distinguish between an extensive and an intensive...Ch. 1 - Determine whether each of the following is an...Ch. 1 - Describe one or more physical properties of each...Ch. 1 - Why must measurements always be written with a...Ch. 1 - What is the only SI base unit that includes a...Ch. 1 - Which SI units are mainly used in chemistry?Ch. 1 - What are derived units? Give two examples of...Ch. 1 - What is the meaning of each of the following...Ch. 1 - What reference points do we use in calibrating the...Ch. 1 - In each pair, which is larger: (a) A Fahrenheit...Ch. 1 - 1.26 Define the term significant figures.
Ch. 1 - Explain how to round numbers.Ch. 1 - What is the difference between accuracy and...Ch. 1 - 1.29 Suppose a length had been reported to be...Ch. 1 - What is the difference between the treatment of...Ch. 1 - When constructing a conversion factor between two...Ch. 1 - Suppose someone suggested using the fraction 3...Ch. 1 - In 1 hour there are 3600 seconds. By what...Ch. 1 - If you were to convert the measured length 4.165...Ch. 1 - 1.35 Write the equation that defines density....Ch. 1 - Compare density and specific gravity. What is the...Ch. 1 - 1.37 Give four sets of units for density. What...Ch. 1 - 1.38 Silver has a density of . Express this as an...Ch. 1 - Determine whether each of the following is a...Ch. 1 - 1.40 Determine whether each of the following is a...Ch. 1 - At room temperature, what is the state of each of...Ch. 1 - At room temperature, determine the appropriate...Ch. 1 - What number should replace the question mark in...Ch. 1 - 1.44 What numbers should replace the question...Ch. 1 - Perform the following conversions. (a) 57CtoF (b)...Ch. 1 - Perform the following conversions. (a) 98FtoC (b)...Ch. 1 - The temperature of the core of the sun is...Ch. 1 - Natural gas is mostly methane, a substance that...Ch. 1 - A healthy dog has a temperature ranging from...Ch. 1 - Prob. 50RQCh. 1 - The length of a wire was measured using two...Ch. 1 - What are the temperatures being measured in the...Ch. 1 - 1.53 How many significant figures do the following...Ch. 1 - How many significant figures do the following...Ch. 1 - 1.55 Perform the following arithmetic and round...Ch. 1 - 1.56 Perform the following arithmetic and round...Ch. 1 - Which are exact numbers and which ones have a...Ch. 1 - Prob. 58RQCh. 1 - 1.59 Perform the following conversions.
Ch. 1 - 1.60 Perform the following conversions.
Ch. 1 - 1.61 Perform the following conversions. If...Ch. 1 - 1.62 Perform the following conversions. If...Ch. 1 - 1.63 Perform the following conversions....Ch. 1 - Prob. 64RQCh. 1 - The human stomach can expand to hold up to 4.2...Ch. 1 - In the movie Cool Hand Luke (1967), Luke wagers...Ch. 1 - 1.67 The winds in a hurricane can reach almost 200...Ch. 1 - 1.68 A bullet is fired at a speed of 2435 ft/s....Ch. 1 - 1.69 A bullet leaving the muzzle of a pistol was...Ch. 1 - 1.70 On average, water flows over Niagara Falls at...Ch. 1 - Prob. 71RQCh. 1 - *1.72 One degree of latitude on the earth’s...Ch. 1 - Calculate the density of kerosene, in g/mL, if its...Ch. 1 - Calculate the density of magnesium, in g/cm3, if...Ch. 1 - Acetone, the solvent in some nail polish removers,...Ch. 1 - A glass apparatus contains 26.223 g of water when...Ch. 1 - 1.77 Chloroform, a chemical once used as an...Ch. 1 - Gasolines density is about 0.65 g/mL. How much...Ch. 1 - Prob. 79RQCh. 1 - Prob. 80RQCh. 1 - The space shuttle uses liquid hydrogen as its...Ch. 1 - Prob. 82RQCh. 1 - 1.83 Some time ago, a U.S. citizen traveling in...Ch. 1 - Driving to work one day, one of the authors of...Ch. 1 - Prob. 85RQCh. 1 - Prob. 86RQCh. 1 - Prob. 87RQCh. 1 - A pycnometer is a glass apparatus used for...Ch. 1 - 1.89 Radio waves travel at the speed of light, ....Ch. 1 - Prob. 90RQCh. 1 - Prob. 91RQCh. 1 - Aerogel or solid smoke" is a novel material that...Ch. 1 - A liquid known to be either ethanol (ethyl...Ch. 1 - An unknown liquid was found to have a density of...Ch. 1 - 1.95 There exists a single temperature at which...Ch. 1 - In the text, the Kelvin scale of temperature is...Ch. 1 - Density measurements can be used to analyze...Ch. 1 - An artist's statue has a surface area of 14.6ft2....Ch. 1 - What is the volume in cubic millimeters of a 3.54...Ch. 1 - 1.100 A solution is defined as a uniform mixture...Ch. 1 - How do you know that Coca-Cola is not a compound?...Ch. 1 - Find two or more web sites that give the values...Ch. 1 - 1.103 Reference books such as the Handbook of...Ch. 1 - A student used a 250 mL graduated cylinder having...Ch. 1 - Prob. 105RQCh. 1 - Gold has a density of 19.31gcm-3. How many grams...Ch. 1 - A Boeing 747 jet airliner carrying 568 people...Ch. 1 - *1.108 Download a table of data for the density of...Ch. 1 - List the physical and chemical properties...Ch. 1 - Prob. 110RQ
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- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
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