Chemistry: The Molecular Nature of Matter
7th Edition
ISBN: 9781118516461
Author: Neil D. Jespersen, Alison Hyslop
Publisher: WILEY
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Chapter 1, Problem 21RQ
Which SI units are mainly used in chemistry?
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When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.
When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.
Which experimental number must be initialled by the Lab TA for the first run of Part 1 of the experiment?
a) the heat capacity of the calorimeter
b) Mass of sample
c) Ti
d) The molarity of the HCl
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Chapter 1 Solutions
Chemistry: The Molecular Nature of Matter
Ch. 1 - Practice Exercise 1.1
What is the process of the...Ch. 1 - Practice Exercise 1.2
Classify the following as an...Ch. 1 - Practice Exercise 1.3
Each of the following can be...Ch. 1 - Practice Exercise 1.4
Each of these properties can...Ch. 1 - Prob. 5PECh. 1 - Prob. 6PECh. 1 - What is 355CinF? (Hint: What tool relates these...Ch. 1 - Convert 55F to its Celsius temperature. What...Ch. 1 - Prob. 9PECh. 1 - Perform the following calculations involving...
Ch. 1 - Practice Exercise 1.11
Use dimensional analysis to...Ch. 1 - Use dimensional analysis to perform the following...Ch. 1 - A 15.0 mL sample of polystyrene used in insulated...Ch. 1 - Practice Exercise 1.14
A crystal of salt was grown...Ch. 1 - A gold-colored metal object has a mass of 365 g...Ch. 1 - Practice Exercise 1.16
A certain metal alloy has a...Ch. 1 - Practice Exercise 1.17
Table wines have a minimum...Ch. 1 - Practice Exercise 1.18
Diabetes can cause a...Ch. 1 - After some thought, give two reasons why a course...Ch. 1 - What steps are involved in the scientific method?Ch. 1 - Prob. 3RQCh. 1 - Can a theory be proved to be correct? Can a theory...Ch. 1 - 1.5 Define matter. Which are examples of matter?...Ch. 1 - Define (a) element, (b) compound, (c) mixture, (d)...Ch. 1 - 1.7 Which kind of change, chemical or physical, is...Ch. 1 - Prob. 8RQCh. 1 - 1.9 What is the name of each of the following...Ch. 1 - For each of the following molecular pictures,...Ch. 1 - 1.11 Consider the following four samples of...Ch. 1 - 1.12 What is a physical change? What is a chemical...Ch. 1 - 1.13 “A sample of calcium (an electrically...Ch. 1 - 1.14 In places like Saudi Arabia, freshwater is...Ch. 1 - How does a chemical property differ from a...Ch. 1 - Distinguish between an extensive and an intensive...Ch. 1 - Determine whether each of the following is an...Ch. 1 - Describe one or more physical properties of each...Ch. 1 - Why must measurements always be written with a...Ch. 1 - What is the only SI base unit that includes a...Ch. 1 - Which SI units are mainly used in chemistry?Ch. 1 - What are derived units? Give two examples of...Ch. 1 - What is the meaning of each of the following...Ch. 1 - What reference points do we use in calibrating the...Ch. 1 - In each pair, which is larger: (a) A Fahrenheit...Ch. 1 - 1.26 Define the term significant figures.
Ch. 1 - Explain how to round numbers.Ch. 1 - What is the difference between accuracy and...Ch. 1 - 1.29 Suppose a length had been reported to be...Ch. 1 - What is the difference between the treatment of...Ch. 1 - When constructing a conversion factor between two...Ch. 1 - Suppose someone suggested using the fraction 3...Ch. 1 - In 1 hour there are 3600 seconds. By what...Ch. 1 - If you were to convert the measured length 4.165...Ch. 1 - 1.35 Write the equation that defines density....Ch. 1 - Compare density and specific gravity. What is the...Ch. 1 - 1.37 Give four sets of units for density. What...Ch. 1 - 1.38 Silver has a density of . Express this as an...Ch. 1 - Determine whether each of the following is a...Ch. 1 - 1.40 Determine whether each of the following is a...Ch. 1 - At room temperature, what is the state of each of...Ch. 1 - At room temperature, determine the appropriate...Ch. 1 - What number should replace the question mark in...Ch. 1 - 1.44 What numbers should replace the question...Ch. 1 - Perform the following conversions. (a) 57CtoF (b)...Ch. 1 - Perform the following conversions. (a) 98FtoC (b)...Ch. 1 - The temperature of the core of the sun is...Ch. 1 - Natural gas is mostly methane, a substance that...Ch. 1 - A healthy dog has a temperature ranging from...Ch. 1 - Prob. 50RQCh. 1 - The length of a wire was measured using two...Ch. 1 - What are the temperatures being measured in the...Ch. 1 - 1.53 How many significant figures do the following...Ch. 1 - How many significant figures do the following...Ch. 1 - 1.55 Perform the following arithmetic and round...Ch. 1 - 1.56 Perform the following arithmetic and round...Ch. 1 - Which are exact numbers and which ones have a...Ch. 1 - Prob. 58RQCh. 1 - 1.59 Perform the following conversions.
Ch. 1 - 1.60 Perform the following conversions.
Ch. 1 - 1.61 Perform the following conversions. If...Ch. 1 - 1.62 Perform the following conversions. If...Ch. 1 - 1.63 Perform the following conversions....Ch. 1 - Prob. 64RQCh. 1 - The human stomach can expand to hold up to 4.2...Ch. 1 - In the movie Cool Hand Luke (1967), Luke wagers...Ch. 1 - 1.67 The winds in a hurricane can reach almost 200...Ch. 1 - 1.68 A bullet is fired at a speed of 2435 ft/s....Ch. 1 - 1.69 A bullet leaving the muzzle of a pistol was...Ch. 1 - 1.70 On average, water flows over Niagara Falls at...Ch. 1 - Prob. 71RQCh. 1 - *1.72 One degree of latitude on the earth’s...Ch. 1 - Calculate the density of kerosene, in g/mL, if its...Ch. 1 - Calculate the density of magnesium, in g/cm3, if...Ch. 1 - Acetone, the solvent in some nail polish removers,...Ch. 1 - A glass apparatus contains 26.223 g of water when...Ch. 1 - 1.77 Chloroform, a chemical once used as an...Ch. 1 - Gasolines density is about 0.65 g/mL. How much...Ch. 1 - Prob. 79RQCh. 1 - Prob. 80RQCh. 1 - The space shuttle uses liquid hydrogen as its...Ch. 1 - Prob. 82RQCh. 1 - 1.83 Some time ago, a U.S. citizen traveling in...Ch. 1 - Driving to work one day, one of the authors of...Ch. 1 - Prob. 85RQCh. 1 - Prob. 86RQCh. 1 - Prob. 87RQCh. 1 - A pycnometer is a glass apparatus used for...Ch. 1 - 1.89 Radio waves travel at the speed of light, ....Ch. 1 - Prob. 90RQCh. 1 - Prob. 91RQCh. 1 - Aerogel or solid smoke" is a novel material that...Ch. 1 - A liquid known to be either ethanol (ethyl...Ch. 1 - An unknown liquid was found to have a density of...Ch. 1 - 1.95 There exists a single temperature at which...Ch. 1 - In the text, the Kelvin scale of temperature is...Ch. 1 - Density measurements can be used to analyze...Ch. 1 - An artist's statue has a surface area of 14.6ft2....Ch. 1 - What is the volume in cubic millimeters of a 3.54...Ch. 1 - 1.100 A solution is defined as a uniform mixture...Ch. 1 - How do you know that Coca-Cola is not a compound?...Ch. 1 - Find two or more web sites that give the values...Ch. 1 - 1.103 Reference books such as the Handbook of...Ch. 1 - A student used a 250 mL graduated cylinder having...Ch. 1 - Prob. 105RQCh. 1 - Gold has a density of 19.31gcm-3. How many grams...Ch. 1 - A Boeing 747 jet airliner carrying 568 people...Ch. 1 - *1.108 Download a table of data for the density of...Ch. 1 - List the physical and chemical properties...Ch. 1 - Prob. 110RQ
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- When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.arrow_forwardQ6: Using acetic acid as the acid, write the balanced chemical equation for the protonation of the two bases shown (on the -NH2). Include curved arrows to show the mechanism. O₂N- O₂N. -NH2 -NH2 a) Which of the two Bronsted bases above is the stronger base? Why? b) Identify the conjugate acids and conjugate bases for the reactants. c) Identify the Lewis acids and bases in the reactions.arrow_forwardQ5: For the two reactions below: a) Use curved electron-pushing arrows to show the mechanism for the reaction in the forward direction. Redraw the compounds to explicitly illustrate all bonds that are broken and all bonds that are formed. b) Label Bronsted acids and bases in the left side of the reactions. c) For reaction A, which anionic species is the weakest base? Which neutral compound is the stronger acid? Is the forward or reverse reaction favored? d) Label Lewis acids and bases, nucleophiles and electrophiles in the left side of the reactions. A. 용 CH3OH я хон CH3O OH B. HBr CH3ONa NaBr CH3OHarrow_forward
- potential energy Br b) Translate the Newman projection below to its wedge-and-dash drawing. F H. OH CH3 CI c) Isopentane (2-methylbutane) is a compound containing a branched carbon chain. Draw a Newman projection of six conformations about the C2-C3 bond of isopentane. On the curve of potential energy versus angle of internal rotation for isopentane, label each energy maximum and minimum with one of the conformations. 0° 。 F A B D C angle of internal rotation E F 360° (=0°) JDownlarrow_forwardQ7: Identify the functional groups in these molecules a) CH 3 b) Aspirin: HO 'N' Capsaicin HO O CH3 CH 3arrow_forwardQ2: Name the following alkanesarrow_forward
- 1. Complete the following table in your laboratory notebook. Substance Formula Methanol CH3OH Ethanol C2H5OH 1-Propanol C3H7OH 1-Butanol C4H9OH Pentane C5H12 Hexane C6H14 Water H₂O Acetone C3H60 Structural Formula Molecular Weight (g/mol) Hydrogen Bond (Yes or No)arrow_forwardQ1: Compare the relative acidity in each pair of compounds. Briefly explain. (a) CH3OH vs NH 3 (b) HF vs CH3COOH (c) NH3 vs CH4 (d) HCI vs HI (e) CH3COOH vs CH3SH (f) H₂C=CH2 vs CH3 CH3 (g) compare the acidity of the two bolded hydrogens O. H N- (h) compare the acidity of the two bolded hydrogens, draw resonance structures to explain H H Harrow_forwardQ3: Rank the following molecules in order of decreasing boiling point: (a) 3-methylheptane; (b) octane; (c) 2,4-dimethylhexane; (d) 2,2,4-trimethylpentane.arrow_forward
- Q5: Conformations of Alkanes a) Draw a Newman Projection of the compound below about the C2-C3 bond. H3C Cli... H IIIH Br CH3arrow_forwardThe ability of atoms to associate with each other depends ona) the electronic structure and its spatial orientation.b) the electron affinity.c) The other two answers are correct.arrow_forwardWhat is the final volume after you reach the final temperature? I put 1.73 but the answer is wrong not sure why The initial volume of gas is 1.60 LL , the initial temperature of the gas is 23.0 °C°C , and the system is in equilibrium with an external pressure of 1.2 bar (given by the sum of a 1 bar atmospheric pressure and a 0.2 bar pressure due to a brick that rests on top of the piston). Then, as you did in Exercise 1, you heat the gas slowly until the temperature reaches 48.2 °Carrow_forward
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