PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
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Textbook Question
Chapter 1, Problem 1.9E
hat difference is necessary for heat to flow between two systems? Can you think of an exception to your answer?
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5. A buffer consists of 0.45 M NH, and 0.25 M NH-CI (PK of NH 474) Calculate the pH of the butter. Ans: 9.52
BAS
PH-9.26 +10g (10.95))
14-4.59
PH=4.52
6. To 500 ml of the buffer on #5 a 0.20 g of sample of NaOH was added
a Write the net ionic equation for the reaction which occurs
b. Should the pH of the solution increase or decrease sightly?
Calculate the pH of the buffer after the addition Ans: 9.54
Explain the inductive effect (+I and -I) in benzene derivatives.
The inductive effect (+I and -I) in benzene derivatives, does it guide ortho, meta or para?
Chapter 1 Solutions
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
Ch. 1 - A bomb calorimeter is a study metal vessel in...Ch. 1 - Difference between the system and the...Ch. 1 - Prob. 1.3ECh. 1 - Prob. 1.4ECh. 1 - Prob. 1.5ECh. 1 - Prob. 1.6ECh. 1 - Prob. 1.7ECh. 1 - A pot of cold water is heated on a stove, and when...Ch. 1 - hat difference is necessary for heat to flow...Ch. 1 - What is the value of FT for a sample of gas whose...
Ch. 1 - What is the value of FP for a sample of gas whose...Ch. 1 - Prob. 1.12ECh. 1 - Hydrogen gas is used in weather balloon because it...Ch. 1 - Prob. 1.14ECh. 1 - A 2.0 L soda bottle is pressurized with 4.5 atm of...Ch. 1 - The Mount Pinatubo volcano eruption in 1991...Ch. 1 - Prob. 1.17ECh. 1 - Scottish physicist W. J. M. Rankine proposed an...Ch. 1 - Use the two appropriate values of R to determine a...Ch. 1 - Prob. 1.20ECh. 1 - Pressures of gases in mixtures are referred to as...Ch. 1 - Earths atmosphere is approximately 80 N2 and 20...Ch. 1 - The atmospheric surface pressure on Venus is 90...Ch. 1 - Prob. 1.24ECh. 1 - Prob. 1.25ECh. 1 - In the anaerobic oxidation of glucose by yeast,...Ch. 1 - What are the slopes of the following lines at the...Ch. 1 - For the following function, evaluate the...Ch. 1 - Determine the expressions for the following,...Ch. 1 - Determine the expressions for the following,...Ch. 1 - Prob. 1.31ECh. 1 - Prob. 1.32ECh. 1 - Prob. 1.33ECh. 1 - Prob. 1.34ECh. 1 - What properties of a nonideal gas do the Vander...Ch. 1 - Prob. 1.36ECh. 1 - Prob. 1.37ECh. 1 - Calculate the Boyle temperatures for carbon...Ch. 1 - Prob. 1.39ECh. 1 - Prob. 1.40ECh. 1 - Table 1.4 show that the second virial coefficient...Ch. 1 - Prob. 1.42ECh. 1 - What is the van der Waals constant a for Ne in...Ch. 1 - Prob. 1.44ECh. 1 - Under what conditions would the van der Waals...Ch. 1 - By definition, the compressibility of an ideal gas...Ch. 1 - The second virial coefficient B and the third...Ch. 1 - Use the approximation 1 x-1 1 x x2 to...Ch. 1 - Why is nitrogen a good choice for the study of...Ch. 1 - Evaluate for a gas following the Redlich-Kwong...Ch. 1 - Numerically evaluate for one mole of methane...Ch. 1 - Under what conditions of volume does a van der...Ch. 1 - At high temperatures, one of the van der Waals...Ch. 1 - Under what conditions of temperature does a...Ch. 1 - The Berthelot equation of state for one mole of...Ch. 1 - Prob. 1.56ECh. 1 - Referring to exercises 1.6 and 1.7, does it matter...Ch. 1 - Prob. 1.58ECh. 1 - Use Figure 1.11 to construct the cyclic rule...Ch. 1 - Prob. 1.60ECh. 1 - Prob. 1.61ECh. 1 - Calculate for one mole of an ideal gas at STP and...Ch. 1 - Prob. 1.63ECh. 1 - Show that = T/p for an ideal gas.Ch. 1 - Determine an expression for V/T p, n in terms of ...Ch. 1 - Prob. 1.66ECh. 1 - Prob. 1.67ECh. 1 - Perform a units analysis on the exponent of the...Ch. 1 - Using the barometric formula, calculate the...Ch. 1 - The barometric formula can also be used for...Ch. 1 - Prob. 1.71ECh. 1 - Prob. 1.72ECh. 1 - Prob. 1.73ECh. 1 - Prob. 1.74ECh. 1 - Prob. 1.75ECh. 1 - Prob. 1.76ECh. 1 - Prob. 1.77ECh. 1 - Prob. 1.78ECh. 1 - Prob. 1.79ECh. 1 - Use the ideal gas law to symbolically prove the...Ch. 1 - Prob. 1.81E
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- 19.57 Using one of the reactions in this chapter, give the correct starting material (A-L) needed to produce each structure (a-f). Name the type of reaction used. (b) ہ مرد (d) HO (c) དང་ ་་ཡིན་ད་དང་ (f) HO Br B D of oli H J Br K C 人 ↑arrow_forwardInductive effect (+I and -I) in benzene derivatives.arrow_forward7. Helparrow_forward
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