PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
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Chapter 1, Problem 1.19E
Use the two appropriate values of R to determine a conversion between L. atm and J.
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3.5
Complete the following sentences to make correct scientific meaning.
3.5.1 The entropy of a perfect gas.
3.5.2
when it expands isothermally.
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3.5.3
temperature is calculated from its
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3.4
Consider the internal energy of a substance
3.4.1
Draw a graph showing the variation of internal energy with temperature at constant volume
3.4.2
Write the mathematical expression for the slope in your graph in 3.4.1
For a system, the excited state decays to the ground state with a half-life of 15 ns, emitting radiation of 6000 Å. Determine the Einstein coefficients for stimulated absorption and spontaneous emission and the dipole moment of the transition. Data: epsilon 0 = 8.85419x10-12 C2m-1J-1
Chapter 1 Solutions
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
Ch. 1 - A bomb calorimeter is a study metal vessel in...Ch. 1 - Difference between the system and the...Ch. 1 - Prob. 1.3ECh. 1 - Prob. 1.4ECh. 1 - Prob. 1.5ECh. 1 - Prob. 1.6ECh. 1 - Prob. 1.7ECh. 1 - A pot of cold water is heated on a stove, and when...Ch. 1 - hat difference is necessary for heat to flow...Ch. 1 - What is the value of FT for a sample of gas whose...
Ch. 1 - What is the value of FP for a sample of gas whose...Ch. 1 - Prob. 1.12ECh. 1 - Hydrogen gas is used in weather balloon because it...Ch. 1 - Prob. 1.14ECh. 1 - A 2.0 L soda bottle is pressurized with 4.5 atm of...Ch. 1 - The Mount Pinatubo volcano eruption in 1991...Ch. 1 - Prob. 1.17ECh. 1 - Scottish physicist W. J. M. Rankine proposed an...Ch. 1 - Use the two appropriate values of R to determine a...Ch. 1 - Prob. 1.20ECh. 1 - Pressures of gases in mixtures are referred to as...Ch. 1 - Earths atmosphere is approximately 80 N2 and 20...Ch. 1 - The atmospheric surface pressure on Venus is 90...Ch. 1 - Prob. 1.24ECh. 1 - Prob. 1.25ECh. 1 - In the anaerobic oxidation of glucose by yeast,...Ch. 1 - What are the slopes of the following lines at the...Ch. 1 - For the following function, evaluate the...Ch. 1 - Determine the expressions for the following,...Ch. 1 - Determine the expressions for the following,...Ch. 1 - Prob. 1.31ECh. 1 - Prob. 1.32ECh. 1 - Prob. 1.33ECh. 1 - Prob. 1.34ECh. 1 - What properties of a nonideal gas do the Vander...Ch. 1 - Prob. 1.36ECh. 1 - Prob. 1.37ECh. 1 - Calculate the Boyle temperatures for carbon...Ch. 1 - Prob. 1.39ECh. 1 - Prob. 1.40ECh. 1 - Table 1.4 show that the second virial coefficient...Ch. 1 - Prob. 1.42ECh. 1 - What is the van der Waals constant a for Ne in...Ch. 1 - Prob. 1.44ECh. 1 - Under what conditions would the van der Waals...Ch. 1 - By definition, the compressibility of an ideal gas...Ch. 1 - The second virial coefficient B and the third...Ch. 1 - Use the approximation 1 x-1 1 x x2 to...Ch. 1 - Why is nitrogen a good choice for the study of...Ch. 1 - Evaluate for a gas following the Redlich-Kwong...Ch. 1 - Numerically evaluate for one mole of methane...Ch. 1 - Under what conditions of volume does a van der...Ch. 1 - At high temperatures, one of the van der Waals...Ch. 1 - Under what conditions of temperature does a...Ch. 1 - The Berthelot equation of state for one mole of...Ch. 1 - Prob. 1.56ECh. 1 - Referring to exercises 1.6 and 1.7, does it matter...Ch. 1 - Prob. 1.58ECh. 1 - Use Figure 1.11 to construct the cyclic rule...Ch. 1 - Prob. 1.60ECh. 1 - Prob. 1.61ECh. 1 - Calculate for one mole of an ideal gas at STP and...Ch. 1 - Prob. 1.63ECh. 1 - Show that = T/p for an ideal gas.Ch. 1 - Determine an expression for V/T p, n in terms of ...Ch. 1 - Prob. 1.66ECh. 1 - Prob. 1.67ECh. 1 - Perform a units analysis on the exponent of the...Ch. 1 - Using the barometric formula, calculate the...Ch. 1 - The barometric formula can also be used for...Ch. 1 - Prob. 1.71ECh. 1 - Prob. 1.72ECh. 1 - Prob. 1.73ECh. 1 - Prob. 1.74ECh. 1 - Prob. 1.75ECh. 1 - Prob. 1.76ECh. 1 - Prob. 1.77ECh. 1 - Prob. 1.78ECh. 1 - Prob. 1.79ECh. 1 - Use the ideal gas law to symbolically prove the...Ch. 1 - Prob. 1.81E
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- Problem a. The following compounds have the same molecular formula as benzene. How many monobrominated products could each form? 1. HC =CC=CCH2CH3 2. CH2=CHC = CCH=CH₂ b. How many dibrominated products could each of the preceding compounds form? (Do not include stereoisomers.)arrow_forwardDon't used Ai solutionarrow_forward4.3 Explain the following terms: 4.3.1 Normal boiling point. 4.3.2 Cooling curve. 4.3.3 Congruent melting. 4.3.4 Ideal solution. 4.3.5 Phase diagram of a pure substance.arrow_forward
- For CO, an electronic transition occurs at 2x1015 Hz. If the dipole moment of the transition is of the order of 1 Debye, calculate:a) The Einstein coefficient of stimulated emissionb) The lifetime of the excited statec) The natural width (in Hz)Data: epsilon 0 = 8.85419x10-12 C2m-1J-1; 1 D = 3.33564x10-30 C m;arrow_forwardA radiation of intensity l0 = 2.5x1010 photos s-1 cm2 affects a dispersion and produces a transmittance of 0.1122. How much incident radiation is absorbed by the music screen?arrow_forwardIf a radiation intensity l0 = 2.5x1010 fotones s-1 cm2 causes a dissolución and an absorbance of 0.95 will be recorded. How much incident radiation is absorbed by the music screen?arrow_forward
- From the causes of the detection of a spectral band of a spectrum obtained by a signal in the gaseous phase that is indicated, you can avoid or minimize those that have their origin in:a) the Doppler effectb) collisionsc) the life time of the excited statearrow_forwarda) Why is it possible that all types of atoms occupy the fundamental energy level?b) What should be the value of the participation function so that it occurs?c) keep in mind that the translational levels of a system are very close, which must be the condition that tenga lugar el condensado de átomos en el fundamental level?arrow_forwardAt the polar moment of Rnm transition, you can confirm thata) nunca can be ser 0b) is a very important magnitude in Raman spectroscopyc) is related to the probability of spectroscopic transactionsd) is related to the selection rulesarrow_forward
- In Fourier transformed spectroscopya) use a very sensitive monocromador systemb) the detection time is inferior to conventional spectroscopiac) the signal is detected depending on the frequencyd) occurs simultaneously at all frequency intervalsarrow_forwardIf a radiation intensity l0 = 2.5x1010 fotones s-1cm2 results in a dissolución, an absorption of 0.95 will be recorded. What is the percentage of incident radiation and transmission?a) 88.88% b) 5% c) 11.22% d) 95%arrow_forwardIndicate the spectroscopic transmission that requires greater energy radiation. Justification:a) NMR b) vibration c) electronica d) rotationarrow_forward
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