α for one mole of an ideal gas at STP and SATP is to be calculated. Concept introduction: Generally, gaseous systems are used to study the thermodynamic properties since, the gaseous systems are well behaved. Intriguingly, the change in the state variables, when a certain state variable is changed can be determined. Thus, the gaseous systems are important in analyzing thermodynamic properties. In this regard, a few partial derivatives can be considered as basic properties of the gas. The two important partial derivatives of having significant interest are; 1) expansion coefficient of a gas ( α) 2) isothermal compressibility ( κ ) of a gas. Since, temperature and pressure of gas varies from location to location a standard reference is important for comparing the analyzing and the documentation of chemical and physical processes. There is a variety of notations for standard reference conditions of temperature and pressure such as STP and SATP.

Question

Part 1. Draw monomer units of the following products and draw their reaction mechanism 1) Bakelite like polymer Using: Resorcinol + NaOH + Formalin 2) Polyester fiber Using a) pthalic anhydride + anhydrous sodium acetate + ethylene glycol B)pthalic anhydride + anhydrous sodium acetate + glycerol 3) Temporary cross-linked polymer Using: 4% polyvinyl alcohol+ methyl red + 4% sodium borate

Answer 1

Question

Chapter 1, Problem 1.61E

Interpretation Introduction

Interpretation:

α for one mole of an ideal gas at STP and SATP is to be calculated.

Concept introduction:

Generally, gaseous systems are used to study the thermodynamic properties since, the gaseous systems are well behaved. Intriguingly, the change in the state variables, when a certain state variable is changed can be determined. Thus, the gaseous systems are important in analyzing thermodynamic properties. In this regard, a few partial derivatives can be considered as basic properties of the gas. The two important partial derivatives of having significant interest are; 1) expansion coefficient of a gas (α) 2) isothermal compressibility (κ) of a gas. Since, temperature and pressure of gas varies from location to location a standard reference is important for comparing the analyzing and the documentation of chemical and physical processes. There is a variety of notations for standard reference conditions of temperature and pressure such as STP and SATP.

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