
Physical Chemistry
2nd Edition
ISBN: 9781285969770
Author: Ball
Publisher: Cengage
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Chapter 1, Problem 1.25E
Interpretation Introduction
Interpretation:
In the reaction between hydrochloric acid and magnesium
100.0 g of HCl(aq) is reacted. The volume of H2 is produced if the temperature is 47.5 °C and the pressure is 1.02 atm is to be calculated. Assume the
Concept introduction:
The ideal gas law or general gas equation is the equation of state of a hypothetical ideal gas. Thought it has some limitations, it is a good approximation of the behavior of several gases under several conditions. The term was first coined by Emile Clapeyron in the year of 1834 as combination of other laws. The ideal gas law can be written as PV = nRT.
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Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
Check
CF3
(Choose one)
OH
(Choose one)
H
(Choose one)
(Choose one)
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Identifying electron-donating and electron-withdrawing effects
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Molecule
Inductive Effects
Resonance Effects
Overall Electron-Density
CF3
O donating
O donating
O electron-rich
O withdrawing
withdrawing
O no inductive effects
O no resonance effects
O electron-deficient
O similar to benzene
OCH3
Explanation
Check
O donating
O donating
○ withdrawing
withdrawing
O no inductive effects
no resonance effects
electron-rich
electron-deficient
O similar to benzene
Х
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The acid-base chemistry of both EDTA and EBT are important to ensuring that the reactions proceed as desired, thus the pH is controlled using a buffer. What percent of the EBT indicator will be in the desired HIn2- state at pH = 10.5. pKa1 = 6.2 and pKa2 = 11.6 of EBT
Chapter 1 Solutions
Physical Chemistry
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