(b)The reaction between H2O2 and lodide; H,0, + 21 + 2H*→2H,0 + 12Proceeds by two parallel mechanism and led to a rate laws,k, [H,0][I] and = k, [H,0][][#*]%3DdtdtThe change in observed rate constants with ionic strength for both themechanisms is given in the following table.k (M's)0.69k2 (M's')Sr. no.Ionic strength (1)19.00.000.02070.6615.030.05250.6712.040.09250.6811.30.690.15750.20259.70.719.2With the help of this data and corresponding plots, comment on whichmechanism between these two would follow Primary salt effect moreprominently.rhich tyne of complex mechanism T-jump

Bronsted-Bjerrum equation is given as: log k =log ko + 1.02 zAzB I1/2 k = rate constant at a an…

Answered: With the help of this data and…

With the help of this data and corresponding plots, comment on which mechanism between these two would follow Primary salt effect more prominently.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

(b)
The reaction between H2O2 and lodide; H,0, + 21 + 2H*→
2H,0 + 12
Proceeds by two parallel mechanism and led to a rate laws,
k, [H,0][I] and = k, [H,0][][#*]
%3D
dt
dt
The change in observed rate constants with ionic strength for both the
mechanisms is given in the following table.
k (M's)
0.69
k2 (M's')
Sr. no.
Ionic strength (1)
19.0
0.00
0.0207
0.66
15.0
3
0.0525
0.67
12.0
4
0.0925
0.68
11.3
0.69
0.1575
0.2025
9.7
0.71
9.2
With the help of this data and corresponding plots, comment on which
mechanism between these two would follow Primary salt effect more
prominently.
rhich tyne of complex mechanism T-jump

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