Please use the values in the resources listed below instead of the textbook values. The rate of the electron-exchange reaction between naphthalene (C10H8) and its anion radical (C10H8¬) in an organic solvent is diffusion controlled. C10H8¯ + C10H8 =C10H8 + C10H8¯ The reaction is bimolecular and second order. The rate constants are as follows. T/K 305 295 291 275 k/109 M-1.s-1 2.64 2.21 2.05 1.49 Calculate the values of Ea, AH°t, ASof and AGot at 295 K for the reaction. [Hint: Rearrange the equation below and plot In(k/T) versus 1/T.] KBT T easot/Re-AHot/RT(M1 – m) k = Ea = 2993.386 x kJ-mol-1 X kJ-mol-1 x J-K-1.mol-1 AH°† = 2991.1 ASo# = -28069.52 AG°† = 107010.2 X kJ•mol-1

Please use the values in the resources listed below instead of the textbook values. The rate of the electron-exchange reaction between naphthalene (C10H8) and its anion radical (C10H8¬) in an organic solvent is diffusion controlled. C10H8¯ + C10H8 =C10H8 + C10H8¯ The reaction is bimolecular and second order. The rate constants are as follows. T/K 305 295 291 275 k/109 M-1.s-1 2.64 2.21 2.05 1.49 Calculate the values of Ea, AH°t, ASof and AGot at 295 K for the reaction. [Hint: Rearrange the equation below and plot In(k/T) versus 1/T.] KBT T easot/Re-AHot/RT(M1 – m) k = Ea = 2993.386 x kJ-mol-1 X kJ-mol-1 x J-K-1.mol-1 AH°† = 2991.1 ASo# = -28069.52 AG°† = 107010.2 X kJ•mol-1

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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