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The table below gives some spectroscopic constants (in cm³¹) for the OH radical in its two lowest electronic states X 2II A 2Σ+ V(Re) 0 32682 < 3735.2 3180.6 √ Xe 82.81 94.93 B 18.87 17.36 (b) Predict the wavenumber of the vibrational overtone transition (v=2v=0) in the ground electronic state (X ²П). (c) Predict the wavenumber of the electronic transition A 2Σ* (v=5, J=5) ← X ²П (v=1, J=5).

The table below gives some spectroscopic constants (in cm³¹) for the OH radical in its two lowest electronic states X 2II A 2Σ+ V(Re) 0 32682 < 3735.2 3180.6 √ Xe 82.81 94.93 B 18.87 17.36 (b) Predict the wavenumber of the vibrational overtone transition (v=2v=0) in the ground electronic state (X ²П). (c) Predict the wavenumber of the electronic transition A 2Σ* (v=5, J=5) ← X ²П (v=1, J=5).

Physical Chemistry
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter15: Introduction To Electronic Spectroscopy And Structure
Section: Chapter Questions
Problem 15.58E
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The table below gives some spectroscopic constants (in cm³¹) for the OH radical in its two lowest electronic states X 2II A 2Σ+ V(Re) 0 32682 < 3735.2 3180.6 √ Xe 82.81 94.93 B 18.87 17.36 (b) Predict the wavenumber of the vibrational overtone transition (v=2v=0) in the ground electronic state (X ²П). (c) Predict the wavenumber of the electronic transition A 2Σ* (v=5, J=5) ← X ²П (v=1, J=5).
Transcribed Image Text:The table below gives some spectroscopic constants (in cm³¹) for the OH radical in its two lowest electronic states X 2II A 2Σ+ V(Re) 0 32682 < 3735.2 3180.6 √ Xe 82.81 94.93 B 18.87 17.36 (b) Predict the wavenumber of the vibrational overtone transition (v=2v=0) in the ground electronic state (X ²П). (c) Predict the wavenumber of the electronic transition A 2Σ* (v=5, J=5) ← X ²П (v=1, J=5).
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