5.30 The average enthalpy change of vaporization of benzene between room temperature and the normal boiling temperature is 34.085 kJ mol-1. The vapor pressure at 26.1°C is 100.0 torr. a. Find the normal boiling temperature. Compare with the correct value, 80.1°C. State any assumptions. b. Find the entropy change of vaporization at the normal boiling temperature. Compare with the prediction of Trouton's rule. State any assumptions.
5.30 The average enthalpy change of vaporization of benzene between room temperature and the normal boiling temperature is 34.085 kJ mol-1. The vapor pressure at 26.1°C is 100.0 torr. a. Find the normal boiling temperature. Compare with the correct value, 80.1°C. State any assumptions. b. Find the entropy change of vaporization at the normal boiling temperature. Compare with the prediction of Trouton's rule. State any assumptions.
Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter18: Principles Of Chemical Reactivity: Entropy And Free Energy
Section18.2: Dispersal Of Energy: Entropy
Problem 1RC: In a spontaneous process, S(universe) is (a) 0 (b) = 0 (c) 0
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Transcribed Image Text:5.30 The average enthalpy change of vaporization of benzene
between room temperature and the normal boiling
temperature is 34.085 kJ mol-1. The vapor pressure at
26.1°C is 100.0 torr.
a. Find the normal boiling temperature. Compare with the
correct value, 80.1°C. State any assumptions.
b. Find the entropy change of vaporization at the normal
boiling temperature. Compare with the prediction of
Trouton's rule. State any assumptions.
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