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The formation of nitroanaline (an important intermediate in dyes) is formed from the reaction of orthonitrochlorobenzene (ONCB) and aqueous ammonia with ammonium chloride as a by-product. NO CI NO NH, + 2NH, + NH,CL ONCB Nitroanaline Let the reaction be represented symbolically as A+ 2B →C + D The reaction occurs in the liquid phase and is first order in both ONCB and ammonia with k = 0.0017 m /kmol.min at 461K with E 11273 cal/mol. The initial entering concentrations of A (ONCB) and B (ammonia) are 1.8 kmol/m and 6.6 kmol/m², respectively. a. Set up a stoichiometric table for this reaction for a flow system b. Write the rate law for the disappearance of ONCB, -rA solely as a function of conversion X c. What is the rate of reaction, -rA when X = 0.9 at i. 461 K ii. 561 K

The formation of nitroanaline (an important intermediate in dyes) is formed from the reaction of orthonitrochlorobenzene (ONCB) and aqueous ammonia with ammonium chloride as a by-product. NO CI NO NH, + 2NH, + NH,CL ONCB Nitroanaline Let the reaction be represented symbolically as A+ 2B →C + D The reaction occurs in the liquid phase and is first order in both ONCB and ammonia with k = 0.0017 m /kmol.min at 461K with E 11273 cal/mol. The initial entering concentrations of A (ONCB) and B (ammonia) are 1.8 kmol/m and 6.6 kmol/m², respectively. a. Set up a stoichiometric table for this reaction for a flow system b. Write the rate law for the disappearance of ONCB, -rA solely as a function of conversion X c. What is the rate of reaction, -rA when X = 0.9 at i. 461 K ii. 561 K

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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The formation of nitroanaline (an important intermediate in dyes) is formed from the reaction of orthonitrochlorobenzene (ONCB) and aqueous ammonia with ammonium chloride as a by-product. NO CI NO NH, + 2NH, + NH,CL ONCB Nitroanaline Let the reaction be represented symbolically as A+ 2B →C + D The reaction occurs in the liquid phase and is first order in both ONCB and ammonia with k = 0.0017 m /kmol.min at 461K with E 11273 cal/mol. The initial entering concentrations of A (ONCB) and B (ammonia) are 1.8 kmol/m and 6.6 kmol/m², respectively. a. Set up a stoichiometric table for this reaction for a flow system b. Write the rate law for the disappearance of ONCB, -rA solely as a function of conversion X c. What is the rate of reaction, -rA when X = 0.9 at i. 461 K ii. 561 K
Transcribed Image Text:The formation of nitroanaline (an important intermediate in dyes) is formed from the reaction of orthonitrochlorobenzene (ONCB) and aqueous ammonia with ammonium chloride as a by-product. NO CI NO NH, + 2NH, + NH,CL ONCB Nitroanaline Let the reaction be represented symbolically as A+ 2B →C + D The reaction occurs in the liquid phase and is first order in both ONCB and ammonia with k = 0.0017 m /kmol.min at 461K with E 11273 cal/mol. The initial entering concentrations of A (ONCB) and B (ammonia) are 1.8 kmol/m and 6.6 kmol/m², respectively. a. Set up a stoichiometric table for this reaction for a flow system b. Write the rate law for the disappearance of ONCB, -rA solely as a function of conversion X c. What is the rate of reaction, -rA when X = 0.9 at i. 461 K ii. 561 K
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