Hydrodealkylation is a process in which side chain alkyl groups (like methyl) are removed from aromatics by reaction with hydrogen. The following reactions take place in the reactor: CH₂CH₂ + H₂¹CH₁ + CH4 C6H4(CH3)2 + H₂ C6H₂CH₂ + CH4 C6H3(CH3)3 + H2C6H4(CH3)2 + CH4 In addition, an unwanted side reaction occurs, in which benzene dimerizes to form diphenyl [C6H5C6H5] 2 CH CH₂CH₂ + H₂ A process stream containing 5 mol % benzene [CH], 20 mol% toluene [C6H-CH3], 35 mol% xylene [C6H4 (CH3)2], and 40 mol% pseudocumene [C6H₂(CH3)3] is fed to a hydrodealkylation plant. This process stream is mixed with hydrogen gas in 5:1 gas-aromatics ratio before being fed to the reactor. A condenser separates hydrogen and methane from the other reactor products (lumped as aromatics). Feed ?B ???? BTXP ?T ? X ?P Reactor Hydrogen Gas ? H₂ →>> a. How many moles are in the feed stream? Light Gases ? ?M Condenser Aromatics ?B ????? BTXPD ?T ?X ?P ?D

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Chapter1: Introduction
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Hydrodealkylation is a process in which side chain alkyl groups (like methyl) are removed from aromatics
by reaction with hydrogen. The following reactions take place in the reactor:
C6H5CH3 + CH4
C6H3 (CH3)3 + H₂C6H4(CH3)2 + CH4
In addition, an unwanted side reaction occurs, in which benzene dimerizes to form diphenyl [C6H5C6H5]
Feed
2 C6H6C6H5C6H₂ + H₂
A process stream containing 5 mol% benzene [CH], 20 mol % toluene [CH₂CH3], 35 mol% xylene
[C6H4 (CH3)2], and 40 mol % pseudocumene [C6H3 (CH3)3] is fed to a hydrodealkylation plant. This
process stream is mixed with hydrogen gas in 5:1 gas-aromatics ratio before being fed to the reactor. A
condenser separates hydrogen and methane from the other reactor products (lumped as aromatics).
BTXP
E1
C6H₂CH3 + H₂C6H6 + CH4
?B
?T
? X
E2
C6H4(CH3)2 + H₂
?P
Reactor
Hydrogen Gas
? H₂
a. How many moles are in the feed stream?
Light Gases
? H₂
?M
Condenser
Aromatics
?B
?T
? X
?P
?D
BTXPD
Transcribed Image Text:Hydrodealkylation is a process in which side chain alkyl groups (like methyl) are removed from aromatics by reaction with hydrogen. The following reactions take place in the reactor: C6H5CH3 + CH4 C6H3 (CH3)3 + H₂C6H4(CH3)2 + CH4 In addition, an unwanted side reaction occurs, in which benzene dimerizes to form diphenyl [C6H5C6H5] Feed 2 C6H6C6H5C6H₂ + H₂ A process stream containing 5 mol% benzene [CH], 20 mol % toluene [CH₂CH3], 35 mol% xylene [C6H4 (CH3)2], and 40 mol % pseudocumene [C6H3 (CH3)3] is fed to a hydrodealkylation plant. This process stream is mixed with hydrogen gas in 5:1 gas-aromatics ratio before being fed to the reactor. A condenser separates hydrogen and methane from the other reactor products (lumped as aromatics). BTXP E1 C6H₂CH3 + H₂C6H6 + CH4 ?B ?T ? X E2 C6H4(CH3)2 + H₂ ?P Reactor Hydrogen Gas ? H₂ a. How many moles are in the feed stream? Light Gases ? H₂ ?M Condenser Aromatics ?B ?T ? X ?P ?D BTXPD
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