i. Determine the mass (in g) of 1 m3 ethylene glycol at 1150 K and 70 bar. Use the Nelson-Obert generalized compressibility chart. Answer in 2 decimal places.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Hydrodealkylation is a process in which side chain alkyl groups (like methyl) are removed from aromatics
by reaction with hydrogen. The following reactions take place in the reactor:
In addition, an unwanted side reaction occurs, in which benzene dimerizes to form diphenyl [C6H5C6H5]
E4
2 C6H6C6H5C6H5 + H₂
A process stream containing 5 mol % benzene [CH], 20 mol% toluene [CH₂CH3], 35 mol% xylene
[C6H4 (CH3)₂], and 40 mol% pseudocumene [CH₂(CH3)3] is fed to a hydrodealkylation plant. This
process stream is mixed with hydrogen gas in 5:1 gas-aromatics ratio before being fed to the reactor. A
condenser separates hydrogen and methane from the other reactor products (lumped as aromatics).
Feed
?B
?T
? X
?P
E1
C6H₂CH3 + H₂C6H6 + CH4
C6H4(CH3)2 + H₂C6H5CH3 + CH4
E3
C6H3(CH3)3 + H₂C6H4(CH3)2 + CH4
BTXP
Reactor
Hydrogen Gas
? H₂
Light Gases
? H₂
?M
Condenser
Aromatics
?B
?T
? X
?P
?D
i. Determine the mass (in g) of 1 m3 ethylene glycol at 1150 K and 70 bar. Use the Nelson-Obert
generalized compressibility chart. Answer in 2 decimal places.
Transcribed Image Text:Hydrodealkylation is a process in which side chain alkyl groups (like methyl) are removed from aromatics by reaction with hydrogen. The following reactions take place in the reactor: In addition, an unwanted side reaction occurs, in which benzene dimerizes to form diphenyl [C6H5C6H5] E4 2 C6H6C6H5C6H5 + H₂ A process stream containing 5 mol % benzene [CH], 20 mol% toluene [CH₂CH3], 35 mol% xylene [C6H4 (CH3)₂], and 40 mol% pseudocumene [CH₂(CH3)3] is fed to a hydrodealkylation plant. This process stream is mixed with hydrogen gas in 5:1 gas-aromatics ratio before being fed to the reactor. A condenser separates hydrogen and methane from the other reactor products (lumped as aromatics). Feed ?B ?T ? X ?P E1 C6H₂CH3 + H₂C6H6 + CH4 C6H4(CH3)2 + H₂C6H5CH3 + CH4 E3 C6H3(CH3)3 + H₂C6H4(CH3)2 + CH4 BTXP Reactor Hydrogen Gas ? H₂ Light Gases ? H₂ ?M Condenser Aromatics ?B ?T ? X ?P ?D i. Determine the mass (in g) of 1 m3 ethylene glycol at 1150 K and 70 bar. Use the Nelson-Obert generalized compressibility chart. Answer in 2 decimal places.
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