[Sucrose] (mol/L) Time (h) 0.501 0.00 0.451 0.50 0.404 1.00 0.363 1.50 0.267 3.00

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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The acid-catalyzed hydrolysis of sucrose occurs by the fol-lowing overall reaction whose kinetic data are given below:C₁₂H₂₂O₁₁(s)  H₂O(l) →C₆H₁₂O₆(aq)  C₆H₁₂O₆(aq) (a) Determine the rate constant and the half-life of the reaction.(b) How long does it take to hydrolyze 75% of the sucrose?(c) Other studies have shown that this reaction is actually sec-ond order overall but appears to follow first-order kinetics.(Such a reaction is called a pseudo–first-order reaction.) Sug-gest a reason for this apparent first-order behavior.

[Sucrose] (mol/L)
Time (h)
0.501
0.00
0.451
0.50
0.404
1.00
0.363
1.50
0.267
3.00
Transcribed Image Text:[Sucrose] (mol/L) Time (h) 0.501 0.00 0.451 0.50 0.404 1.00 0.363 1.50 0.267 3.00
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