Suppose the decomposition of ozone proceeds by the following mechanism: step elementary reaction rate constant 1 O3(9) → O,(9) + O(g) 2 03(9) + O(g) → 2O2(g) k2 Suppose also k,»k,. That is, the first step is much faster than the second. Write the balanced chemical equation for the overall chemical reaction: D-0 Write the experimentally- observable rate law for the overall chemical reaction. rate = k|| Note: your answer should not contain the concentrations of any intermediates.

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Writing the rate law implied by a simple mechanism
Suppose the decomposition of ozone proceeds by the following mechanism:
step elementary reaction
rate constant
1
O3(9) → O2(g) + O(g)
k1
2 03(9) + O(g) → 20,(g)
Suppose also k,»k,. That is, the first step is much faster than the second.
Write the balanced
chemical equation for the
overall chemical reaction:
Write the experimentally-
observable rate law for the
?
overall chemical reaction.
rate = k]
Note: your answer should
not contain the
concentrations of any
intermediates.
Express the rate constant
k for the overall chemical
reaction in terms of k1, k2,
and (if necessary) the rate
constants k.1 and k.2 for
k = 1
the reverse of the two
elementary reactions in
the mechanism.
Transcribed Image Text:0/5 Writing the rate law implied by a simple mechanism Suppose the decomposition of ozone proceeds by the following mechanism: step elementary reaction rate constant 1 O3(9) → O2(g) + O(g) k1 2 03(9) + O(g) → 20,(g) Suppose also k,»k,. That is, the first step is much faster than the second. Write the balanced chemical equation for the overall chemical reaction: Write the experimentally- observable rate law for the ? overall chemical reaction. rate = k] Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of k1, k2, and (if necessary) the rate constants k.1 and k.2 for k = 1 the reverse of the two elementary reactions in the mechanism.
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