¹₂(g) + ICl(g) → HI(g) + HCl(g) HI(g)+ ICI(g) 1₂(g) + HCl(g) Suppose also k₁«k₂. That is, the first step is much slower than the second. 2 4 Write the balanced chemical equation for the overall chemical reaction: Write the experimentally- observable rate law for the overall chemical reaction. Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of k₁, k₂, and (if necessary) the rate constants k.₁ and k-2 for the reverse of the two elementary reactions in the mechanism. k0 rate = k k₁ k = 0 k₂

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O KINETICS AND EQUILIBRIUM
Writing the rate law implied by a simple mechanism
H₂(g) + ICI(g) -
1
HI(g) + HCl(g)
k₁
2 HI(g) + ICl(g) 1₂(g) + HCl(g)
k₂
Suppose also k₁«k₂. That is, the first step is much slower than the second.
Write the balanced
chemical equation for the
overall chemical reaction:
Write the experimentally-
observable rate law for the
overall chemical reaction.
Note: your answer should
not contain the
concentrations of any
intermediates.
Express the rate constant
k for the overall chemical
reaction in terms of k₁, K₂,
and (if necessary) the rate
constants k.₁ and k-2 for
the reverse of the two
elementary reactions in
the mechanism.
Explanation
Check
rate = k0
= 0
k =
JUL
16
L
tv
W
MacBook Air
ローロ
00
X
0-
© 2023 McGraw Hill LLC. All Rights Reserved.
Terms of
70
Transcribed Image Text:O KINETICS AND EQUILIBRIUM Writing the rate law implied by a simple mechanism H₂(g) + ICI(g) - 1 HI(g) + HCl(g) k₁ 2 HI(g) + ICl(g) 1₂(g) + HCl(g) k₂ Suppose also k₁«k₂. That is, the first step is much slower than the second. Write the balanced chemical equation for the overall chemical reaction: Write the experimentally- observable rate law for the overall chemical reaction. Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of k₁, K₂, and (if necessary) the rate constants k.₁ and k-2 for the reverse of the two elementary reactions in the mechanism. Explanation Check rate = k0 = 0 k = JUL 16 L tv W MacBook Air ローロ 00 X 0- © 2023 McGraw Hill LLC. All Rights Reserved. Terms of 70
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