Step 1) 2) 3) 4) 5) 6) CI-CI hv CH₂ + Cl CH3 + CI-CI ci + CH3 CH3 + CH3 ci + ci 2 CI* of the mechanism steps shown is the rate-determining step for the chlorination of methane. CH3 + HCI CH3Cl + Ci CH3CI CH3CH3 CI-CI

Step 1) 2) 3) 4) 5) 6) CI-CI hv CH₂ + Cl CH3 + CI-CI ci + CH3 CH3 + CH3 ci + ci 2 CI* of the mechanism steps shown is the rate-determining step for the chlorination of methane. CH3 + HCI CH3Cl + Ci CH3CI CH3CH3 CI-CI

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter13: Substitution

Section: Chapter Questions

Problem 43CTQ

See similar textbooks

Related questions

Q: In a hydrocarbon solution, the gold compound (CH3)3AUPH3 decomposes into ethane (C2H6) and a…

Q: What is the mechanism for the reaction below? Sketch a transition state of the rate-determining…

A: The question is based on organic reactions. We need to identify the product and explain its…

Q: The following Reaction Mechanism is used: A+B+C --> D+E (slow) D+F --> B+X (fast)…

A: Correct option is (e). e) A+C+F --> E+X

Q: Draw the mechanism and the energetic profile for the following reaction: Br CH,CH,OH a) HC D

Q: The following sequence shows a suggested mechanism for a reaction: Step 1: NO₂ (9) + Cl₂ (9) NO₂Cl…

A: The following sequence shows a suggested mechanism for a reaction:Step 1: NO2 (g)+Cl2 (g)…

Q: Analyze a mechanism, including molecularities; write a net reaction; and identify any catalysts or…

A: Answer: Molecularity is related to step of the reaction while order of reaction is the power of…

Q: The three step mechanism for the following reaction can be seen below…

A: We have to predict the rate of reaction.

Q: For the reaction mechanism shown, identify the intermedlate(S). A) Cl(g) Clb(g) = 20(g) B) CI,(g)…

A: Reaction mechanism:- Cl2 <--------> 2Cl CHCl3(g) + Cl(g) <-------> HCl(g) + CCl3(g)…

Q: 7. Tert-butyl alcohol reacts with aqueous hydrochloric acid to give tert-butyl chloride as shown…

Q: Nitryl chloride (NO2CI) decomposes to nitrogen dioxide (NO₂) and chlorine gas (Cl₂) according to the…

Q: what is a chemical equation that is similar to the bromination of acetone in terms of the rate law

Q: A reaction is found to have a change in enthalpy of -8.67 kJ/mol and a change in entropy of 29.87…

Q: Tertiary butyl chloride reacts in basic solution according to the equaqtion (CH3)3CCl + OH- →…

Q: H3C-C-CH3 + Br2 = H3C-C-CH2B1 + Br + H* %3D K OH %3D H3C-C-CH3 + H* = [H3C-C-CH3]* A OH OH k1…

Q: What is the catalyst for this mechanism

Q: 11. Consider the reaction mechanism/s involved in each of the following cases: III CI ~ KOH, heat…

A: "Dear student, as an expert we are only allowed to answer one quesstion at a time and 4 subpart at a…

Q: The mechanism for the reaction of CH3OH and HBr is believed to involve two steps. The overall…

A: (a) An equation for the overall reaction is obtained by adding given two steps. Step-1 Fast Step-2…

Q: C,H¬Br + OH¯→ C,H¬OH + NaBr The rate equation for the hydrolysis of C3H,Br with sodium hydroxide is:…

Q: The conversion of acetyl chloride to methyl acetate occurs via the following two-step mechanism: :0:…

A: The rate equation of a chemical reaction is the relationship between the rate of the reaction and…

Q: You react the following molecule with a strong bulky base (like KOtBu), and you know that the Br…

A: Answer:In elimination reaction, atoms or groups leave the molecule and without any addition of any…

Q: The following initial rate data was collected for the reaction: HI (g) + C₂H5l (g) --> C₂H6 (g) + 12…

Q: Biacetyl is stable at room temperature but decomposes by first order kinetics at temperatures above…

A: The problem is asking us to find out how long the food can last with 85.0% of the flavoring agent…

Q: 2. What is the rate of disappearance of KClO3 in the following reaction: 2 KCIO3(s) → 2 KCI(s) + 3…

A: The rate of the formation of the product or the rate of disappearance of the reactants is known as…

Q: The gas phase decomposition of dinitrogen pentoxide at 335 K N₂O5 (9)→ 2 NO2(g) + ½/2O₂(g) is first…

Q: Consider the reaction mechanism shown below. Derive an equation for the rate of production of…

Q: Me i) H2SO4, heat ii) NaOH N. Br

Q: O State what rate law you would expect from this mechanism (Rate = k[Acetone]"[H*]"[1₂]') o Compare…

A: The objective of the question is to determine the rate law from the given mechanism and compare it…

Q: 2X C-C FGI FGA `CN `CN `Cl Br Br 5 Blanc reaction CI CI CI

A: Blanc reaction is the addition of chloromethane to the benzene ring. NaCN is an oxidizing agent.…

Q: Progress of reaction Which of the following mechanisms is consistent with the reaction profile shown…

Q: 12) The catalytic hydrogenation of ethylene can occur by the following two-step mechanism: Step 1:…

A: Any chemical species which is formed during the reaction and gets exhausted completely during the…

Q: The decomposition of di-2-methylpropan-2-yl peroxide produces propanone and ethane: (CH3)3COOC(CH3)3…

A: Intermediates: a chemical species that is formed in one elementary step and consumed in a subsequent…

Q: Use the data provided below to determine the most accurate experimental rate law for the reaction:…

A: Given, The reaction mixture of acetone, H+ , and I2

Q: Compound A decomposes in the gas phase according to this mechanism in two stages:1. A + A ⇄ A* + A…

Q: The rearrangement of cyclopropane to propene at 500 °C is first order (k = 6.70x10-4s ¹). (CH₂)3(9)…

Q: Develop and explain the Reaction Mechanism:

A: ** This is the formation of tert- Butyl Chloride from tert- Butyl alcohol and HCl by SN1 mechanism.…

Q: The answers can be found at the end of the practice problem set, and full solutions can be discussed…

A: (1) Reaction is EtOH + H(+) + Cl- ======> EtCl + H20 EtOH2+ is the reaction intermediate Rate law…

Q: State the units of K corresponding to each of the rate equations below: Rate = K [NO]2 Rate = K…

A: Rate = K [ Concentration] K = Rate /[Concentration]

Q: 16. Step 1 Step 2 Step 3 Students in a SCH4U class were examining the reaction between…

Q: Write a balanced reaction for which the following rate relationships are true. Rate = 1 A[N₂1_4[0₂]…

A: Given -> Rate=1/2(∆[N2]/∆t)= ∆[O2]/∆t =-1/2(∆[N2O]/∆t)

Q: 16. Step 1 Step 2 Step 3 Students in a SCH4U class were examining the reaction between…

Q: How many transition states are there for the mechanism shown below? H20 H2O H20

A: The above mechanism shows the substitution of Cl by -OH group.

Q: What is the rate expression for this reaction? CH3-CH2-Br + CH3-NH2 polar aprotic solvent (A) rate =…

A: Given reaction: CH3CH2Br + CH3NH2 →polar aprotic solvent In order to find the rate expression for…

Q: Icyclopropane]/ [propene] / mol dm 3 Time / min mol dm 3 1.50 0.00 1.23 0.27 10 1.00 0.50 15 0.82…

A: A question based on kinetics of chemical reactions that is to be accomplished.

Q: a) The following are typical reactions of alkyl halides. In each case, draw the structure of the…

Q: A kinetics experiment measured the reaction between compound A and compound B and gave the following…

Q: HNO3 + H₂C(OH)2 → HNO2 + HCOOH + H₂O has a rate law: rate = k [H₂C(OH)₂] [HNO₂] Given a rate…

A: The objective of this question is to find how long will take for methanediol concentration to fall .

Question

Step
1)
2)
3)
4)
5)
6)
CI-CI
hv
CH₂ + Cl
CH3 + CI-CI
ci + CH3
CH3 + CH3
ci + ci
2 CI*
of the mechanism steps shown is the rate-determining step for the chlorination of methane.
CH3 + HCI
CH3Cl + Ci
CH3CI
CH3CH3
CI-CI

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1: Given question

VIEW

Step 2: Solution

VIEW

Solution

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 3 steps with 3 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Acetic anhydride reacts with water in the following manner: CH3C(O)-O-C(O)CH3 + H2O = 2CH3CO2 If this reaction is carried out in an inert solvent with low concentrations of both acetic anhydride and water, it follows the rate law rate = k [CH3C(O)-O-C(O)CH3] [H2O] with a rate constant of 0.0035 s-1. However, if low concentrations of acetic anhydride are placed in pure water, it follows the rate law rate = K [CH3C(O)-O-C(O)CH3] where K = 0.1944 s-1. Explain why this is happening.
The decomposition of di-2-methylpropan-2-yl peroxide produces propanone and ethane: (CH3)3COOC(CH3)3 → 2CH3COCH3 + C₂H6 and is described by the generally accepted mechanism: (CH3)3COOC(CH3)3 → 2 (CH3)3CO (CH3)3CO → CH3COCH3 + CH3* CH3 + CH3 →→ C₂H6 k₁ k₂ k3 1. Identify the intermediates. 2. Explain why this is NOT a chain reaction. 3. Confirm using the steady state approximation that the production of ethane is first order even though it takes place in a number of steps.
A mechanism that has been proposed for the conversion of 2-methylpropene to tert-butyl alcohol in acidic aqueous solution is: step 1 slow: (CH3)2C=CH2 + H+ --------> (CH3)3C+ step 2 fast: (CH3)3C+ + H2O ---------> (CH3)3COH + H+ (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. ____________ + __________ = _______________ + ______________ (2) Which species acts as a catalyst? Enter formula. If none, leave box blank: ____________ (3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank: ______________ (4) Complete the rate law for the overall reaction that is consistent with this mechanism. (Use the form k[A]m[B]n... , where '1' is understood (so don't write it) for m, n etc.) Rate = _______________
The following is a nucleophilic substitution reaction of S-3-chloro-2-methylhexane with "CN. The experimental rate law for this reaction is Rate k [S-3-chloro-2-methylhexane] CH3 H;C. C. C H. CH3 CEN H2 H. The mechanism for this reaction is SN1 Draw the orgamic molecule(s) which is(are) formed in this reaction. Do not include molecules like H,O or HCl. Draw the specific configuration (R or S) at any chiral carbons within your product(s). If both configurations are formed in the product(s), draw both as separate molecules/products.
1) What would the mechanism be for these reactions?
1. For the rearrangement of cyclopropane to propene at 500°C, the following data have been obtained: [(CH2)3], M (CH2), CH,CH=CH2 2.98 x10- 5.55 x10-2 1.60 x10- 8.56x10-3 time, min 15.5 31.0 46.5 What is the rate of disappearance of (CH2); over the time period from 0 to 15.5 minutes? 1. a. 0.00166 M/min b. 0.00127 M/min 0.00101 M/min d. 0.000890 M/min e. 0.000480 M/min C.
The rate of elimination of cis-1-bromo-4(1,1-dimethyl)cyclohexane is proportional to the concentration of both substrate and base, but that of the trans isomer is proportional only to the concentration of the substrate. a) draw the structures of cis and trans 1-bromo-4(1,1,-dimethyl)cyclohexane b) explain the difference in kinetics between the elimination reaction of cis and trans isomers.
d) During the reaction between 3, 3-dimethylbutene (W) and HBr, intermediate species and Y are formed. CH3 CH;-C-CH=CH2 ČH3 HBr Y step 1 step 2 step 3 i) Write a mechanism for the formation of intermediate X? ii) Write the structure of intermediate Y? iii) Explain in your own words what happens in step 2 of the reaction? iv) Write a mechanism for the formation of Z from Y?
Chloromethane reacts with dilute sodium cyanide (Na+ -C‚N) chloromethane cyanide acetonitrile chloride. When the concentration of chloromethane is doubled, the rate is observed to double. When the concentration of cyanide ion is tripled, the rate is observed to triple. Write the rate equation for this reaction.
The rate of hydration of 2-butene and 2-methylpropene differ by several orders of magnitude. Whcih alkene is more rapidly hydrated and why?
5. Bromoethane, CH3CH2Br, reacts with sodium hydroxide in an elimination reaction to form ethene.(i) Outline a mechanism for this elimination reaction.(ii) Suggest one reason why this method for making ethene is not used in industry.....................................................................................................................................................................................................................................................(4)
6. a) Write the reaction mechanism between 2-chloro-2-methylbutane with water CH,CH(CH,)CHCICH3 + H20 > CH3COH(CH3)CH2CH3 i) Name the type of reaction for this mechanism.