Write the rate law. Find the rate constant

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The bromination of aceton is acid –catalyzed.

 CH3COCH3     +      Br  + H+   --------->      CH3COCH2Br  +  2H+  + Br-

 

                               The rate of disappearance of bromine was measured for several different concentrations of acetone, bromine, and H+ ion at a certain temperature.

 

           

                      A                                B               C                               

     [ CH3COCH3]    

               [Br2]

 [ H+]

Rate of disapperance

              [ Br2]

0.30

0.050

0.050

5.7 x 10 -5

0.30

0.10

0.050

5.7 x 10 –5

0.30

0.050

0.10

1.2 x 10 -4

0.40

0.050

0.20

3.1 x 10 -4

 

 

  • Write the rate law.
  • Find the rate constant.
  • Determine the half-life of the reaction if the [A]o = 0.50M ;  [B]o = 0.40 M;  [C]o = 0.6 M. ( Half-life is based on over all order of the reacaction)

 

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