The following initial rate data are for the reaction of tertiary butyl bromide with hydroxide ion at 55 °C: (CH3)3CB + OH → (CH3)3COH + Br Experiment [(CH3)3CB1],, M [OH], M Initial Rate, Ms-1 1 0.890 1.50x10-3 1.50x10-3 3.01x10-3 3.01x10-3 0.118 0.118 2 1.78 0.890 1.78 3 0.237 4 0.237 Complete the rate law for this reaction in the box below. Use the form k[A]j™[B]" , where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n Rate = From these data, the rate constant is

Chemistry & Chemical Reactivity
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Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section: Chapter Questions
Problem 90IL: The acid-catalyzed iodination of acetone CH3COCH3(aq) + I2(aq) CH3COCH2I(aq) + HI(aq) is a common...
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The following initial rate data are for the reaction of tertiary butyl bromide with hydroxide
ion at 55 °C:
(CH3)3CB + OH → (CH3)3COH + Br
Experiment
[(CH3)3CB1],, M [OH], M
Initial Rate, Ms-1
1
0.890
1.50x10-3
1.50x10-3
3.01x10-3
3.01x10-3
0.118
0.118
2
1.78
0.890
1.78
3
0.237
4
0.237
Complete the rate law for this reaction in the box below.
Use the form k[A]j™[B]" , where '1' is understood for m or n and concentrations taken to the
zero power do not appear. Don't enter 1 for m or n
Rate =
From these data, the rate constant is
Transcribed Image Text:The following initial rate data are for the reaction of tertiary butyl bromide with hydroxide ion at 55 °C: (CH3)3CB + OH → (CH3)3COH + Br Experiment [(CH3)3CB1],, M [OH], M Initial Rate, Ms-1 1 0.890 1.50x10-3 1.50x10-3 3.01x10-3 3.01x10-3 0.118 0.118 2 1.78 0.890 1.78 3 0.237 4 0.237 Complete the rate law for this reaction in the box below. Use the form k[A]j™[B]" , where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n Rate = From these data, the rate constant is
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