a) Sketch the energy diagram for the conversion of tertiary butyl bromide to methyl t-butyl ether. Note that this is a two step reaction with the t-butyl cation as an intermediate. Assume that this is overall an exothermic reaction. Show the location of both transition states and the intermediate. The first step has the higher energy of activation and is the rate determining step. (CH3)3C-Br ------> (CH3)3C+ + Br- (CH3)3C+ + H3CO- ------> (CH3)3C-O-CH3 (b)Draw the curved arrow mechanism and the transition state when the tertiary butyl carbocation reacts with the methoxide ion to give an ether. (CH3)3C+ + H3CO- ------> (CH3)3C-O-CH3

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
a) Sketch the energy diagram for the conversion of tertiary butyl bromide to methyl t-butyl ether. Note that this is a two step reaction with the t-butyl cation as an intermediate. Assume that this is overall an exothermic reaction. Show the location of both transition states and the intermediate. The first step has the higher energy of activation and is the rate determining step. (CH3)3C-Br ------> (CH3)3C+ + Br- (CH3)3C+ + H3CO- ------> (CH3)3C-O-CH3 (b)Draw the curved arrow mechanism and the transition state when the tertiary butyl carbocation reacts with the methoxide ion to give an ether. (CH3)3C+ + H3CO- ------> (CH3)3C-O-CH3
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 1 images

Blurred answer
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY