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- Draw the most stable conformation of 1,4-dichlorobutane, using wedges and dashes to represent bonds coming out of the paper and going behind the paper, respectively.4. Isomers and Stereocenters ( (a) Assign each set of molecules as constitutional isomers, conformational isomers, enantiomers, diastereomers, or identical. Please write the full name for the type. Molecules Type (b) H₂Ca HgC.. CH3 OCH₂ CH3 af OCH, SP H₂C**** H₂C H₂C NGOCH, H.C_OCKS OCH₂ CH₂ H₁C HC H*** CI H H CI Br H3C CH₂ Br (d) E) (0) For each of the following molecules, write the number of stereocenters and circle the center of any stereocenters. (i) (ii) H₂C (онт (eg 5) (b) -CH3 Isegna CH3 on mots eno H₂C CH3Draw the two-dimensional representation that corresponds to the chair conformation provided in Figure 1. H. ÇI CH3 ČHĄCH3
- Which of the following is the staggered conformation for rotation about the C1- C2 bond in the following structure? HyCH;C H. CH H3C. H,C H. H,C H,CH C. Hwhich is most stable conformation int Et Me * H H Me H A. "iPr It' H HA Et Me H B. CH₂ ile Hips H- H с H ilrQ5: Classify the following pair of molecules as constitutional isomers, enantiomers, diastereomers, the same molecule, or completely different molecules. Br O CI Br OH OH 111 Br .!!!/Br F OH and ...m Br Br OH CI Br OH ་་་་་" ། ་
- dDetermine the # of chiral centers. Determine the most stable chair conformation then indicate which are equatorial and which are axial.d Copy the following structures into your notebook and determine the absolute configuration of each chiral center: H3CH₂C F Cl H H MIC1 CH3 ||| BI H₂CH₂C H H I ||||| CH₂CH₂CH3 "III COOH H OH OH
- What chair structure corresponds to the highest energy conformation of trans-1,4-dichlorocyclohexane (shown on left)? CI CI CI CI CI CI CI .CI CI A C D CI B O O O OGive the official name of the chiral compound including g notation of assymetric centersFill in the blank. Constitutional Isomer? Conformational Isomer? Enantiomer? Diastereomer?



