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Organic Chemistry: A Guided Inquiry

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter14: Elimination

Section: Chapter Questions

Problem 33E

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Draw the major product or the starting material of the following reactions. Where
appropriate indicate if the product resulted from SN2, SN1, E2, or E1 in the box provided. When
a racemic mixture is formed, you must draw both enantiomers and write "racemic" in the box.
A)
NaCl
DMSO
B)
C)
Br
H₂O
NaOH
H₂O
E2
D)
NaOH
E)
F)
Cl
CH3OH
H₂O
E2
t-BuOK
E2

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Draw the major product formed for each reaction. Assume the reactions are irreversible. Include stereochemistry when products contain stereocenter(s). (a) Draw only the substitution product. Both elimination and substitution occur here. H³C" Br CH3OH
Draw all possible products for the following reactions, including stereochemistry. If more than one product can be produced, indicate which would be the major product. а) c) NaOH (CH,CH,),CBr CH3 H3C, CH2CH3 CH,OH, A CH3OK CH3OH H3C CH2CH3 CI b) d) Br Br NaOEt CH30K CH3OH
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None
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