Q4. The acid base indicator HIn undergoes the following reaction in dilute aqueous solution 10 H+ + In HIn When a 5x10-4 M solution of HIn put in 0.1 M NaOH and in 0.1 M HCl, the following data were obtained. Note that all the indicator will be existing as HIn in 0.1 M HCl and existing as In in NaOH, Solution 0.1 M NaOH 0.1 M HCI A at 485 nm 0.052 0.454 A at 625 nm 0.823 0.176 Calculate a) The molar absorptivity of HIn and In" at 485 and 625 nm b) The acid dissociation constant (Ka) if a small amount of the indicator at pH 5 gave A = 0.472 at 485 nm and A = 0.351 at 625 nm.

Q4. The acid base indicator HIn undergoes the following reaction in dilute aqueous solution 10 H+ + In HIn When a 5x10-4 M solution of HIn put in 0.1 M NaOH and in 0.1 M HCl, the following data were obtained. Note that all the indicator will be existing as HIn in 0.1 M HCl and existing as In in NaOH, Solution 0.1 M NaOH 0.1 M HCI A at 485 nm 0.052 0.454 A at 625 nm 0.823 0.176 Calculate a) The molar absorptivity of HIn and In" at 485 and 625 nm b) The acid dissociation constant (Ka) if a small amount of the indicator at pH 5 gave A = 0.472 at 485 nm and A = 0.351 at 625 nm.

Introductory Chemistry: A Foundation

9th Edition

ISBN:9781337399425

Author:Steven S. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Donald J. DeCoste

Chapter16: Acids And Bases

Section: Chapter Questions

Problem 61QAP: . Which component of a buffered solution is capable of combining with an added strong acid? Using...

See similar textbooks

Similar questions

Sketch the titration curve for a weak acid titrated by a strong base. When performing calculations concerning weak acidstrong base titrations, the general two-slep procedure is to solve a stoichiometry problem first, then to solve an equilibrium problem to determine the pH. What reaction takes place in the stoichiometry part of the problem? What is assumed about this reaction? At the various points in your titration curve, list the major species present after the strong base (NaOH, for example) reacts to completion with the weak acid, HA. What equilibrium problem would you solve at the various points in your titration curve to calculate the pH? Why is pH 7.0 at the equivalence point of a weak acid-strong base titration? Does the pH at the halfway point to equivalence have to be less than 7.0? What does the pH at the halfway point equal? Compare and contrast the titration curves for a strong acidstrong base titration and a weak acidstrong base titration.
. How is the strength of an acid related to the fact that a competition for protons exists in aqueous solution between water molecules and the anion of the acid?
You have a solution of the weak acid HA and add some of the salt NaA to it. What are the major species in the solution? What do you need to know to calculate the pH of the solution, and how would you use this information? How does the pH of the solution of just the HA compare with that of the final mixture? Explain.
Write the Lewis structures of the reactants and product of each of the following equations, and identify the Lewis acid and the Lewis base in each: (a) CS2+SHHCS3 (b) BF3+FBF4 (c) I+SnI2SnI3 (d) Al(OH)3+OHAl(OH)4 (e) F+SO3SFO3
A 10.00-g sample of the ionic compound NaA, where A is the anion of a weak acid, was dissolved in enough water to make 100.0 mL of solution and was then titrated with 0.100 M HCl. After 500.0 mL HCl was added, the pH was 5.00. The experimenter found that 1.00 L of 0.100 M HCl was required to reach the stoichiometric point of the titration. a. What is the molar mass of NaA? b. Calculate the pH of the solution at the stoichiometric point of the titration.
E University Librarie. E UNIVERSITY POR. Student Detail Sc. Part A The table shows respective color change when a universal indicator is added to the clear solutions. Rank the samples based on increasing order of acid strength. Solutions Color change 0.001 M lactic Light red 0.01 M phenol Light yellow 0.01 M nitrous acid Light orange 0.001 M hydrogen peroxide Light green Rank the solutions by Increasing order of their acid strength. To rank items as equivalent, overlap them. > View Available Hint(s) Reset Help 0.01 Mnitrous acid 0.001 Mlactic acid 0.001 M hydrogen peroxide 0.01 Mphenol Least acidic Most acidic P Pearson Copyright © 2021 Pearson Education Inc. All rights reserved. Terms of Use | Privacy Policy | Permissions | Contact Us | MacBook Air 80 888 DII DD F3 F4 F5 F6 F7 F8 F9 F10 F11 $ & 3 4 7 8. 9. { R Y U 一 F J K く C V B N M + I| .. .- エト
! ( plz given detail explanation)
A 81.0 mL sample of 0.0500 M HBrO4 is titrated with 0.100 M NaOH solution. Calculate the pH after the following volumes of base have been added. (a) 14.2 mLpH = (b) 39.3 mLpH = (c) 40.5 mLpH = (d) 42.5 mLpH = (e) 79.0 mLpH =
10a.
Based on this table of values and the information provided, what is the identity of the unknown acid using the list of the polyprotic acids.
A 10.0 mL solution of 0.330 M NH, is titrated with a 0.110 M HCI solution. Calculate the pH after the following additions of the HC1 solution: 0.00 mL,10.0 mL, 30.0 mL, and 40.0 mL. Round your answer to 3 decimal places. Note: Reference the Ka of acids at 25 °C and Kb of bases at 25 °C tables for additional information.
8. A 100. mL sample of 0.10 MHCI is mixed with 50. mL of 0.12 M NH.. What is the resulting pH? (K, for NH3 = 1.8 × 10-- 3.07 10.93 1.57 12.43 1.40