Problem 2: https://doi.org/10.1016/S0040-4039(00)76159-4 Answer to Problem 2: Hint. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer. OsO4 ? A HO HO.... Η Но HO.... B с D HO но HO HO. HH H H
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- Please predict the outcome of each reaction below: Type you answer as a letter: A, B, ...., or F.Which chair represents the most stable conformation of Molecule A? A B b D d E e Molecule A Me ..Me 'Me Ме Chair conformations Me a) Me b) c) Me Me Me Me Me Me- -Me Me Ме Me d) Ме e) Ме Me Me- Ме Me Me MePlease help with the highlighted problem attached
- 8. Identify the stereochemical relationship between the structural pairs shown below as (A) identical structures that are not meso; (B) identical structures that ARE meso; (C) structures that are enantiomers; or (D) structures that are diastereomers. a) b) H3C c) CH3 Br H. CH3 Br Br CH3 H. CI Holl H Cill Cl- CH3 Br H. CI CH3 HO. H. H3C Cl H3C- H- H. CH3 Cl a) b) c) 9. Identify the stereochemical relationship between the structural pairs shown below as (A) identical structures that are not meso; (B) identical structures that ARE meso; (C) structures that are enantiomers; or (D) structures that are diastereomers. a) b) c) CH2CH3 NH2 HO CH3 H3C. CH3 Cl HO H;C CH2CH3 F. F H;C. CI H H,N -CH3 CH3 NH2 H3C Br H2N C1 H3C CH3 CH3 H;CH,C- Cl F H. H Br CH,CH3 CH3 a) b) c)4)- Calculate the free-energy for the first three conformers of A (i.e., A- conformation of A, A. Show how you were able to determine th receive full credit. A") starting from the most stable hation of A, A. Show how you were able to determine the answer an provide the answers below to IA] Calculation and Structure of A:_ Final Answer, Calculation and Structure of A': Final Answer Calculation and Structure of A" Final Answer 4Draw all six confirmations for the molecule shown (three eclipsed and three staggered Newman projections). Identify the anti-conformation. Identify the conformation that has the highest energy. Identify a staggered conformation with the most Gauche interactions.
- 2. Our knowledge of chair conformations allows us to use them to determine a great deal about a reaction's mechanism. In particular, using a t-butyl group to 'fix' a cyclohexane in a single conformation can help us learn about the spatial requirements and energetics of a reaction. Consider the following two reaction products: a. NO NID ALOH 1) NaCN 2) H+ 1) NaBH4 2) H3O+ OH Group -H -CN -OH A Value (kcal/mol) Defined as 0 0.2 kcal/mol 1.0 kcal/mol Draw the most stable chair conformation for each of the two products. b. Based on the A values in the table above, do the two products have the most stable conformation at the new stereocenter?1) RCO H 2) [H₂SOJ. ? Modify the given structure to draw the major product(s). Use the single bond tool to interconvert between double and single bonds. If a racemic mixture of enantiomers is expected, draw both enantiomers. Note: you can select a structure and use Copy and Paste to save drawing time. H₂C. OH th CH, CH₂ OH H₂C OH aff CH₂ CH₂ Edit Drawing5. The structure on the right is cortisone. What is the index of hydrogen deficiency (IHD) of cortisone? HINT: To answer this question, count the number of rings and double bonds. That's easier than figuring out what the formula of the molecule is. A) 4 B) 5 C) 6 D) 7 E) 8 I H- OH I OH
- Draw the most stable chair conformation possible for this compound. Are there any 1,3-diaxial interactions in the most stable chair conformation ( H-H not included ) and please fill in the blank: From the biomolecules surveyed, the compound is a(n)___________08.20b 1) ВН, THF 2) H,O2, NaOH Modify the given carbon skeleton to draw the major product(s) of the given reaction. If a racemic mixture of enantiomers is expected, draw both enantiomers. Note: you can select a structure and use Copy and Paste to save drawing time. CHis this (Z) or (E) conformation, and how do you know?

