Chemistry Be sure to answer all parts.Find the pH of the equivalence points when 28.9 mL of 0.0850 M H2SO3 is titrated with0.0652 M NaOH.pH1st = 4.32PH2nd=

Answered: Be sure to answer all parts. Find the…

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter15: Additional Aqueous Equilibria

Section: Chapter Questions

Problem 93QRT: When 40.00 mL of a weak monoprotic acid solution is titrated with 0.100-M NaOH, the equivalence...

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A buffer is prepared by dissolving 0.062 mol of sodium fluoride in 127 mL of 0.0399 M hydrofluoric acid. Assume no volume change after NaF is added. Calculate the pH of this buffer.
The titration of 0.100 M acetic acid with 0.100 M NaOH is described in the text. What is the pH of the solution when 35.0 mL of the base has been added to 100.0 mL of 0.100 M acetic acid?
What mass of NH4Cl must be added to 0.750 L of a 0.100-M solution of NH3 to give a buffer solution with a pH of 9.26? (Him: Assume a negligible change in volume as the solid is added.)
A 0.2481 M solution of KOH is used to titrate 30.00 mL of 0.269 M hydrobromic acid. Assume that volumes are additive. (a) Write a balanced net ionic equation for the reaction that takes place during the titration. (b) What are the species present at the equivalence point? (c) What volume of KOH is required to reach the equivalence point? (d) What is the pH of the solution 1. before any KOH is added? 2. halfway to the equivalence point? 3. at the equivalence point?
Consider the nanoscale-level representations for Question 110 of the titration of the aqueous weak acid HX with aqueous NaOH, the titrant. Water molecules and Na+ ions are omitted for clarity. Which diagram corresponds to the situation: After a very small volume of titrant has been added to the initial HX solution? When enough titrant has been added to take the solution just past the equivalence point? Halfway to the equivalence point? At the equivalence point? Nanoscale representations for Question 110.
Malonic acid (HO2CCH2CO2H) is a diprotic acid. In the titration of malonic acid w ith NaOH, stoichiometric points occur at pH = 3.9 and 8.8. A 25.00-mL sample of malonic acid of unknown concentration is titrated with 0.0984 M NaOH, requiring 31.50 mL of the NaOH solution to reach the phenolphthalein end point. Calculate the concentration of the initial malonic acid solution. (Sec Exercise 113.)
A 0.400-M solution of ammonia was titrated with hydrochloric acid to the equivalence point, where the total volume was 1.50 times the original volume. At what pH does the equivalence point occur?
You want to make a buffer with a pH of 10.00 from NH4+/NH3. (a) What must the [ NH4+ ]/[ NH3 ]ratio be? (b) How many moles of NH4Cl must be added to 465 mL of an aqueous solution of 1.24 M NH3 to give this pH? (c) How many milliliters of 0.236 M NH3 must be added to 2.08 g of NH4Cl to give this pH? (d) What volume of 0.499 M NH3 must be added to 395 mL, of 0.109 M NH4Cl to give this pH?
a Draw a pH titration curve that represents the titration of 50.0 mL of 0.10 M NH3 by the addition of 0.10 M HCl from a buret. Label the axes and put a scale on each axis. Show where the equivalence point and the buffer region are on the titration curve. You should do calculations for the 0%, 30%, 50%, and 100% titration points. b Is the solution neutral, acidic, or basic at the equivalence point? Why?
Sketch the titration curve for a weak acid titrated by a strong base. When performing calculations concerning weak acidstrong base titrations, the general two-slep procedure is to solve a stoichiometry problem first, then to solve an equilibrium problem to determine the pH. What reaction takes place in the stoichiometry part of the problem? What is assumed about this reaction? At the various points in your titration curve, list the major species present after the strong base (NaOH, for example) reacts to completion with the weak acid, HA. What equilibrium problem would you solve at the various points in your titration curve to calculate the pH? Why is pH 7.0 at the equivalence point of a weak acid-strong base titration? Does the pH at the halfway point to equivalence have to be less than 7.0? What does the pH at the halfway point equal? Compare and contrast the titration curves for a strong acidstrong base titration and a weak acidstrong base titration.
A 0.400-g sample of propionic acid was dissolved in water to give 50.0 mL of solution. This solution was titrated with 0.150 M NaOH. What was the pH of the solution when the equivalence point was reached?
Each of the solutions in the table has the same volume and the same concentration, 0.1 M. Which solution requires the greatest volume of 0.1-M NaOH to titrate to the equivalence point? Explain your answer.

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Be sure to answer all parts. Find the pH of the equivalence points when 28.9 mL of 0.0850 M H2SO3 is titrated with 0.0652 M NaOH. pH1st = 4.32 PH2nd =