Experiment shows that the rate formation of carbon tetrachloride from chloroform,CH3 +Cl2 → CCl4 + HCIis the first order in CHCl3, ½ order in Cl2 and 3/2 order overall. Is the followingmechanism consistent with the overall rate low?Cl2 2 Cl(K1, K-1)fastCl + CHCl 3 → HCI + CC13⚫(k2)slowCCl3 + Cl⚫CCl4(K3)fast(Use the steady state principle for the radicals Cl• and CC13. to determine thedifferential rate equation of carbon tetrachloride formation d [CCl4] / dt).

Step 1:To determine if the proposed mechanism is consistent with the observed rate law, let's…

Answered: Experiment shows that the rate…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter12: Chemical Kinetics

Section: Chapter Questions

Problem 12Q: The plot below shows the number of collisions with a particular energy for two different...

See similar textbooks

Similar questions

Which of the following will confirm that the decomposition of SO2Cl2 (to form SO2 and Cl2) is a first-order process? (a) A graph of [SO2Cl2] vs. time gives a curved line. (b) A graph of ln[SO2Cl2] vs. time gives a curved line. (c) A graph of 1/[SO2Cl2] vs. time gives a straight line. (d) A graph of ln[SO2Cl2] vs. time gives a straight line.
For the past 10 years, the unsaturated hydrocarbon 1, 3-butadiene (CH2 = CH - CH = CH2) has ranked 38th among the top 50 industrial Chemicals. It is used primarily for the manufacture of synthetic rubber. An isomer exists also as cyclobutene: The isomerization of cyclobutene to butadiene is first-order and the rate constant has been measured as 2.0104s1 at 150 C in a 0.53-L ?ask. Determine the partial pressure of cyclobutene and its concentration after 30.0 minutes if an isomerization reaction is carried out at 150 C with an initial pressure of 55 torr.
There are two molecules with the formula C3H6 Propane, CH3CH = CH2, is the monomer of the polymer polypropylene, which is used for indoor-outdoor carpets. Cyclopropane is used as an anesthetic: When heated to 499 C, cyclopropane rearranges (isomerizes) and forms propane with a rate constant of 5.95104s1. What is the half-life of this reaction? What fraction of the cyclopropane remains after 0.75 h at 499 C?
The rate constant for the ?rst-order decomposition at 45 C of dinitrogen pentoxide, N2O5, dissolved in chloroform, CHCI3, is 6.2104 min-1. 2N2O54NO2+O2 What is the rate of the reaction when [N2O5] = 0.40 M?
The rate constants for the ﬁrst order reaction were found at different temperatures (below). What is theactivation energy for this reaction in kJ/mol? T1 = 11.6 oC k1 = 0.35 T2 = 48.6 oC k2 = 7.1Report your answer to the nearest whole number.
Answer following parts only. a(ii) , c
þne proposed mechanism for the condensation of propanone, ((CH3)2CO), is as follows: (CH3),CO(aq) + OH (aq) = CH;C(0)CH2(aq) + H20(1) %3D CH;C(O)CH2 (aq) + (CH3)2CO(aq) product Use the steady-state approximation to determine the rate of formation for the product.
Rate law = k [HgCl2] [C2O4 -2]^2 I believe k = 0.022584815 s^-1 d. What is the rate of disappearance of oxalate ion when [C2O2−4]= 0.10 M[C2O42−]= 0.10 M and [HgCl2] = 0.20 M[HgCl2] = 0.20 M? e. Is the overall reaction likely to be an elementary step? Explain. f. Which species is oxidized in the reaction? Which is reduced?
24 = 25 = 26 27 = 28 29 = 30 = 31 = 32 = 33 34 35 36 The rate at which a certain drug is eliminated by the body follows first-order kinetics, with a half life of 74 minutes. Suppose in a particular patient the concentration of this drug in the bloodstream immediately after injection is 0.16 ug/mL. What will the concentration be 296 minutes later? do Round your answer to 2 significant digits. Ar x10 mL Submit Assignment Continue MacBook Air F12 >> FI F10 F9 F8 F7 D00 O00 FA F6 딤 F3 F5 sc
What is the rate law for the proposed mechanism? A) rate = k[H2][NO] H2(g) + 2NO(g) → N2O(g) + H2O(g) k[H•J°[NO] Step 1 (slow) B) rate = rate = k[H:][NO]? %3D N20(g) + H2(g) –→ N2(g) + H2O(g) Step 2 (fast) D) rate = k[H:]°[NO]? E) rate = k[H:][N:O]
Options for part a: Unimolecular, bimolecular, termolecular
A+B⟶C+Drate=?[A][B]2A+B⟶C+Drate=k⁡[A]⁢[B]2 has an initial rate of 0.0790 M/s.0.0790 M/s. What will the initial rate be if [A][A] is halved and [B][B] is tripled?

SEE MORE QUESTIONS

Recommended textbooks for you

Chemistry

ISBN:

9781305957404

Author:

Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:

Cengage Learning

Chemistry: An Atoms First Approach

Chemistry

ISBN:

9781305079243

Author:

Steven S. Zumdahl, Susan A. Zumdahl

Publisher:

Cengage Learning

Chemistry

ISBN:

9781133611097

Author:

Steven S. Zumdahl

Publisher:

Cengage Learning

Chemistry

ISBN:

9781305957404

Author:

Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:

Cengage Learning

Chemistry: An Atoms First Approach

Chemistry

ISBN:

9781305079243

Author:

Steven S. Zumdahl, Susan A. Zumdahl

Publisher:

Cengage Learning

Chemistry

ISBN:

9781133611097

Author:

Steven S. Zumdahl

Publisher:

Cengage Learning

Chemistry: The Molecular Science

Chemistry

ISBN:

9781285199047

Author:

John W. Moore, Conrad L. Stanitski

Publisher:

Cengage Learning

Chemistry: Principles and Practice

Chemistry

ISBN:

9780534420123

Author:

Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:

Cengage Learning

Chemistry & Chemical Reactivity

Chemistry

ISBN:

9781133949640

Author:

John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Publisher:

Cengage Learning

SEE MORE TEXTBOOKS