Experiment shows that the rate formation of carbon tetrachloride from chloroform,CH3 +Cl2 → CCl4 + HCIis the first order in CHCl3, ½ order in Cl2 and 3/2 order overall. Is the followingmechanism consistent with the overall rate low?Cl2 2 Cl(K1, K-1)fastCl + CHCl 3 → HCI + CC13⚫(k2)slowCCl3 + Cl⚫CCl4(K3)fast(Use the steady state principle for the radicals Cl• and CC13. to determine thedifferential rate equation of carbon tetrachloride formation d [CCl4] / dt).

Step 1:To determine if the proposed mechanism is consistent with the observed rate law, let's…

Answered: Experiment shows that the rate…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter12: Chemical Kinetics

Section: Chapter Questions

Problem 12Q: The plot below shows the number of collisions with a particular energy for two different...

See similar textbooks

Similar questions

Which of the following will confirm that the decomposition of SO2Cl2 (to form SO2 and Cl2) is a first-order process? (a) A graph of [SO2Cl2] vs. time gives a curved line. (b) A graph of ln[SO2Cl2] vs. time gives a curved line. (c) A graph of 1/[SO2Cl2] vs. time gives a straight line. (d) A graph of ln[SO2Cl2] vs. time gives a straight line.
For the past 10 years, the unsaturated hydrocarbon 1, 3-butadiene (CH2 = CH - CH = CH2) has ranked 38th among the top 50 industrial Chemicals. It is used primarily for the manufacture of synthetic rubber. An isomer exists also as cyclobutene: The isomerization of cyclobutene to butadiene is first-order and the rate constant has been measured as 2.0104s1 at 150 C in a 0.53-L ?ask. Determine the partial pressure of cyclobutene and its concentration after 30.0 minutes if an isomerization reaction is carried out at 150 C with an initial pressure of 55 torr.
There are two molecules with the formula C3H6 Propane, CH3CH = CH2, is the monomer of the polymer polypropylene, which is used for indoor-outdoor carpets. Cyclopropane is used as an anesthetic: When heated to 499 C, cyclopropane rearranges (isomerizes) and forms propane with a rate constant of 5.95104s1. What is the half-life of this reaction? What fraction of the cyclopropane remains after 0.75 h at 499 C?
The rate constant for the ?rst-order decomposition at 45 C of dinitrogen pentoxide, N2O5, dissolved in chloroform, CHCI3, is 6.2104 min-1. 2N2O54NO2+O2 What is the rate of the reaction when [N2O5] = 0.40 M?
Experiment shows that the rate of formation of carbontetrachloride from chloroform,CHCl₃(g)+Cl₂(g) → CCl₄(g)+HCl(g) is first order in CHCl₃, order in Cl₂, and order overall. Show that the following mechanism is consistent with the rate law:
90. Given an irreversible trimolecular – type reaction A + B + C = products with CD0 much greater than CA0 and CB0, the reaction is a) First order b) third order c) zero order d) second order
A proposed mechanism for the formation of N₂O5(g) from NO₂(g) and O3(g) is NO₂(g) + O3(9) ✩ NO3(g) + O₂(g) NO₂(g) + NO3(g) + M(9) K₂ N₂O5(9) + M(9) Determine the rate law expression for the production of N₂O5(g) given this mechanism.
Please answer fast
Answer following parts only. a(ii) , c
Rate law = k [HgCl2] [C2O4 -2]^2 I believe k = 0.022584815 s^-1 d. What is the rate of disappearance of oxalate ion when [C2O2−4]= 0.10 M[C2O42−]= 0.10 M and [HgCl2] = 0.20 M[HgCl2] = 0.20 M? e. Is the overall reaction likely to be an elementary step? Explain. f. Which species is oxidized in the reaction? Which is reduced?
Suppose the following exchange of water reactions were carried out by an associative mechanism rather than a dissociative mechanism: M(H₂0)6+ + H₂018 M(H₂O)5(H₂018)n+ + H₂O -> Please select all correct statements for this reaction (there may be more than one answer). The rate equation for this reaction is rate = k₁[M(H₂O)6+]. If the metal's charge increases, the reaction rate would increase. The intermediate has a lower coordination number than the starting complex. If the metal's size decreases, there would be more steric hindrance in the
24 = 25 = 26 27 = 28 29 = 30 = 31 = 32 = 33 34 35 36 The rate at which a certain drug is eliminated by the body follows first-order kinetics, with a half life of 74 minutes. Suppose in a particular patient the concentration of this drug in the bloodstream immediately after injection is 0.16 ug/mL. What will the concentration be 296 minutes later? do Round your answer to 2 significant digits. Ar x10 mL Submit Assignment Continue MacBook Air F12 >> FI F10 F9 F8 F7 D00 O00 FA F6 딤 F3 F5 sc

SEE MORE QUESTIONS

Recommended textbooks for you

Chemistry

ISBN:

9781305957404

Author:

Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:

Cengage Learning

Chemistry: An Atoms First Approach

Chemistry

ISBN:

9781305079243

Author:

Steven S. Zumdahl, Susan A. Zumdahl

Publisher:

Cengage Learning

Chemistry

ISBN:

9781133611097

Author:

Steven S. Zumdahl

Publisher:

Cengage Learning

Chemistry

ISBN:

9781305957404

Author:

Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:

Cengage Learning

Chemistry: An Atoms First Approach

Chemistry

ISBN:

9781305079243

Author:

Steven S. Zumdahl, Susan A. Zumdahl

Publisher:

Cengage Learning

Chemistry

ISBN:

9781133611097

Author:

Steven S. Zumdahl

Publisher:

Cengage Learning

Chemistry by OpenStax (2015-05-04)

Chemistry

ISBN:

9781938168390

Author:

Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser

Publisher:

OpenStax

Chemistry & Chemical Reactivity

Chemistry

ISBN:

9781133949640

Author:

John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Publisher:

Cengage Learning

Chemistry: The Molecular Science

Chemistry

ISBN:

9781285199047

Author:

John W. Moore, Conrad L. Stanitski

Publisher:

Cengage Learning

SEE MORE TEXTBOOKS