Problem 3: https://doi.org/10.1021/ja9093988 Answer to Problem 3: Hint. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer. H CO₂Me H2 ? PtO2 HO A B с D H CO₂Me H CO₂Me H CO₂Me H CO₂Me HO HO HO

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter25: Biomolecules: Carbohydrates
Section25.5: Cyclic Structures Of Monosaccharides: Anomers
Problem 13P
Question
Please predict the outcome of each reaction below: Type you answer as a letter: A, B, ...., or F.
Problem 3: https://doi.org/10.1021/ja9093988
Answer to Problem 3:
Hint. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer.
H CO₂Me
H2
?
PtO2
HO
A
B
с
D
H CO₂Me
H
CO₂Me
H CO₂Me
H CO₂Me
HO
HO
HO
Transcribed Image Text:Problem 3: https://doi.org/10.1021/ja9093988 Answer to Problem 3: Hint. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer. H CO₂Me H2 ? PtO2 HO A B с D H CO₂Me H CO₂Me H CO₂Me H CO₂Me HO HO HO
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