IR Spectrum(liquid film)4000www.bl10080604020408013C NMR Spectrum(20.0 MHz, CDCI solution)expansion130proton decoupled200¹H NMR Spectrum(400 MHz, CDCI, solution)expansion.2.87.4% of base peak1030007.2 ppm9918922000120125v (cm¹)M+134L1602.6m/e1601716002001.7 1.661200800Mass SpectrumC10 H14280120expansions240I1solventли5L801.5 1.4I40.00.51.01.51absorbance200Problem 94UV spectrum1.430mg / 10 mlspath length: 2.00 cmsolvent: hexane250300H-C-HH-C-H1401.1 1.0 ppm32H-C-Hλ (nm)1-CH3TMS0113502008 (ppm)TMS08 (ppm)183

Answered: Image /qna-images/answer/423929f0-3174-4d3a-bdd2-59a952ea2255.jpg

IR Spectrum (liquid film) 4000 3000 2000 V (cm¹) 100 91 80 92 60 TH M+ 40 134 20 40 80 13C NMR Spectrum (20.0 MHz, CDCI, solution) expansion T 130 proton decoupled 1 200 ¹H NMR Spectrum (400 MHz, CDCI, solution) expansion 2.8 7.4 7.2 ppm 10 9 8 % of base peak 120 160 200 m/e 125 1600 160 2.6 1200 800 0.0 Mass Spectrum 0.5 1.0 C10H14 1.5 240 280 120 expansions solvent ли 1 80 1 absorbance 200 Problem 94 UV spectrum 1.430mg/10 mls path length: 2.00 cm solvent: hexane 250 300 H-C-H H-C-H L 40 ille 1.7 1.6 1.5 1.4 1.1 1.0 1 1 1 7 6 5 4 3 λ (nm) H-C-H ppm -CH3 TMS 350 tut 1 2 1 200 08 (ppm) TMS 0 8 (ppm)

IR Spectrum (liquid film) 4000 3000 2000 V (cm¹) 100 91 80 92 60 TH M+ 40 134 20 40 80 13C NMR Spectrum (20.0 MHz, CDCI, solution) expansion T 130 proton decoupled 1 200 ¹H NMR Spectrum (400 MHz, CDCI, solution) expansion 2.8 7.4 7.2 ppm 10 9 8 % of base peak 120 160 200 m/e 125 1600 160 2.6 1200 800 0.0 Mass Spectrum 0.5 1.0 C10H14 1.5 240 280 120 expansions solvent ли 1 80 1 absorbance 200 Problem 94 UV spectrum 1.430mg/10 mls path length: 2.00 cm solvent: hexane 250 300 H-C-H H-C-H L 40 ille 1.7 1.6 1.5 1.4 1.1 1.0 1 1 1 7 6 5 4 3 λ (nm) H-C-H ppm -CH3 TMS 350 tut 1 2 1 200 08 (ppm) TMS 0 8 (ppm)

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

4000 100 80 60 IR Spectrum (liquid film) 40 20 $ 2 2960 3000 41 77 79 40 13C NMR Spectrum (50.0 MHz. CDCI, solution) proton decoupled 200 ¹H NMR Spectrum (200 MHz, CDCI, solution) T 40 10 9 80 2000 107/109 1 8 120 v (cm¹) m/e 1600 M** 156/158/160 160 160 3.5 1200 120 200 240 766 800 Mass Spectrum expansions ppm 2.5 1 7 6 5 650 C3H6Br Cl 280 T 2.0 ppm solvent 80 4 H-C-H Problem 18 No significant UV absorption above 220 nm H-C-H 1 3 40 H-C-H 0 1 2 1 124 8 (ppm) TMS 0 8 (ppm) 107
4000 100 80 60 IR Spectrum (liquid film) 20 wwwladdade % of base peak expansion 13C NMR Spectrum (100.0 MHz, CDCI, solution) 7.5 10 3000 40 1H NMR Spectrum (400 MHz, CDCI, solution) 80 proton decoupled 200 9 DEPT CH₂ CH₂ CH4 7.3 ppm 1 8 105 2000 120 . mmp V (cm¹) M+= 134 m/e 160 1600 160 7 6 1200 120 2.8 2.7 ppm Mass Spectrum 200 240 280 800 5 C10H14 1.8 solvent 80 expansions 4 UV Spectrum max 260 nm (log₁08 2.5) 40 1.7 ppm 1.45 1.35 ppm 3 0 AHA 1.05 0.95 2 8 (ppm) 1 expansion TMS 1 0 8 (ppm)
4000 IR Spectrum quid film) 100 80 60 40 YI 2248 41 10 3000 43 40 proton decoupled "C NMR Spectrum (150 MHz CDC, solution) 68 DEPT CH, CH, 1 CHT 9 200 ¹H NMR Spectrum (600 MHz, CDC, solution) M83 (<1%) 80 120 2000 v (cm) 8 m/e 160 160 2.3 L 7 1600 2.2 200 ryper 1200 6 ▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬ 120 Mass Spectrum 240 21 2.0 expansions (not to scale) 800 I CsH₂N 280 5 expansion 80 4 270 255 256 255 expansion No significant UV absorption above 220 nm 27.0 245 250 255 1.0 3 40 L 2 0 8 (ppm) 1 1 TMS L 1 0 8 (ppm) 10 ¹H-¹C me-HSQC Spectrum (600 MHz, CDC, solution) Black cross-peaks CH and CH Red cross-peaks CH₂ ppm 20 ¹H-"C HMBC Spectrum (600 MHz, CDC), solution) -22 -24 -26 -28 116 118 120 122 124 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0.6 ppm ppm 20 22 -24 26 28 -116 118 -120 122 -124 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0.6 ppm IR: List bands and possible/probable structural units responsible Band (cm³) Possible…
m 00 trum solutic 4000 88892 IR Spectrum (liquid fem) 100 80 60 40 20 % of base peak m 1600 v (cm¹) 68 M 147/149 40 80 120 160 m/e 13C NMR Spectrum (100 MHz. CDC, solution) 10 3000 54 DEPT CHY CH1 CHA proton decoupled 200 ¹H NMR Spectrum (200 MHz. CDCI, solution) 108 2249 2000 160 expansion 34 30 26 9 8 7 1200 800 Mass Spectrum C₂H6NBr 200 240 280 120 22 ppm 6 5 solvent 1 80 4 Problem 19 No significant UV absorption above 220 nm 40 3 0 125 8 (ppm) TMS 1 0 8 (ppm) 2 1
Myriam 1718 1. 4000 3000 1600 1200 800 V (cm¹) 100 Mass Spectrum 43 119 80 60 JIK M+* 40 176 20 161 C12 H16 O 40 80 200 280 120 160 m/e 13C NMR Spectrum (50.0 MHz, CDCI, solution) expansion 188 IR Spectrum (liquid film) % of base peak DEPT CH₂ CH₂ CH proton decoupled L 200 ¹H NMR Spectrum (200 MHz, CDCI, solution) J 1 9 10 I 8 2000 160 the 1 7 6 240 120 130 130 125 ppm 125 ppm L 5 expansion 1 80 1 4 solvent Problem 99 UV Spectrum max 262 nm (log₁0 € 2.5) solvent methanol 40 t I 3 1 2 4 08 (ppm) TMS 1 0 8 (ppm) 1 1 205
IR Spectrum (liquid film) 184 4000 100 80 60 40 20 40 13C NMR Spectrum (50.0 MHz, CDCI, solution) proton decoupled 200 ¹H NMR Spectrum (600 MHz, CDCI, solution) 1 10 9 8 3000 % of base peak 80 128 my 2000 V (cm¹) 119 M+* 134 120 160 m/e expansion 124 ppm 160 1600 I 7 200 I 6 120 ppm 1200 800 Mass Spectrum C10 H14 280 solvent 80 240 I 5 7.4 1 4 expansion 3 Problem 95 UV Spectrum max 262 nm (log10 € 2.5) solvent: ethanol -CH3 C 40 7.2 2 1 0 8 (ppm) TMS 1 I 1 0 8 (ppm) 201
опанит 1715 1600 IR Spectrum 100 4000 (liquid film) 43 80 75 60 M 40 20 % of base peak 10 3000 40 C 13C NMR Spectrum (20.0 MHz, CDCI solution) proton decoupled 9 80 200 ¹H NMR Spectrum (100 MHz, CDCI, solution) 101 8 2000 v (cm¹) M** 132 120 160 m/e 160 7 6 1200 120 Mass Spectrum 200 240 280 800 C-H 5 C6H1203 solvent L 80 4 -CH3 No significant UV absorption above 220 nm 3 H-C-H u -CH3 40 2 59 TMS 0 1 8 (ppm) TMS 0 8 (ppm)
4000 100 80 60 20 % of base peak 3376 40 10 3000 59 13C NMR Spectrum (50.0 MHz, CDCI, solution) 173 proton decoupled 200 I 9 80 ¹H NMR Spectrum (200 MHz, CDCI, solution) DEPT CH₂ CH₂ CH4 IR Spectrum (liquid film) 2000 M+88 (<1%) 120 1600 v (cm¹) m/e 160 160 I I 8 7 mmm 1 120 200 240 6 1200 . Mass Spectrum L 800 1 5 C5H₁20 280 solvent L 80 4 problem 78 3 No significant UV absorption above 220 nm 40 Il 08 (ppm) 1 2 1 TMS 0 8 (ppm)
43 184 IR Spectrum (Iquid film) 4000 3000 100 80 60 40 20 40 13C NMR Spectrum (100.0 MHz, CDCI, solution) 9 80 DEPT CH₂ CH₂4 CHA proton decoupled 200 ¹H NMR Spectrum (400 MHz CDCI, solution) expansion 7.5 7.3 ppm 8 P 10 SAMSUNG Galaxy A53 5G 2000 1600 V (cm) 105 M+- 134 120 160 m/e 160 09b0f2ca-eac1-4... 1200 T L 120 2.8 2.7 ppm 7 6 ww 800 Mass Spectrum C10H14 200 240 280 T 1 5 solvent " 80 expansions 1.8 1.7 ppm 1 4 3:54 م 0 *1 470 صفحة Problem 96 UV Spectrum max 260 nm (log10=2.5) PE 40 1.45 1.35 ppm 3 2 Problem 97 08 (ppm) expansion 1.05 0.95 TMS I 0 8 (ppm) 1 202 تمشح بـ 100 جيجابايت تخزين على OneDrive cloud لمدة 6 أشهر 185.
IR Spectrum (liquid film) لللللللللللا 4000 100 80 60 408 20 40 3000 39 10 proton decoupled "C NMR Spectrum (100 MHz, CDC, solution) 75 200 9 ¹H NMR Spectrum (400 MHz, CDCI, solution) 77 5.50 558 expansion 188- ▬▬▬▬▬▬ 2000 T 8 M+ 110/112/114 80 120 160 200 240 m/e V (cm) DEPT CH₂ CH₂ 1 CH 1 160 1600 5.42 5.40 ppm mp 7 L W 6 1200 120 Mass Spectrum 800 5 C3H4Cl2 280 solvent T I 80 1 4 3 No significant UV absorption above 220 nm 40 expansion 4.18 4.16 pom 111 2 08 (ppm) 1 1 TMS L 0 ō (ppm) IR: List bands and possible/probable structural units responsible Band (cm³) Possible stretches/functional groups MS: Molecular Formula 13C NMR: 1 2 3 4 5 6 Chem. Shift (8) Type of C (sp, sp², carbonyl, etc.) ¹H NMR: 1 2 3 4 5 Chem. Shift (8) Multiplicity (singlet, doublet, etc.) IHD(DU)= (Show calculation) 6 If you need more space, add any additional signal info here: # of attached H's #of identical C's in signal Probable Type of H (methyl, aromatic, etc.) # of identical H's in signal
3296 IR Spectrum (quid film) ....... wwwddd 4000 100 80 60 40F 8 -28 20 40 proton decoupled 10 13C NMR Spectrum (100 MHz, CDC, solution) 2H - 3000 ¹H NMR Spectrum (400 MHz, CDC, solution) 55 200 2.5 9 80 82 2114 8 2000 M = 83 120 V (cm-¹) 2H L 160 expansion 1600 1200 C₂H₂N 160 200 240 280 m/e DEPT CH, I CH₂ 1 CH 1 2.0 I 7 1H 6 L 120 Mass Spectrum 2H 1.5 800 5 solvent I 80 exchanges with DO 4 2H L 3 No significant UV absorption above 220 nm ||| L 40 2 113 08 (ppm) 1 1 TMS 0 8 (ppm) IR: List bands and possible/probable structural units responsible Band (cm³) Possible stretches/functional groups MS: Molecular Formula 13C NMR: 1 2 3 4 5 6 ¹H NMR: 1 Chem. Shift (8) Type of C (sp, sp2², carbonyl, etc.) 2 Chem. Shift (8) Multiplicity (singlet, doublet, etc.) IHD(DU)= 3 4 5 6 If you need more space, add any additional signal info here: (Show calculation) of attached c # of attached H's # of identical C's in signal Probable Type of H (methyl, aromatic, etc.) # of identical H's in signal
2 IR Spectrum (liquid film) 4000 100 80 20 my 2251 % of base peak 3000 40 80 13C NMR Spectrum (100.0 MHz, CDCI, solution) 10 DEPT CH₂ CH₂ CH proton decoupled 200 ¹H NMR Spectrum (400 MHz. CDCI, solution) 2000 9 8 v (cm¹) M 117 120 160 200 m/e expansion 130 129 130 129 1600 expansion 160 ppm ppm 120 1200 800 Mass Spectrum C8H7N 240 280 solvent 1 80 40 7 6 5 4 3 2 0 8 (ppm) 1 TMS L 0 8 (ppm)