If the stationary phase and the compound being tested are both polar, will the retention factor (Rf) likely be smaller or larger than if a nonpolar compound was tested? Why? The retention factor will likely be smaller as it has a smaller interaction with O 1) the stationary phase 2) The retention factor will likely be greater as it has a smaller interaction with the stationary phase 3) The retention factor will likely be smaller as it has a greater interaction with the stationary phase 4) The retention factor will likely be greater as it has a greater interaction with the stationary phase
If the stationary phase and the compound being tested are both polar, will the retention factor (Rf) likely be smaller or larger than if a nonpolar compound was tested? Why? The retention factor will likely be smaller as it has a smaller interaction with O 1) the stationary phase 2) The retention factor will likely be greater as it has a smaller interaction with the stationary phase 3) The retention factor will likely be smaller as it has a greater interaction with the stationary phase 4) The retention factor will likely be greater as it has a greater interaction with the stationary phase
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![### Chromatography and Retention Factor (Rf) Educational Exercise
**Question:**
If the stationary phase and the compound being tested are both polar, will the retention factor (Rf) likely be smaller or larger than if a nonpolar compound was tested? Why?
**Multiple Choice Options:**
1. The retention factor will likely be smaller as it has a smaller interaction with the stationary phase.
2. The retention factor will likely be greater as it has a smaller interaction with the stationary phase.
3. The retention factor will likely be smaller as it has a greater interaction with the stationary phase.
4. The retention factor will likely be greater as it has a greater interaction with the stationary phase.
---
**Explanation:**
In chromatography, the retention factor (Rf) is a measure of how far a compound travels relative to the distance traveled by the solvent. It is calculated as follows:
\[ Rf = \frac{\text{Distance traveled by the compound}}{\text{Distance traveled by the solvent}} \]
- **When both the stationary phase and the compound are polar:** The compound will have a higher affinity for the stationary phase, leading to greater interaction and thus slower movement. This results in a smaller Rf value.
- **When the stationary phase is polar and the compound is nonpolar:** The compound will have less interaction with the stationary phase and therefore move faster, resulting in a larger Rf value.
**Interpretation of Options:**
- **Option 1:** Incorrect - Smaller interaction would lead to a greater Rf.
- **Option 2:** Incorrect - Smaller interaction would lead to a greater Rf, not applicable here.
- **Option 3:** **Correct** - Greater interaction with the stationary phase results in a smaller Rf.
- **Option 4:** Incorrect - Greater interaction would result in a smaller Rf, not a greater one.
**Correct Answer:** **3) The retention factor will likely be smaller as it has a greater interaction with the stationary phase.**](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F43424990-d5f9-4075-b304-9971f8aa7069%2Ffdc1e4b1-242a-490c-9b6d-95573a3f0062%2F91qmsxs_processed.jpeg&w=3840&q=75)
Transcribed Image Text:### Chromatography and Retention Factor (Rf) Educational Exercise
**Question:**
If the stationary phase and the compound being tested are both polar, will the retention factor (Rf) likely be smaller or larger than if a nonpolar compound was tested? Why?
**Multiple Choice Options:**
1. The retention factor will likely be smaller as it has a smaller interaction with the stationary phase.
2. The retention factor will likely be greater as it has a smaller interaction with the stationary phase.
3. The retention factor will likely be smaller as it has a greater interaction with the stationary phase.
4. The retention factor will likely be greater as it has a greater interaction with the stationary phase.
---
**Explanation:**
In chromatography, the retention factor (Rf) is a measure of how far a compound travels relative to the distance traveled by the solvent. It is calculated as follows:
\[ Rf = \frac{\text{Distance traveled by the compound}}{\text{Distance traveled by the solvent}} \]
- **When both the stationary phase and the compound are polar:** The compound will have a higher affinity for the stationary phase, leading to greater interaction and thus slower movement. This results in a smaller Rf value.
- **When the stationary phase is polar and the compound is nonpolar:** The compound will have less interaction with the stationary phase and therefore move faster, resulting in a larger Rf value.
**Interpretation of Options:**
- **Option 1:** Incorrect - Smaller interaction would lead to a greater Rf.
- **Option 2:** Incorrect - Smaller interaction would lead to a greater Rf, not applicable here.
- **Option 3:** **Correct** - Greater interaction with the stationary phase results in a smaller Rf.
- **Option 4:** Incorrect - Greater interaction would result in a smaller Rf, not a greater one.
**Correct Answer:** **3) The retention factor will likely be smaller as it has a greater interaction with the stationary phase.**
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