Answered: Explain the physical origin of the…

Science

Chemistry

Explain the physical origin of the general selection rules of microwave and infrared spectroscopy.

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter28: Atomic Spectroscopy

Section: Chapter Questions

Problem 28.3QAP

See similar textbooks

Related questions

Q: Question 20: A redox reaction between aluminum ion and nitrogen monoxide is carried out in basic…

A: In a redox reaction, one species is oxidized (loses electrons) and another is reduced (gains…

Q: A sample of a hydrocarbon gas weighing 0.832 grams has a volume of 273 milliliters at a pressure of…

Q: Show work with explanation needed. don't give Ai generated solution

A: All are alkane with halide substituents.Steps to follow:Step 1: Identify longest carbon chain with…

Q: 6c5: In addition to solving the problem please give brief explanation for concepts and solution if…

Q: Don't use AI.

Q: For each of the following molecules, assign the molecule as chiral or achiral

A: If you have any question related to any part, you can ask.

Q: Don't use AI.

Q: Please correct answer and don't use hand raiting

A: Here's how the two diastereomeric products could be formed from the carbocation…

Q: Ignore the writing in the photo, only look at text.

A: The question asks which of the given compounds are paramagnetic. Let's analyze the options shown in…

Q: 3. Provide the product and mechanism for the following reaction 1. OCH3 2. H+ N

A: Step 1:The reactants are enamine and α, β-unsaturated ester. The given reaction is an example of…

Q: Help me with my study guide

A: Thank you.

Q: Q6. How many chiral carbons in the following compound? (1 point) 1. 2 II. 3 III. 5 IV. 1 HO H CH2 OH…

A: Chiral carbons must have four different groups attached to it. The molecule given contains two such…

Q: what structure do i need to draw?

Q: My question is about part C of the question shown. The answer is shown and then I drew an…

A: If you still have any confusion, you can ask!

Q: Determine the energy of a photon with a wvelength of 444 nm

A: The energy of a photon is given by the equation E = h * c / λ, where E is the energy of the photon,…

Q: Can you provide steps and explanations? When to use each reagents? Focus on c and d. Provide some…

A: Step 1:(a) The reactant is an alkyne while the product is a trans or E-alkene. The alkyne can be…

Q: Write the structure(s) for the organic product(s) of the carbohydrates reaction below.

A: α-D-glucopyranose, the cyclic form of D-glucose, is reduced by NaBH4 to D-glucitol or sorbitol. This…

Q: Water is exposed to infrared radiation of wavelength 2.9×10−4 cm . Assume that all the radiation is…

A: if doubt arises please mention in the comments.

Q: 25. please dont submit AI. answer as its wrong

A: Thank you.

Q: Analyze the IR spectrum of fumaric acid and write down the main bonds. Ignore any wavelength below…

A: Step 1:

Q: Add the necessary reaction conditions above or below the arrow in this organic reaction. Also, if a…

A: Step 1: Step 2: Step 3: Step 4:

Q: Identify the element in period 2 that would form each of the following ions. E is used as a general…

A: Approach to solving the question: we need to see which element will be stable after loosing or…

Q: 14. Please answer. NO AI. Please Check on answer to confrim its correct.

Q: 3. please dont submit AI. answer as its wrong

Q: Please correct answer and don't use hand raiting

A: Understanding the Problem:We have a sample of 5 moles of an ideal gas with Cv = 3/2R undergoing a…

Q: 2. please dont submit AI. answer as its wrong

A: Thank you.

Q: 18

A: In a single replacement reaction, one element replaces another element in a compound. The general…

Q: There are eight primary amines with the molecular formula C5H13N . (a) Name and draw a structural…

A: Step 1: Step 2: Step 3: Step 4:

Q: Please correct answer and don't use hand raiting

A: Retrosynthetic Analysis:Disconnection: Ester CleavageTarget: Lactone Disconnection: Cleavage of the…

Q: A. Please provide the products of each reaction. H₂N CI CI OH F NaOCI CH3CN / Acetic Acid

Q: 7. Draw energy diagrams for exergonic reactions that meet the following criteria: slow reaction with…

A: In the exothermic or exergonic reaction, the energy of reactants is higher than that of products,…

Q: What are the major products from the reactions.

Q: What is more nucleophilic CH3O- or CH3S- ? The solvent isn't mentioned, or it can be assumed it's…

A: In an aprotic solvent, CH₃S⁻ is more nucleophilic than CH₃O⁻. This is because sulfur is larger and…

Q: Predict the major products of the following reaction. Be sure to show the stereochemistry of the…

A: Approach to solving the question: The given reaction is a halogenation of alkyne which gives the…

Q: Please correct answer and don't use hand raiting

A: From the Bohr's formula, energy of electron in atom is,E=−n2RyRy = 2.18 × 10-18 JEnergy of…

Q: Find the mistakes in the answers below, state whats wrong, and correctly answer the questions as…

A: Step 1: Step 2: Step 3: Step 4:

Q: The standard Gibbs energy (p = 100 kPa, 25 °C) of formation of H2O (1) is 237.129 kJ mol-1 and its…

Q: a. Fe(CN)6³ b. Fe(CN)64 Which compound would have the largest value of Ao? the ligand CN as here,…

A: The question is asking which compound has the largest value of (Δ0), which is the crystal field…

Q: Please correct answer and don't use hand raiting

A: This reaction shows 2-methylpropene, also known as isobutene reacting with PBA, which stands for…

Q: Use the chart to calculate the theoretical yield, the example provided please create one like the…

A: Step 1: Understanding the ReactionWe assume a reaction where sodium borohydride (NaBH₄) reduces…

Q: Find the normalization constant for the "phi part" of the hydrogen-like wave function.

Q: In addition to solving the problem please give brief explanation for concepts and solution if able.

A: Step 1: The problem involves determining the units of the rate constants k2 k1 and in a rate law.…

Q: /9 9. Draw the orbital structure of a triple bond between 2 carbons. Please label each orbital with…

A: Step 1: Step 2: Step 3: Step 4: FINAL STRUCTURE : TRIPLE BOND BETWEEN TWO CARBON:

Q: Draw a structural formula of the S configuration of the compound shown below. 0- CH₂CI • Use the…

A: Step 1:R and S designation is helpful to distinguish stereoisomers which has the same formula but…

Q: Please correct answer and don't use hand rating

A: Key PointsThe curved arrows show the movement of electrons during the reaction.The lone pairs on the…

Q: Which of the following contains potential energy? -a ball bouncing downhill -a chocolate bar on a…

A: Potential energy is the energy that an object has because of its position in relation to other…

Q: solve these questions

Q: Please correct answer and don't use hand raiting

A: The given compound is (s)-1-bromo-2-butanol.Structure of the compound:Now, given…

Q: Indicate which of the reactions shown below are oxidation/reduction reactions. If the reaction is a…

A: In a redox (reduction-oxidation) reaction, one or more elements undergo a change in oxidation state.…

Q: Show work with explanation needed..don't give Ai generated solution. Avoid handwritten Solution

A: Following structures are correct for given names.As you have asked about names ,These names are…

Question

100%

Explain the physical origin of the general selection rules of microwave and infrared spectroscopy.

AI-Generated Solution

AI-generated content may present inaccurate or offensive content that does not represent bartleby’s views.

Unlock instant AI solutions

Tap the button
to generate a solution

Click the button to generate
a solution

SEE SOLUTION

Similar questions

Explain the physical origin of the general selection rules of spectroscopy.
Provide a description of the general characteristics of rotational spectroscopy.
(i) Explain how the mass of the particle(s) involved affects the separation between energy levels in quantum mechanics. (ii) Explain why the sensitivity of an NMR experiment is affected by the strength of the applied magnetic field. (iii) Explain why, to a good approximation, rotational and vibrational transitions do not change the energies of electrons.
Rotating, vibrating and electronic spectroscopy are the techniques used to study the different energy transfers in molecules. Indicate the techniques of absorption, emission and Raman spectroscopy that are used in every case.
(b) The UV-visible electronic absorbance spectrum of the following azo dye has an absorption maximum at 524 nm. Three Raman excitation wavelengths are available to obtain the spectrum of this molecule; 406 nm, 514 nm and 785 nm. Explain as fully as possible, the differences in the spectra that would be expected using each of these different excitation wavelengths, and why differences occur. State which wavelength would be the most appropriate, justify your answer. NH2 Meo OMe N N-NH Azo dye
5. What is the basis of vibrational spectroscopy. Derive the expression for natural frequency for vibration of a spring with spring constant K and mass m.
Discuss the physical origins of the gross selection rules for microwave spectroscopy and rotational Raman spectroscopy.
Define and differentiate rotational spectroscopy, vibrational spectroscopy and electron spectroscopy.
Describe the units of IR in relation to frequency and energy and describe the functions of an FT-IR spectrometer.
7) Explain the basis of the Franck-Condon principle and how it leads to the formation of a vibrational progression.
Why is there no zero point energy associated with roational spectroscopy.
Plasma emission spectroscopy can be used to determine the concentration of elements such as iron or zinc in pharmaceutical preparations. with the aid of suitable diagrams, outline the principles behind this technique and explain how it can be used to provide qualitative and quantitative information about these elements.