Please predict the products for each of the following reactions. Hint: one of the reactions is the Friedel-Crafts Acylation. о 010 1. SOCI₂ 2. Py (base) HO 1. SOCI₂ 2. LIAIH (excess) 3. H₂O 1. SOCI₂ 2. AICI 3 6 00 8 10 SOCI₂ EtOH, H₂O* heat OH 1. SOCI₂ 2. NH3 (excess) 6 1. SOCI 2 2. Ph₂CuLi 1. SOCI₂ 2. PhMgBr (exce 3. H₂O A B ΝΗ NH2 A B C D 50 1. SOCI₂ 2. NH 1. SOCI₂ 2. Et³N (base) HO D NH2 CI

Please predict the products for each of the following reactions. Hint: one of the reactions is the Friedel-Crafts Acylation. о 010 1. SOCI₂ 2. Py (base) HO 1. SOCI₂ 2. LIAIH (excess) 3. H₂O 1. SOCI₂ 2. AICI 3 6 00 8 10 SOCI₂ EtOH, H₂O* heat OH 1. SOCI₂ 2. NH3 (excess) 6 1. SOCI 2 2. Ph₂CuLi 1. SOCI₂ 2. PhMgBr (exce 3. H₂O A B ΝΗ NH2 A B C D 50 1. SOCI₂ 2. NH 1. SOCI₂ 2. Et³N (base) HO D NH2 CI

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions

Section: Chapter Questions

Problem 20.27P

See similar textbooks

Similar questions

26. Which sequence of reactions would be the best choice to carry out the step below? Но HO а. d. 1. MgBr CI . AICI3 2. Но b. е. 1. / CI . AIC13 CI, AICI3 2. Zn(Hg), HCl с. 1. Br,. FeBr3 2. MgBr
18 of 21 60. Select the compound that is not an intermediate in the following organic transformation. ОН НО НО НО ОН ОН ОН А 61. When treated with 0.01 M HCI, molecule _will be protonated to the greatest extent while molecule will be protonated to the least extent. NH2 II IV || O=N* а. 1, I b. III, I C. III, II d. III, IV 62. Identify the mechanistic step in a Claisen condensation with the largest equilibrium constant value. a. initial proton transfer by ethoxide to yield the enolate ion b. nucleophilic attack of the enolate ion on the ester electrophile c. reformation of the carbonyl to promote heterolysis of the alkoxide leaving group d. proton transfer of the alkoxide on the newly formed beta keto ester substrate
24. Which of the following steps involves umpolung? а. 1. LIAIH4 2. Но* Но H b. Cul 2 Li CULI с. Br NaOCH3 d. 1. P(C,H5)3 2. NaH Br е. H2 Pt
Please explain how they are either Sn1, Sn2, E1, or E2.
The synthesis of an azo dye is shown below. Please answer the following questions. NH2 1) Na2CO3 2) NaNO2, HCI B N-Ñ A Š3H ŠO3 Step 1 Step 2 ŠO3 2 1 1. Why you need to add Na2CO3 in step 1? (multiple answers) Oa)To decrease the solubility of compound 1 - "salting out" ob) To deprotonate compound 1, increase solubility in water Oc) To increase the reaction yield Od)To slow down the reaction rate Oe)To neutralize the HCI
Jj.117.
CH;CH,Mgl, then aq. acid workup 1. Mg, anhydrous ether 2. Н-о -Br g. OCH3 H3C-B OCH, Pd catalyst Br h. H,C MgBr (excess) OCH3 then aq. acid workup j. Pd catalyst Heck Reaction
What is the final product of the following reaction sequence? Give structural details of all significant intermediates.
Predict the products (if any) of the reaction of each of the ff. reagents with benzoic acid. a. NaBH 4b. H2, Pt, 1 atm, room temp.c. SOCl2d. conc. HCle. CH3OH
Determine the best starting materials for the following reactions. J Kloster.. 2 ©2022 . CHEM40B W22 ©2022loster 122 J Klosterman CHEM40 V22 2024 V22 ©2022 J Klostermarr CHEM40B W22 ©202 RoORosterman CHEM4 22I Klogerman CHEM40B W22 2022 | K a) Klosternia CHEMOR N22 ©2 Br Prod#891502 b) I Klosten CHEM408 W22 CHEL Prod#502658 H2 H Et I Klos Et EMe Me Pd/C Write your answer in the Answer sheet template. 2022 Prod#658891
HO NH2 CO₂Me PG! A NH HO PG² HO CO₂Me PG! NH `PG³ PG! `NH PG3 PG! `NH B PG2 CO₂Me C PG20 LiBH4 strong reducing agent, strong nucleophile PG! NH OH
Which of the following scheme is the first step in the following Grignard reaction? + I. BrMg I. BrMg + II. :BrMg IV. :BrMg ※套